A multidisciplinary approach to reveal the Sicily Climate and Environment over the last 20 000 years

We present a thorough review of the knowledge on the climate and environment in Sicily over the last 20 000 years, taking into account results of several studies carried using terrestrial and marine records. We obtain a coherent framework of the most important changes succeeded in the island, even if some points need further investigation. All the reconstructions of surface temperatures of the seas and the air surrounding Sicily point out severe climatic conditions during the last glacial period. The steppe- and semisteppe-like vegetation pattern testifies, together with additional evidence from geochemical data of lacustrine evidence, markedly arid conditions. Fi-nally, significant episodes of sea level drop connected Sicily to the Italian Peninsula and favoured the dispersion of faunal elements from southern Italy. The transition between the last glacial and the Holocene was not characterized by a gradual warming but was punctuated by two abrupt suborbital climatic fluctuations: Bølling-Allerød (warm) and Younger Dryas (cold), as recognized in the sediments recovered close to the northern and southern coast of Sicily. A denser arboreal cover is possibly indicated by the occurrence of dormouse and Arvicola remains. Finally the sensitivity of Sicily to climate perturbations is demonstrated by the occurrence of repeated subtle climatic anomalies during the Holocene, including the Little Ice Age, also known from historical chronicles. Forests, woods and Mediterranean maquis developed in the early-middle Holocene. Thereafter was a general decline of arboreal vegetation, following a general aridification trend that seems to be a common feature in southern Europe and North Africa. Science Greek colonization (7^th century before Christ), the landscape was intensively modelled for agriculture and breeding, leading to a significant loss of vegetation cover.     

The distance–redshift equation in quintessence cosmology and the estimation of H0 through time delays

We calculate analytically and numerically the distance–redshift equation in perfect fluid quintessence models and give an accurate fit to the numerical solutions for all the values of the density parameter and the quintessence equation of state. Then we apply our solutions to the estimation of H ₀ from multiple image time delays and find that the inclusion of quintessence modifies significantly the likelihood distribution of H ₀, generally reducing the best estimate with respect to a pure cosmological constant. Marginalizing over the other parameters (Ω _m and the quintessence equation of state) we obtain H ₀=71±6 km s⁻¹ Mpc⁻¹ for an empty beam and H ₀=64±4 km s⁻¹ Mpc⁻¹ for a filled beam. These errors, however, do not take into account the uncertainty on the modelling of the lens. We also discuss the future prospects for distinguishing quintessence from a cosmological constant with time delays.     

Vertical distribution of two sympatric labrid fishes in the Western Mediterranean and Eastern Atlantic rocky subtidal: local shore topography does matter

Changes in the shore topography (e.g. slope) occur at a scale of hundreds of meters in several locations in the Lusitanian and the Mediterranean Sea provinces. We tested whether differences in the bottom inclination might affect the vertical distribution patterns of two sympatric coastal labrid fishes, the rainbow wrasse Coris julis and the ornate wrasse Thalassoma pavo. Visual censuses were used to determine the distribution and abundance of these labrid species in high (≥30°) and low (≤3°) slope rocky substrates covered by brown macroalgae and at two different depths (shallow, 4–7 m, and deep 14–20 m). Pectoral fin aspect ratio was used as an estimate of swimming performance to potentially explain the patterns observed. Despite the intrinsic biogeographical differences in the overall density of T. pavo and C. julis, on steep coasts the ornate wrasse dominated in shallow waters, whereas the two species coexisted both in shallow and deeper depths on gentle slope coasts. These distribution patterns were consistent across locations, and fin aspect ratio was not a good predictor of between‐habitat use for wrasses. We show that, under specific topographical conditions, the depth segregation pattern seems to be an interactive segregation (likely related to resource competition) rather than a result of selective segregation due to morphological differences in the pectoral fin. Significant ecological changes might occur in locations where the density of T. pavo has recently increased as a result of water warming.     

Low temperature behaviour of natural saline fluid inclusions in saddle dolomite (Paleozoic,NW Spain)

The origin of many dolomites is still a matter of debate because of many possible chemical and hydrological conditions of formation. Fluid inclusion studies have been applied in order to improve knowledge about paleofluids responsible for the precipitation of dolomite, and used to define temperatures and salinities. The combination of Raman Spectroscopy and microthermometry is tested here to improve the analytical method to identify the main ion species present in individual inclusions. Natural samples of saddle dolomite from the Cambrian Láncara Fm., Cantabrian Mountains (NW Spain), contain zoned crystals with two‐phase aqueous fluid inclusions (liquid‐rich). The most stable phase assemblage in these inclusions at −150 °C consists of ice, hydrohalite and an unknown salt hydrate. The latter melts between −47 and −41 °C, probably representing a eutectic temperature. Subsequently, ice melts in the range of −32.5 to −29 °C and, finally, hydrohalite melts between −9 and −3.5 °C. Salinities can be calculated in the fluid system H₂O–NaCl with addition of another salt, either CaCl₂ or MgCl₂, and result in 7.5–10.6 eq. mass% NaCl and 17.0–21.0 eq. mass% CaCl₂. Dependent on the rate of cooling runs, three different types of metastability may occur, i.e. the absence of hydrohalite, the unknown salt‐hydrate is not formed, and the nucleation of only ice. Salinity calculations from those melting temperatures differ substantially from equilibrium behaviour values. The unknown salt‐hydrate needs to be further specified by comparison to standard solutions. The method gives an opportunity to characterize the major compounds in complex fluid systems active during dolomitization, thus contributing to a better understanding of the ‘dolomite problem’.     

An anthropogenic origin of the “Sirente crater,” Abruzzi,Italy

Abstract— In this paper, we review the recent hypothesis, based mostly on geomorphological features, that a ～130 m‐wide sag pond, surrounded by a saddle‐shaped rim from the Sirente plain (Abruzzi, Italy), is the first‐discovered meteoritic crater of Italy. Sub‐circular depressions (hosting ponds), with geomorphological features and size very similar to those exhibited by the main Sirente sag, are exposed in other neighboring intermountain karstic plains from Abruzzi. We have sampled present‐day soils from these sag ponds and from the Sirente sags (both the main “crater” and some smaller ones, recently interpreted as a crater field) and various Abruzzi paleosols from excavated trenches with an age range encompassing the estimated age of the “Sirente crater.” For all samples, we measured the magnetic susceptibility and determined the Ni and Cr contents of selected specimens. The results show that the magnetic susceptibility values and the geochemical composition are similar for all samples (from Sirente and other Abruzzi sags) and are both significantly different from the values reported for soils contaminated by meteoritic dust. No solid evidence pointing at an impact origin exists, besides the circular shape and rim of the main sag. The available observations and data suggest that the “Sirente crater,” together with analogous large sags in the Abruzzi intermountain plains, have to be attributed to the historical phenomenon of “transumanza” (seasonal migration of sheep and shepherds), a custom that for centuries characterized the basic social‐economical system of the Abruzzi region. Such sags were excavated to provide water for millions of sheep, which spent summers in the Abruzzi karstic high pasture lands, on carbonatic massifs deprived of natural superficial fresh water. Conversely, the distribution of the smaller sags from the Sirente plain correlates with the local pattern of the calcareous bedrock and, together with the characteristics of their internal structure, are best interpreted as natural dolines. In fact, reported radiocarbon ages for the formation of the main sag pond and of the smaller sags differ (significantly) by more than two millennia, thus excluding that they were all contemporaneously formed by a meteoritic impact.     

Use of ETM+ images to extend stem volume estimates obtained from LiDAR data

Airborne LiDAR techniques can provide accurate measurements of tree height, from which estimates of stem volume and forest woody biomass can be obtained. These techniques, however, are still expensive to apply repeatedly over large areas. The current paper presents a methodology which first transforms mean stand heights obtained from LiDAR over small strips into relevant stem volume estimates. These are then extended over an entire forest by applying two estimation methods (k-NN and locally calibrated regression) to Landsat ETM+ images. The methodology is tested over a coastal area covered by pine forest in the Regional Park of San Rossore (Central Italy). The results are evaluated by comparison with the ground stem volumes of a recent forest inventory, taking into consideration the effect of stand size. In general, the accuracies of two estimation methods are dependent on the size of the forest stands and are satisfactory only when considering stands larger than 5-10 ha. The outputs of the parametric regression procedure are slightly more stable than those of k-NN and more faithfully reproduce the spatial patterns of the ground data.     

Crystallization kinetics of alkali feldspars in cooling and decompression-induced crystallization experiments in trachytic melt

Cooling and decompression experiments have been carried out on trachytic melts in order to investigate crystallization kinetics of alkali feldspar, the effect of the degree of undercooling (ΔT = T _liquidus ? T _experimental) and time on nucleation and crystal growth process. This experimental work gives us new data about crystallization kinetics of trachytic melts, and it that will be useful to better understand the natural system of Campi Flegrei volcanoes. Experiments have been conducted using cold seal pressure vessel apparatus, at pressure between 30 and 200 MPa, temperature between 750 and 855 °C, time between 7,200 and 57,600 s and redox condition close to the NNO +0.8 buffer. These conditions are ideal to reproducing pre- and syn-eruptive conditions of the Campi Flegrei volcanoes, where the “conditions” pertain to the complete range of pressures, temperatures and time at which the experiments were performed. Alkali feldspar is the main phase present in this trachyte, and its abundance can strongly vary with small changes in pressure, temperature and water content in the melt, implying appreciable variations in the textures and in the crystallization kinetics. The obtained results show that crystallization kinetics are strictly related to ΔT, time, final pressure, superheating (?ΔT) and water content in the melt. ΔT is the driving force of the crystallization, and it has a strong influence on nucleation and growth processes. In fact, the growth process dominates crystallization at small ΔT, whereas the nucleation dominates crystallization at large ΔT. Time also is an important variable during crystallization process, because long experiment durations involve more nucleation events of alkali feldspar than short experiment durations. This is an important aspect to understand magma evolution in the magma chamber and in the conduit, which in turn has strong effects on magma rheology.     

Implementing a trans-boundary flood risk management plan: a method for determining willingness to cooperate and case study for the Scheldt estuary

In this paper, I applied statistical, econometric, and mathematical methodologies to evaluate the conditions required for implementing a publicly supported trans-boundary flood risk management plan in accordance with the EU Floods Directive (2007/60/EU). Although this paper adopts a focus on the methodology rather than on solving a specific problem, the Scheldt estuary is used to provide an illustrative case study of this approach. I showed that, apart from some expected minor differences, the Belgians and the Dutch can be considered a relatively homogeneous population. Moreover, I estimated the main determinants of both perceived flood risk (PFR) and willingness to pay (WTP) for a compensation fund by using a linear model and an ordered probit model (based on a double-bounded dichotomous-choice approach), respectively. Some policies appear to be potentially effective: a campaign to inform the general public about evacuation and trauma management could increase WTP by 19 and 21 %, respectively; an information campaign focused on young women could reduce PFR; and a campaign to inform the general public about flood strategies and the need to disregard flood events in the press could reduce PFR by 56 and 54 %, respectively. Finally, I showed that, apart from some expected differences between the values at risk in Belgium and the Netherlands, both individual rationality and overall feasibility conditions are met. Thus, if information campaigns and other measures are designed to account for differences between the Belgians and the Dutch, a publicly supported trans-boundary flood risk management plan can be successfully implemented.     

Packed‐Column of Granular Activated Carbons for Removal of Chemical Oxygen Demand from Industrial Wastewater

In the present study, chemical oxygen demand (COD) removal by packed‐columns of activated carbon (AC) derived from two different materials (coal activated carbon, CAC and wood activated carbon, WAC) is reported as part of an on‐site wastewater treatment system for handling small volumes of wastewater generated at wood‐floor industries for which there are no proper on‐site treatment options available in the market. The performance of the sorbents, the effect of bed depth (0.19 and 0.57 m) and volumetric load (0.10 and 0.24 m h^?1) on the breakthrough curve of sorption systems were studied. The results indicated the feasibility of using both ACs to treat these wastewaters. At the bed depth (0.57 m), volumetric load (0.24 m h^?1), and 30% breakthrough, CAC and WAC showed treatment capacity of 40.5 L kg^?1 in 250 h and 23.8 L kg^?1 in 63 h, respectively. This indicated that CAC requires longer retention times to reach a performance similar to WAC. The experimental data was fit into the bed depth‐service time model showing that under the same conditions, CAC had higher maximum sorption capacity (N₀) than WAC. Moreover, thermal regeneration at 500°C temperature could be a cost‐effective procedure since the reuse of spent AC through such regeneration process for further treatment could still achieve 90% of the initial sorption capacity, reducing then costs for the use of new sorbents and also the need for waste disposal.