Collins Glacier Retreat Process and Regional Climatic Variations,King George Island,Antarctica

This paper investigates the recent climatic variability and changes in snow line and ice front position in Collins Glacier, King George Island, South Shetland Islands, Antarctic Peninsula. This region has recorded one of the largest temperature increases in the past fifty years and has been demonstrated to be highly sensitive to climate changes. To monitor recent changes (1983–2006), we determined the fluctuations of the terminus and snow line of the glacier via remote sensing data and field observation in the summer of 2013. We conclude that the Collins Glacier has responded slowly to regional climate changes (decades or even centuries), as glacial responses to climatic events do not depend solely on one environmental variable. The glacier presented more retreat and elevation of the snow line in the north sector. The retreat data are correlated with the mean monthly temperature and annual number of days of melting‐degree variations.     

DmpIRFs and DmpST:DAMPE instrument response functions and science tools for gamma-ray data analysis

Observing GeV gamma-rays is an important goal of the DArk Matter Particle Explorer(DAMPE)for indirect dark matter searching and high energy astrophysics. In this work, we present a set of accurate instrument response functions for DAMPE(DmpIRFs) including the effective area, point-spread function and energy dispersion, which are crucial for gamma-ray data analysis based on statistics from simulation data. A dedicated software named DmpST is developed to facilitate the scientific analyses of DAMPE gamma-ray data. Considering the limited number of photons and angular resolution of DAMPE, the maximum likelihood method is adopted in DmpST to better disentangle different source components. The basic mathematics and framework regarding this software are also introduced in this paper.     

Creating regional climate change scenarios over southern South America for the 2020’s and 2050’s using the pattern scaling technique: validity and limitations

Dynamical downscaling of global climate simulations is the most adequate tool to generate regional projections of climate change. This technique involves at least a present climate simulation and a simulation of a future scenario, usually at the end of the twenty first century. However, regional projections for a variety of scenarios and periods, the 2020s or the 2050s, are often required by the impact community. The pattern scaling technique is used to estimate information on climate change for periods and scenarios not simulated by the regional model. We based our study on regional simulations performed over southern South America for present climate conditions and two emission scenarios at the end of the twenty first century. We used the pattern scaling technique to estimate mean seasonal changes of temperature and precipitation for the 2020s and the 2050s. The validity of the scalability assumptions underlying the pattern scaling technique for estimating near future regional climate change scenarios over southern South America is assessed. The results show that the pattern scaling works well for estimating mean temperature changes for which the regional changes are linearly related to the global mean temperature changes. For precipitation changes, the validity of the scalability assumption is weaker. The errors of estimating precipitation changes are comparable to those inherent to the regional model and to the projected changes themselves.     

Regional climate change experiments over southern South America. II: Climate change scenarios in the late twenty-first century

We present an analysis of climate change over southern South America as simulated by a regional climate model. The regional model MM5 was nested within time-slice global atmospheric model experiments conducted by the HadAM3H model. The simulations cover a 10-year period representing present-day climate (1981–1990) and two future scenarios for the SRESA2 and B2 emission scenarios for the period 2081–2090. There are a few quantitative differences between the two regional scenarios. The simulated changes are larger for the A2 than the B2 scenario, although with few qualitative differences. For the two regional scenarios, the warming in southern Brazil, Paraguay, Bolivia and northeastern Argentina is particularly large in spring. Over the western coast of South America both scenarios project a general decrease in precipitation. Both the A2 and B2 simulations show a general increase in precipitation in northern and central Argentina especially in summer and fall and a general decrease in precipitation in winter and spring. In fall the simulations agree on a general decrease in precipitation in southern Brazil. This reflects changes in the atmospheric circulation during winter and spring. Changes in mean sea level pressure show a cell of increasing pressure centered somewhere in the southern Atlantic Ocean and southern Pacific Ocean, mainly during summer and fall in the Atlantic and in spring in the Pacific. In relation to the pressure distribution in the control run, this indicates a southward extension of the summer mean Atlantic and Pacific subtropical highs.     

Contemporary Rates of Carbon Sequestration Through Vertical Accretion of Sediments in Mangrove Forests and Saltmarshes of South East Queensland,Australia

Mangrove forests and saltmarshes are important habitats for carbon (C) sequestration in the coastal zone but variation in rates of C sequestration and the factors controlling sequestration are poorly understood. We assessed C sequestration in Moreton Bay, South East Queensland in mangrove forests and tidal marshes that span a range of environmental settings and plant communities, including mangrove forests and tidal marshes on the oligotrophic sand islands of the eastern side of Moreton Bay and on the nutrient enriched, western side of the bay adjacent to the city of Brisbane. We found that rates of C sequestration in sediments were similar among mangrove forests over the bay, despite large differences in the C density of sediments, because of different rates of vertical accretion of sediments. The C sequestration on the oligotrophic sand island tidal marshes, dominated by Juncus kraussii, had the highest rate of C sequestration in the bay while the western saltmarshes, which were dominated by Sarcocornia quinqueflora, had the lowest rate of C sequestration. Our data indicate C sequestration varies among different tidal wetland plant community types, due to variation in sediment characteristics and rates of sediment accretion over time.     

Responses of testate amoebae assemblages (Amoebozoa: Arcellinida) to recent volcanic eruptions,inferred from the sediment record in Laguna Verde,southern Patagonia,Argentina

Journal of Paleolimnology - There is little knowledge about testate amoebae in lakes and their responses to volcanic eruptions. To address this knowledge gap, we studied the paleoecology of these...     

Biomonitoring with benthic macroalgae and direct assay of heavy metals in seawater of the Oporto coast (northwest Portugal)

The concentrations of dissolved Cd, Cu, Hg and Pb in seawater and algae (Enteromorpha spp. and Porphyra spp.) were determined in parallel on three beaches located in the Oporto coast (Portugal), during 8 successive months, comprising periods of low and high biological productivity. The concentrations of dissolved metals in seawater varied markedly during the sampling period and exhibited seasonality. The concentrations of Cd were high in autumn and winter, but low in spring. The concentrations of Cu and Hg were high in autumn, low in winter and peaked in May. The concentrations of Pb were low in autumn and winter, and also peaked in May. It is likely that biological activity was, at least partially, responsible for the observed seasonal changes. The mean concentrations of dissolved metals in seawater were similar to those reported for polluted and industrialized european coastal areas. Metal concentration factors, calculated month-to-month for each alga, metal and site, varied markedly during the sampling period, indicating that concentration factors based on single or few determinations could be misleading. On the contrary, mean concentration factors (calculated by dividing the mean metal concentration in the algae by the mean metal concentration in seawater) were relatively constant at all three sites, indicating that in the Oporto coast, Enteromorpha spp. can be used to estimate the mean concentration of dissolved Cd, Cu and Hg in seawater, and Porphyra spp., the mean concentration of Cd, Cu and Pb. However, considering that future estimates of the concentrations of these metals in seawater should be based on determinations of the metal contents in Enteromorpha spp. and Porphyra spp. carried out on several occasions spanning a considerable period of time, the use of these algae as monitors of heavy metal pollution can have limited practical advantages over the direct assay of the metals in seawater.     

Characterization of Late Cretaceous to Miocene source rocks in the Eastern Mediterranean Sea: An integrated numerical approach of stratigraphic forward modelling and petroleum system modelling

Stratigraphic forward modelling was used to simulate the deposition of Upper Cretaceous, Eocene and Oligo‐Miocene source rocks in the Eastern Mediterranean Sea and, thus, obtain a process‐based 3D prediction of the quantity and quality distribution of organic matter (OM) in the respective intervals. Upper Cretaceous and Eocene models support the idea of an upwelling‐related source rock formation along the Levant Margin and the Eratosthenes Seamount (ESM). Along the margin, source rock facies form a narrow band of 50 km parallel to the palaeo shelf break, with high total organic carbon (TOC) contents of about 1% to 11%, and HI values of 300–500 mg HC/g TOC. On top of the ESM, TOC contents are mainly between 0.5% and 3% and HI values between 150 and 250 mg HC/g TOC. At both locations, TOC and HI values decrease rapidly towards the deeper parts of the basin. In the Oligo‐Miocene intervals, terrestrial OM makes up the highest contribution to the TOC content, as marine organic matter (OM) is diluted by high‐sedimentation rates. In general, TOC contents are low (<1%), but are distributed relatively homogenously throughout the whole basin, creating poor quality, but very thick source rock intervals of 1–2 km of cumulative thickness. The incorporation of these source rock models into a classic petroleum system model could identify several zones of thermal maturation in the respective source rock intervals. Upper Cretaceous source rocks started petroleum generation in the late Palaeocene/early Eocene with peak generation between 20 and 15 Ma ca. 50 km offshore northern Lebanon. Southeast of the ESM, generation started in the early Eocene with peak generation between 18 and 15 Ma. Eocene source rocks started HC generation ca. 25 Ma ago between 50 and 100 km southeast of the ESM and reached the oil to wet gas window at present day. However, until today they have converted less than 20% of their initial kerogen. Although the Miocene source rocks are mostly immature, Oligocene source rocks lie within the oil window in the southern Levant Basin and reached the onset of the wet gas window in the northern Levant Basin. However, only 10%–20% of their initial kerogen have been transformed to date.     

Evidence for Strong Copper(I) Complexation by Organic Ligands in Seawater

Thiols like glutathione and cysteine form such stable complexes with copper(I) that they preclude the presence of copper(II). Conventionally seawater is titrated with copper(II) whilst monitoring the labile or reactive copper concentration by voltammetry or with other techniques, to determine the concentration of copper(II) binding complexing ligands in seawater. Titrations of seawater to which copper(I) binding ligands have been added reveal that the copper(I) binding ligands are detected when seawater is titrated with copper(II). The copper(II) in seawater is reduced to copper(I) within 2 to 40 minutes depending on the nature of the copper(I) binding ligand. The titrations of seawater with copper(II) thus give a response to the presence of copper(I) binding ligands indiscernible from that for copper(II) binding ligands. The stoichiometry of the detected apparent ligand concentrations for given concentrations of glutathione and cysteine suggest that 2 : 1 (thiol : Cu) complexes are formed. This was confirmed using voltammetry of free glutathione. Values of 21.2 and 22.2 were found for log _CuL for glutathione and cysteine respectively (for the reaction of Cu + 2L CuL₂). The complex stability is similar to that of natural organic species in the oceanic water column. The high stability of the copper(I) complexes was apparent from values of 32.1 and 32.6 for log Cu(I)L2 (for the reaction Cu⁺ + 2L CuL₂) for the copper(I) complexes with glutathione and cysteine in seawater. Glutathione and other thiols are common in the marine system including the water column. It is therefore possible that at least some of the ligands detected in seawater, and previously assumed to be copper(II) binding ligands, are in fact strongly complexed as copper(I). The copper(I) oxidation state may thus be stabilised in seawater.     

Bulk transfer velocity to and from natural and artificial surfaces

A wide set of published mass and heat transfer data is reviewed in terms of the stochastic renewal theory. A simple model is then proposed describing the transfer in terms of the fluid bulk properties. Two expressions are presented and they enable us to evaluate the bulk transfer velocity as a function of the turbulence of the flow for smooth and fully-rough surfaces in large ranges of Schmidt (or Prandtl) and Reynolds numbers. The transfer over transitional surfaces can also be evaluated by using a simple criterion for the choice of the right expression. The proposed relationships agree satisfactorily with data from laboratory and atmospheric measurements, for both solid and liquid surfaces.