越南西北部地区Sinh Quyen岩组副片麻岩的锆石年龄及其地质意义

在大地构造位置上, 越南西北部地区是古特提斯造山带东段重要的组成部分, 并记录了印支陆块和华南板块碰撞拼合历史.其构造归属是厘定该地区古特提斯板块缝合带位置的关键.报道了出露的基底岩石Sinh Quyen岩组副片麻岩的碎屑锆石年龄, 探讨其沉积物源和归属问题.该岩组主要由长英质副片麻岩和混合岩等岩石类型构成, 被认为是越南西北部中元古代—古元古代基底岩石.采用LA-ICP-MS锆石U-Pb定年方法分析了3个长英质副片麻岩样品的116粒碎屑锆石.123个分析点锆石年龄的统计结果显示, 碎屑锆石形成时代主要集中在约1.8 Ga左右, 有少量约2.2~3.0 Ga中太古代碎屑锆石, 暗示Sinh Quyen副片麻岩沉积物源主要为早古元古代基底岩石.基底岩石在形成时间上与华南板块古老基底相似, 推断Sinh Quyen岩组在构造归属上可能来自华南板块.部分碎屑锆石边部记录约250 Ma变质增生作用, 可能与华南板块—印支板块的印支期拼合有关, 记录了古特提斯造山作用.      

Effect of loading duration on uncertainty in creep analysis of clay

Some studies suggest that creep parameters should be determined using a greater quantity of creep test data to provide more reliable prediction regarding the deformation of soft soils. This study aims to investigate the effect of loading duration on model updating. One‐dimensional consolidation data of intact Vanttila clay under different loading durations collected from the literature is used for demonstration. The Bayesian probabilistic method is used to identify all unknown parameters based on the consolidation data during the entire consolidation process, and their uncertainty can be quantified through the obtained posterior probability density functions. Additionally, the optimal models are also determined from among 9 model candidates. The analyses indicate that the optimal models can describe the creep behavior of intact soft soils under different loading durations, and the adopted method can evaluate the effect of loading duration on uncertainty in the creep analysis. The uncertainty of a specific model and its model parameters decreases as more creep data are involved in the updating process, and the updated models that use more creep data can better capture the deformation behavior of an intact sample. The proposed method can provide quantified uncertainty in the process of model updating and assist engineers to decide whether the creep test data are sufficient for the creep analysis.     

准噶尔盆地断拗转换期剥蚀厚度及其分布规律

准噶尔盆地为我国重要的陆上含油气盆地, 对其进行地层剥蚀厚度恢复能够有效地研究盆地演化历史以及油气资源评价.通过分析声波时差法的方法原理及其适用条件, 认为此方法适用于恢复准噶尔盆地断拗转换期剥蚀地层的厚度.实际计算结果表明: 断拗转换期上、中二叠统之间为主不整合, 剥蚀厚度大; 三叠系与二叠系之间形成次级不整合, 盆地剥蚀厚度相对较大, 区域位于西部盆缘地带, 自北西向南东剥蚀量逐步降低, 至盆地中心剥蚀量最低.各构造单元中, 凸起相比于凹陷所遭受的剥蚀程度较大, 反映古地貌呈现盆地西北缘高、腹部低的地形特征, 同时反映准噶尔盆地断拗转换期二叠纪晚期至三叠纪早期改造具西强东弱、边缘强内部弱的特点.     

Dissolved and particulate trace metals and their partitioning in a hypoxic estuary: The Tanshui Estuary in Northern Taiwan

The distribution and partitioning of trace metals (Co, Cu, Fe, Mn, Ni, and Zn) between dissolved and particulate phases were studied in the Tanshui Estuary. The upper reach of the estuary is hypoxic and heavily polluted due to domestic and industrial discharges. The concentration ranges of dissolved and leachable particulate trace metals in the Tanshui Estuary were: Co: 0.3–6.1 nM, 1.8–18.6 mg kg⁻¹; Cu: 5–53 nM, 22–500 mg kg⁻¹; Fe: 388–3,364 nM, 1.08–6.67%; Mn: 57–2,914 nM, 209–1,169 mg kg⁻¹; Ni: 7–310 nM, 6–108 mg kg⁻¹; and Zn: 12–176 nM, 62–1,316 mg kg⁻¹; respectively. The dissolved concentrations of the metals were 2–35 times higher than the average values of the world river water. The distributions of dissolved and particulate studied metals, except Mn, in the estuary showed scattering, which could be attributed to the discharges from many industrial wastewater disposal works located in the upper tributaries. The daily input of dissolved metals from the disposal works to the Tanshui Estuary ranged from 0.1–0.4 tons. Dissolved Mn was nearly conservative in the region with salinity higher than 10 psu, while particulate Mn decreased in the region with salinity of 10–15 psu. The concentration increased significantly seawards, corresponding with the distribution of dissolved oxygen. The distribution coefficient (K_D) for Mn in the lower estuary was nearly three orders of magnitude higher than in the upper estuary. This phenomenon may be attributed to the diffusion of Mn from the anoxic sediment in the upper estuary and gradual oxidation into particulate Mn in the middle and lower estuary as the estuarine water became more oxygenated. The distribution coefficient for Cu decreased with increasing salinity. The percentages of trace metals bound by suspended particulate matter decreased in the following order: Fe>Zn, Cu>Co>Mn>Ni.     

平原河网区域来水组成原理

对于一般树状分布河网，上一级河道总是汇入至下一级河道，位于河道下游断面的流量总是由其上游汇集而至。但对于平原河网地区，特别是人工控制建筑物众多，又受潮汐影响的地区(如太湖流域)，河网错综复杂，水流方向不定，要跟踪某个断面的水流去向，或某个河段的水体、断面流量是从哪里汇集而来的，非常困难。但这样的问题在生产实践中往往对其很感兴趣。例如从常熟枢纽引长江水流进入望虞河后，流向何处?河网各断面流量中或各河段水体中常熟枢纽引江水量占多少比重?对这些问题的研究可以估计常熟枢纽引江的效果和影响范围。因此，平原河网区域来水组成方法在生产实践中具有重要意义。重点介绍了平原河网区域来水组成原理及其在太湖流域的应用。     

长江三峡地区的夷平面在宜昌地区白垩纪—第四纪沉积物中的反映

通过对湖北宜昌地区白垩纪-第四纪沉积演化的研究,发现存在3个明显的沉积旋回,每个旋回由下部颗粒粗大的砾石层和上部颗粒较细小的粉砂-泥质层组成。3个沉积旋回对应了宜昌以西三峡地区3期构造演化旋回,同时反映了三峡地区3期夷平面的存在。结合前人研究结果、古生物化石和对第四系善溪窑组的测年数据,认为3期夷平面形成时代分别为:鄂西期夷平面形成于白垩纪晚期-古近纪的始新世,山原期夷平面形成于上新世-早更新世初,云梦期夷平面形成于早更新世末-中更新世早期。     

巴东北部地区地表水的环境化学特征及水质评价

对巴东北部地区地表水的环境化学特征进行了初步研究,并且定量分析了此区域的水质.研究表明,该地区地表水属于典型的碳酸盐地表水,元素含量都处于低水平,没有明显的重金属污染,测定7个水样中的元素含量的平均值可以作为巴东北部地区地表水的背景值.     

Eutrophication,health risk assessment and spatial analysis of water quality in Gucheng Lake,China

The water characteristics of the Gucheng Lake, such as eutrophication, health and spatial distribution, were investigated. On the basis of the trophic state index (TSI) and entropy weight, a synthesized trophic state index (STSI) model was established to assess lake eutrophication condition through calculating STSI, choosing TP, TN, COD, BOD and NH₃-N as trophic variables. The STSI ranged from 50.58 to 62.44, which showed that the water has been between eutrophic and supereutrophic. A histogram was applied to health risk assessment which was analyzed from carcinogenic substances (Cr⁺⁶, As and Cd) and non-carcinogenic substances (hydroxybenzene, Pb, Hg, CN⁻ and NH₃), and the results showed that the former was much greater than the latter for effect. The total risk for each resident caused by all pollutants ranged from 5.18E-05 to 8.34E-05, which is far higher than the standard, recommended by Sweden Bureau of Environment Protection and Holland Ministry of Building and Environment Protection (1.0E-05). Cluster analysis was used to detect similarities and dissimilarities among the seven sampling sites and explain the observed clustering in terms of affected conditions. Twenty-one variables were used to divide seven sampling sites into three groups, namely, north lake, south lake and lake center.     

Quantitative C NMR of whole and fractionated Iowa Mollisols for assessment of organic matter composition

Both the concentrations and the stocks of soil organic carbon vary across the landscape. Do the amounts of recalcitrant components of soil organic matter (SOM) vary with landscape position? To address this question, we studied four Mollisols in central Iowa, two developed in till and two developed in loess. Two of the soils were well drained and two were poorly drained. We collected surface-horizon samples and studied organic matter in the particulate organic matter (POM) fraction, the clay fractions, and the whole, unfractionated samples. We treated the soil samples with 5 M HF at ambient temperature or at 60 °C for 30 min to concentrate the SOM. To assess the composition of the SOM, we used solid-state nuclear magnetic resonance (NMR) spectroscopy, in particular, quantitative ¹³C DP/MAS (direct-polarization/magic-angle spinning), with and without recoupled dipolar dephasing. Spin counting by correlation of the integral NMR intensity with the C concentration by elemental analysis showed that NMR was ?85% quantitative for the majority of the samples studied. For untreated whole-soil samples with <2.5 wt.% C, which is considerably less than in most previous quantitative NMR analyses of SOM, useful spectra that reflected ?65% of all C were obtained. The NMR analyses allowed us to conclude (1) that the HF treatment (with or without heat) had low impact on the organic C composition in the samples, except for protonating carboxylate anions to carboxylic acids, (2) that most organic C was observable by NMR even in untreated soil materials, (3) that esters were likely to compose only a minor fraction of SOM in these Mollisols, and (4) that the aromatic components of SOM were enriched to ∼53% in the poorly drained soils, compared with ∼48% in the well drained soils; in plant tissue and particulate organic matter (POM) the aromaticities were ∼18% and ∼32%, respectively. Nonpolar, nonprotonated aromatic C, interpreted as a proxy for charcoal C, dominated the aromatic C in all soil samples, composing 69-78% of aromatic C and 27-36% of total organic C in the whole-soil and clay-fraction samples.