Anthropogenic contamination of groundwater with nitrate in arid region: case study of southern Hodna (Algeria)

In southern Hodna, an arid region of Algeria, the extension of irrigated agriculture and overexploitation of groundwaters have led to a rupture with traditional land use by pastoralism. Due to the arid conditions, groundwaters are the only water resources for man and irrigation. This study focuses on nitrate contamination of groundwaters and its increase since the last 40 years, on the basis of two archives and recent analyses. The chemical facies of waters is sulphate-chloride, the risk of salinity is moderate to large. The sodicity risk, as estimated by the SAR, is low due to the large salinity and the sandy soil texture. Nitrate contamination of deep groundwater is a clear evidence when recent data are compared to the historical data. From 1996 to 2008, the proportion of samples with NO ₃ ^? concentrations larger than 50 mg/L increases from 24 to 61 %, the proportion of samples with NO ₃ ^? concentrations larger than 100 mg/L increases from 12 to 27 %. The study points at a general contamination of aquifers from anthropic origin: phreatic water was already contaminated when pastoralism was dominant (1967); as population increased and irrigation agriculture developed with large use of N-fertilizers and organic amendments, contamination extended spatially and vertically to deep aquifer. To remediate this contamination, fertilizers should be fractionated and limited to plant requirements on the basis of soil and plant analyses. Excess of irrigation should be avoided. Soil surface should be continuously covered to prevent nitrate leaching. Secondly, more efficient irrigation techniques, such as localized irrigation, should be implemented, with adaptation of crop systems and fertilizer inputs to arid conditions. Farmers should then be trained; simultaneously, local agronomic references that are presently lacking should be acquired.     

Revisiting the Curie Balance Concept: Towards Simple High-Field Magnetic Measurements

A combination of a standard electronic balance and a movable permanent magnet field source (Halbach cylinder: HC) is demonstrated using two HCs of 0.3 and 1 T fields. It provides high field susceptibility and saturation magnetization measurements with high sensitivity (about 3e^-7 SI and 0.1 Am^-1, corresponding to a 0.1 mg balance sensitivity) and high speed. This set-up opens the possibility for systematic high field parameter determination on standard samples.     

Inter-laboratory calibration of low-field magnetic and anhysteretic susceptibility measurements

Inter-laboratory and absolute calibrations of rock magnetic parameters are fundamental for grounding a rock magnetic database and for semi-quantitative estimates about the magnetic mineral assemblage of a natural sample. Even a dimensionless ratio, such as anhysteretic susceptibility normalized by magnetic susceptibility (K_a/K) may be biased by improper calibration of one or both of the two instruments used to measure K_a and K. In addition, the intensity of the anhysteretic remanent magnetization (ARM) of a given sample depends on the experimental process by which the remanence is imparted. We report an inter-laboratory calibration of these two key parameters, using two sets of artificial reference samples: a paramagnetic rare earth salt, Gd₂O₃ and a commercial “pozzolanico” cement containing oxidized magnetite with grain size of less than 0.1 μm according to hysteresis properties. Using Gd₂O₃ the 10 Kappabridges magnetic susceptibility meters (AGICO KLY-2 or KLY-3 models) tested prove to be cross-calibrated to within 1%. On the other hand, Kappabridges provide a low-field susceptibility value that is ca. 6% lower than the tabulated value for Gd₂O₃, while average high-field susceptibility values measured on a range of instruments are indistinguishable from the tabulated value. Therefore, we suggest that Kappabridge values should be multiplied by 1.06 to achieve absolute calibration. Bartington Instruments magnetic susceptibility meters with MS2B sensors produce values that are 2-13% lower than Kappabridge values, with a strong dependence on sample centering within the sensor. The K_a/K ratio of ca. 11, originally obtained on discrete cement samples with a 2G Enterprises superconducting rock magnetometer and a KLY-2, is consistent with reference parameters for magnetites of grain size <0.1 μm. On the other hand, K_a values from a 2G Enterprises magnetometer and K values from a Bartington Instruments MS2C loop sensor for u-channel and discrete cement samples, will produce average K_a/K values that are unrealistically high if not properly corrected for the nominal volume detected by the sensors for these instruments. Inter-laboratory measurements of K and K_a for standard paleomagnetic plastic cubes filled with cement indicate remarkable differences in the intensity of the newly produced ARMs (with a standard deviation of ca. 21%), that are significantly larger than the differences observed from the calibration of the different magnetometers employed in each laboratory. Differences in the alternating field decay rate are likely the major source of these variations, but cannot account for all the observed variability. With such large variations in experimental conditions, classical interpretation of a “King plot” of K_a versus K would imply significant differences in the determination of grain size of magnetite particles on the same material.     

Understanding solubilisation using principles of surfactant self-assembly as geometrical constraintsCompréhension de la solubilisation par utilisation des principes d'auto-association des tensioactifs à partir des contraintes géometriques

Our aim is to give a short introduction of the use of phase diagrams in order to rationalise general principles of surfactant self-assembly. These can be rationalised in terms of geometrical constraints: volume, surface and curvature. Binary (two components: surfactant and water) and ternary systems (surfactants, water, oil) are considered separately. Models for solubilisation, to be understood within the general principles and not as tabulated data, are presented. Finally, some examples of application of solubilisation in formulation are given. To cite this article: F. Testard, T. Zemb, C. R. Geoscience 334 (2002) 649–663.     

High-resolution last deglaciation record from the Congo fan reveals significance of mangrove pollen and biomarkers as indicators of shelf transgression

High abundances of mangrove pollen have been associated with transgressive cycles on tropical margins, but the detailed relations between systems tracts and the taphonomy of the pollen are unclear. We report here the occurrence and high abundance of Rhizophora pollen, in association with taraxerol, a Rhizophora-sourced biomarker, from a high-resolution Congo fan core covering the last deglaciation. An age model based on ¹⁴C dates enables the temporal changes in taraxerol content and the percentage frequencies and flux (pollen grains (pg) cm⁻² (10³ yr)⁻¹) of mangrove pollen to be compared quantitatively with the lateral rate of transgression across the flooding surface (derived from glacio-hydro-isostatic model output and the bathymetry of the margin). Rhizophora pollen concentrations and taraxerol content of the sediment are very strongly positively correlated with the lateral rate of transgression and indicate, independently of any sequence stratigraphic context, that mangrove pollen spikes are associated with the transgressive systems tract rather than the highstand systems tract or maximum flooding surface. Lower-resolution longer-term records from this margin indicate an association between taraxerol concentrations and transgressive rather than regressive phases. The flux of these materials to the Congo fan is interpreted as a function of the erosion of flooded mangrove swamp on the shelf and, less importantly, changing extent of mangrove habitat, during sea-level rise. Congo River palaeoflood events also result in reworking of mangrove pollen and supply to the fan, but this mechanism is subdominant. Rhizophora pollen has been underestimated in many palynological studies undertaken on cores from the African margin because of inappropriate sieve mesh size used during laboratory preparation.     

Legitimacy issues in public participation in coastal decision making processes: Case studies from Belgium and France

Public participation is one of the central principles of Integrated Coastal Zone Management (ICZM). However, within current public participation practice in coastal decision making there remain questions regarding whether or not the project leaders or participation processes can be considered legitimate. The paper explores the issue of legitimacy, examining case studies of coastal decision making processes from Belgium and France, focusing on the legal constraints for public participation including degree of formality and government style. It reveals that there are legitimacy issues in public participation related to the legal and institutional framework of the project, as well as to the knowledge base, and characteristics of the stakeholders and their interests. This study concludes that legitimacy issues in an ICZM process cannot be solved entirely through an institutional framework and associated legislation.     

The problem of critical inclination combined with a resonance in mean motion in artificial satellite theory

In this paper the two-degree of freedom problem of a geosynchronous artificial satellite orbiting near the critical inclination is studied. First a local approach of this problem is considered. A semi-numerical method, well suited to describe the perturbations of a non-trivial separable system, is then applied such that surfaces of section illustrating the global secular dynamics are obtained. The results are confirmed by numerical integrations of the full Hamiltonian.Research Assistant for the Belgian National Fund for Scientific Research     

Climatic instability in west equatorial Africa during the Mid- and Late Holocene

Millennial-scale climatic variations have punctuated the Holocene characterised by abrupt changes from warm to cool or wetter to drier conditions. Amongst these climatic events, there is increased evidence for an abrupt multicentennial shift of climatic conditions around 3.8/3.7 kyr BP (4.1 cal. kyr BP) in mid- to low-latitude regions which had a profound impact on landscape and population migration. In the Mediterranean region, subtropical, tropical and equatorial Africa, a number of continental proxies (lake-levels, pollen sequences, stable isotopes) record this abrupt change towards drier conditions. However, regionalism in climatic conditions is reflected in the vegetation records, possibly in relation to orographic conditions and the influence of sea-surface conditions. Hitherto there have been very few marine sequences that record this particular climatic shift at high-resolution. We present here new data from the Congo deep-sea fan containing integrated marine and terrestrial proxies. Around 5–4 cal. kyr BP, shifts in surface conditions off the Congo River mouth are observed, with possible establishment of seasonal coastal upwelling, and lower sea-surface temperatures. In parallel, pollen data indicate fluctuations of herbaceous, afromontane taxa and charred grass cuticles, suggesting more open vegetation in the lowland regions and an increase in cloud forest and/or afromontane vegetation at higher altitudes within the Congolese region.