Sediment-water interactions of thallium under simulated estuarine conditions

Thallium(I) has been added to estuarine sediment suspended in various natural and artificial aqueous samples in order to examine its reactivity under simulated estuarine conditions. In river water and sea water, adsorption of Tl to sediment was so rapid that a period of desorption-relaxation succeeded instantaneous adsorption. Entire time-courses could not be fitted with a conventional kinetic model, but pseudo-first-order forward and reverse rate constants of 0.0044 and 0.30 h⁻¹, respectively, were derived for river water by omitting measurements defining the adsorption “overshoot” observed at the onset of the experiment. The extent of adsorption after a 16 h equilibration period was considerably greater in river water than in sea water, and displayed a quasi-linear increase with increasing pH over the range 2-9 in the former but no clear dependence on pH in the latter. A logarithmic reduction in the sediment-water distribution coefficient, K_D, was observed on estuarine mixing from river water to sea water. Experiments conducted in electrolyte solutions coupled with inorganic equilibrium speciation modeling revealed that the effect was the combined result of a reduction in the activity of Tl⁺, an increase in the proportion of TlCl⁰ and increasing competition for adsorption sites from K⁺ with an increase in salinity. Overall, there was little experimental evidence for either the oxidation of Tl⁺ or its complexation by dissolved organic matter. The findings of the investigation are discussed in terms of the likely behavior of Tl in estuaries.     

A search for evolutionary period variations of Cepheids using the Harvard plate stacks: FF Aql

Photographic plates of the Harvard Observatory stacks have been used to obtain 1261 brightness estimates for the low-amplitude Cepheid FF Aql (P = 4.47 days). Combined with published visual, photoelectric, and CCD observations, these data enable the construction of an O-C diagram spanning 122 years. The resulting O-C diagram is parabola-shaped, enabling the determination of quadratic brightness elements for the first time. The evolutionary rate of increase of the period, dP/dt = 0.072 ± 0.011 s/year, is in agreement with theoretical computations for the third crossing of the instability strip. The available data, reduced using the technique of by Eddington and Plakidis, reveal the presence of small, random period fluctuations, ? = 0.0061^d ± 0.0044^d, that do not distort the evolutionary trend of the O-C residuals.     

New 1982 — 1990 photometry of λ Andromedae and its 11-year cycle

We present photoelectric photometry of λ And never before published, obtained between February 1982 and December 1990 at 29 different observatories. Then we combine it with all other photometry available to us (previously published, contained in the I.A.U. Commission 27 Archives, and obtained with the Vanderbilt 16-inch automatic telescope but not yet published), to yield a 14.8-year data base. Analysis reveals a long-term cycle in mean brightness, with a full range of 0^m.15 and a period of 11.4 ± 0.4 years. Because most of our new photometry was concentrated in the 1983-84 observing season, we analyze that one well-defined light curve with a two-spot model. Spot A keeps a 0^m.04 amplitude throughout four rotation cycles whereas the amplitude of spot B diminishes from 0^m.09 down almost to 0^m.03. The spot rotation periods were 55^d.9 ± 0^d.6 and 520^d.8 ± 1^d.0, respectively.     

A simple numerical model for inlet sedimentation at intermittently open–closed coastal lagoons

This contribution aims to model the dominant processes that control sedimentation within the ocean inlet to intermittently open–closed coastal lagoons; focussing on the role of infilling, backfilling and morphodynamic feedback. The key elements that have been included in the present model are: (1) the delivery of sediment to the mouth of the estuary by littoral processes; (2) sediment transport processes within the inlet due to non-linear tidal flow; and (3) the down-slope diffusion of sediment. The model discussed here includes a simple one-dimensional (1-D), non-linear flow parameterisation that predicts the spatial variability in the magnitude and non-linearity of the tidal flow. The predicted third and fourth velocity moments are used to drive a morphodynamic module. Down-slope diffusion of sediment is dealt with in a separate diffusion term in the bed-evolution equation. Feedback between the evolving morphology and the flow field are integral to the model. Numerical simulations are used to investigate different modes of evolution for this type of inlet system. Inlet closure due to infilling is critically controlled by the balance between sediment addition at the mouth due to littoral processes and the removal of sediment by non-linear tidal flow. Rapid widening or deepening of the inlet at its landward margin leads to the deposition of a flood shoal. Under conditions of high sedimentation (and low diffusion) the flood shoal can become sufficiently well developed to present a physical barrier to sediment entering the lagoon. Under these circumstances backfilling can become significant. The infilling and backfilling processes are ameliorated by efficient down-slope diffusion which is controlled in the present model by a diffusion parameter, D. High diffusion coefficients slow inlet closure and allow sediment to propagate further into the lagoon.     

The origin of [Fe ii] emission in NGC 4151

The centre of NGC 4151 has been observed in the J band with the SMIRFS integral field unit (IFU) on the UK Infrared Telescope. A map of [Fe  ii ] emission is derived, and compared with the distributions of the optical narrow-line region and radio jet. We conclude that, because the [Fe  ii ] emission is associated more closely with the visible narrow-line region than with the radio jet, it arises mainly through photoionization of gas by collimated X-rays from the Seyfert nucleus. The velocity field and strength with respect to Pa β are found to be consistent with this argument. The performance of the IFU is considered briefly, and techniques for observation and data analysis are discussed.     

Comparative Analysis of a Transition Region Bright Point with a Blinker and Coronal Bright Point Using Multiple EIS Emission Lines

Since their discovery 20 year ago, transition region bright points have never been observed spectroscopically. Bright point properties have not been compared with similar transition region and coronal structures. In this work we have investigated three transient quiet Sun brightenings including a transition region bright point (TR BP), a coronal bright point (CBP) and a blinker. We use time-series observations of the extreme-ultraviolet emission lines of a wide range of temperature T (logT=5.3?–?6.4) from the EUV Imaging Spectrometer (EIS) onboard the Hinode satellite. We present the EIS temperature maps and Doppler maps, which are compared with magnetograms from the Michelson Doppler Imager (MDI) onboard the SOHO satellite. Doppler velocities of the TR BP and blinker are ≤?25 km?s^?1, which is typical of transient TR phenomena. The Doppler velocities of the CBP were found to be ≤?20 km?s^?1 with exception of those measured at logT=6.2 where a distinct bi-directional jet is observed. From an EM loci analysis we find evidence of single and double isothermal components in the TR BP and CBP, respectively. TR BP and CBP loci curves are characterized by broad distributions suggesting the existence of unresolved structure. By comparing and contrasting the physical characteristics of the events we find that the BP phenomena are an indication of multi-scaled self-similarity, given the similarities in both their underlying magnetic field configuration and evolution in relation to EUV flux changes. In contrast, the blinker phenomena and the TR BP are sufficiently dissimilar in their observed properties as to constitute different event classes. Our work is an indication that the measurement of similar characteristics across multiple event types holds class-predictive power, and is a significant step towards automated solar atmospheric multi-class classification of unresolved transient EUV sources. Finally, the analysis performed here establishes a connection between solar quiet region CBPs and jets.     

Shock metamorphism of quartz in nature and experiment: II. Significance in geoscience*

Abstract— The occurrence of shock metamorphosed quartz is the most common petrographic criterion for the identification of terrestrial impact structures and lithologies. Its utility is due to its almost ubiquitous occurrence in terrestrial rocks, its overall stability and the fact that a variety of shock metamorphic effects, occurring over a range of shock pressures, have been well documented. These shock effects have been generally duplicated in shock recovery experiments and, thus, serve as shock pressure barometers. After reviewing the general character of shock effects in quartz, the differences between experimental and natural shock events and their potential effects on the shock metamorphism of quartz are explored. The short pulse lengths in experiments may account for the difficulty in synthesizing the high-pressure polymorphs, coesite and stishovite, compared to natural occurrences. In addition, post-shock thermal effects are possible in natural events, which can affect shock altered physical properties, such as refractive index, and cause annealing of shock damage and recrystallization. The orientations of planar microstructures, however, are unaffected by post-impact thermal events, except if quartz is recrystallized, and provide the best natural shock barometer in terms of utility and occurrence. The nature of planar microstructures, particularly planar deformation features (PDFs), is discussed in some detail and a scheme of variations in orientations with shock pressure is provided. The effect of post-impact events on PDFs is generally limited to annealing of the original glass lamellae to produce decorated PDFs, resulting from the exsolution of dissolved water during recrystallization. Basal (0001) PDFs differ from other PDF orientations in that they are multiple, mechanical Brazil twins, which are difficult to detect if not partially annealed and decorated. The occurrence and significance of shock metamorphosed quartz and its other phases (namely, coesite, stishovite, diaplectic glass and lechatelierite) are discussed for terrestrial impact structures in both crystalline (non-porous) and sedimentary (porous) targets. The bulk of past studies have dealt with crystalline targets, where variations in recorded shock pressure in quartz have been used to constrain aspects of the cratering process and to estimate crater dimensions at eroded structures. In sedimentary targets, the effect of pore space results in an inhomogeneous distribution in recorded shock pressure and temperature, which requires a different classification scheme for the variation of recorded shock compared to that in crystalline targets. This is discussed, along with examples of variations in the relative abundances of planar microstructures and their orientations, which are attributed to textural variations in sedimentary target rocks. Examples of the shock metamorphism of quartz in distal ejecta, such as at the K/T boundary, and from nuclear explosions are illustrated and are equivalent to that of known impact structures, except with respect to characteristics that are due to long-term, post-shock thermal effects. Finally, the differences between the deformation and phase transformation of quartz by shock and by endogenic, tectonic and volcanic processes are discussed. We confirm previous conclusions that they are completely dissimilar in character, due to the vastly different physical conditions and time scales typical for shock events, compared to tectonic and volcanic events. Well-characterized and documented shock effects in quartz are unequivocal indicators of impact in the natural environment.     

Kinetics of phosphate adsorption by iron oxyhydroxides in aqueous systems

The rate of uptake of phosphate onto synthetic Fe(III)- and Fe(II)-derived oxyhydroxides has been studied using reaction conditions similar to those encountered in natural waters. Kinetic analyses were carried out on the adsorption profiles and both first-order and second-order conditional rate constants were obtained. The temperature dependence of some of the rate constants was investigated and corresponding apparent activation energies calculated. Similar experiments and analyses were undertaken using Fe from natural sources and in general the conditional rate constants obtained in seawater were in agreement with the synthetic ones. The results of this study are of value when comparing the time scales of adsorption processes in natural waters with the time scales of mixing and advection.