基于电化学法的铬盐清洁生产工艺研究

现有铬盐生产技术阻碍了铬盐行业的清洁化发展,研发新型铬盐生产技术实属必要。中国科学院青海盐湖研究所自行研发出一套以电化学法为基础的铬盐清洁生产工艺,涵盖三条大工艺和四种母系铬盐产品。包括氢氧化钠溶液中电化学氧化铬铁制备铬酸钠联产三氧化二铬和三氧化二铁工艺,离子膜电解法从铬酸钠合成重铬酸钠工艺,以及离子膜电解法从重铬酸钠合成铬酸酐工艺。相比现有铬盐生产技术,该技术的优势主要体现在以下五点:温和化、去渣化、高值化、自动化和高效化。目前相关研发工作业已走出实验室,走过产业化中间试验,正向产业化示范线迈进。     

Spatiotemporal characteristics of Qinghai Lake ice phenology between 2000 and 2016

Journal of Geographical Sciences - Lake ice phenology is considered a sensitive indicator of regional climate change. We utilized time series information of this kind extracted from a series of...     

Water Cooperation Priorities in the Lancang-Mekong River Basin Based on Cooperative Events Since the Mekong River Commission Establishment

The Lancang-Mekong River has attracted much attention from researchers, but the cooperation on water issues in this river basin has been limited, even after the establishment of the Mekong River Commission(MRC). Cooperation on water resources has been determined as one of the key priority areas in the Lancang-Mekong Cooperation Mechanism, but there are no details of targets. In order to establish the priorities of water cooperation under the mechanism, we adopted nine categories to classify the objectives of 87 water cooperation events based on the ‘Lancang-Mekong Water Cooperative Events Database' from 1995 to 2015. Based on the occurrence of cooperative events, cooperative objectives, cooperative scales, and approaches to cooperation, we conducted statistical, correlation, and text analyses. Our analyses indicated the following results: under the impact of economic conditions inside and outside the river basin, full cooperation appeared more difficult than bilateral and multilateral cooperation. Each of the partners adopted different preferences for cooperation targets. Cooperation with more definite objectives was easier to establish than cooperation with broader and more complex objectives. The potential objectives for water cooperation were navigation, hydropower, joint management, data sharing, flood control and water use. Because hydropower development is controversial, and because water cooperation is avoided by most existing regional cooperation mechanisms due to its complexity, we suggest the following priority areas for water cooperation in the Lancang-Mekong River Basin. 1) Navigation and flood control/drought relief are attractive objectives for all the riparian countries across the whole watershed. 2) Data sharing should be a priority for cooperation in the watershed due to its laying the foundation for the equitable and reasonable utilization of transboundary waters. 3) Hydropower is an objective best implemented mainly through bilateral cooperation, and on tributaries.     

河套盆地北缘色尔滕山河流地貌参数特征及其成因分析

地貌形态是构造和地表过程相互作用的复杂产物,主要通过构造活动和岩石的抗侵蚀能力等来调节。构造活动相对较弱的古老造山带往往可以忽略构造驱动的岩石抬升,使得研究岩石抗侵蚀能力对其地貌雕刻的贡献成为可能。但是目前大多数活动造山带地貌研究的结果显示地貌主要受控于活动构造,关于岩性对地貌演化影响的报道较少。色尔滕山山前断裂为河套盆地北缘的一条重要控盆断裂,全新世以来该断裂的活动性较强,曾发生过两次较大震级地震（M6. 4和M5. 9）。前人活动构造研究表明该断裂的活动性具有空间差异,中部乌加河镇活动性最强,两端逐渐减弱。但相对河套盆地北缘其他大型断裂（如狼山山前断裂、乌拉山北缘断裂和大青山山前断裂）,该断裂的地貌参数研究较少。同时其地貌演化特征及发育机理仍然不清楚,这些均制约了对该断裂的变形动力学理解。本文基于30 m分辨率的DEM数据对该断裂进行详细的河流地貌学参数研究,包括使用Arcgis和Matlab脚本提取色尔滕山山前33条河流的子流域盆地面积 高程积分（HI）和相应河道陡峭指数（Ksn）、河道纵剖面及其裂点等地貌学参数。结果表明研究区河流HI值大部分处于0. 40~0. 66之间,其中乌加河镇附近具有高值,流域盆地处于发育的壮年期。瞬态河道和稳态河道均沿着色尔滕山山前断裂走向分布,可能表明色尔滕山山前大部分河道目前处于瞬时地貌向均衡地貌演化阶段,并且通过对比发现瞬态河道裂点成因存在岩性和构造共同控制的现象。河道陡峭指数空间分布差异性较大,乌加河镇附近（S13~S20）陡峭指数较大,向两边陡峭指数逐渐减小,在S8河流以西又有增大的趋势。通过结合岩性和降雨情况分析发现,河道陡峭指数除了受岩性抗侵蚀能力影响外,其分布还与色尔滕山山前断裂垂直滑移速率分布和垂直位错分布基本一致。综合来看,地貌参数的空间分布是岩性差异和色尔滕山山前断裂活动分段差异性共同控制的结果,表明该地区岩性和构造对地貌的协同塑造作用。     

海南岛4—9月短时强降水的天气型和环境参数特征

利用海南岛加密自动站逐小时降水资料、ERA5再分析资料,对海南岛短时强降水日环流配置进行了天气学分型,并进一步探讨了各天气型下海南岛短时强降水的时空分布、环流形势和关键环境参数特征。结果表明：(1)海南岛短时强降水有明显的日变化特征,呈单峰型,主要出现在15:00—19:00。(2)海南岛短时强降水的天气型主要有南海低压槽、华南沿海槽、西南低压槽和冷锋型。(3)南海低压槽、华南沿海槽、西南低压槽和冷锋型短时强降水分别占37%,31%,16%和16%。南海低压槽和华南沿海槽型主要出现在7、8和9月;西南低压槽型除9月外,其余各月份均可能出现;冷锋型绝大多数出现在4、5月。(4)南海低压槽和华南沿海槽型整层湿度条件都较好,不稳定能量较大,垂直风切变较弱。西南低压槽型不稳定能量较大,湿度条件一般,垂直风切变较弱。冷锋型存在明显的上干下湿特征,垂直风切变最大,0～6 km风速差75%分位大于10 m/s,不稳定能量最小。     

三维激光扫描单点定位精度评定方法研究

三维激光扫描技术是当前的一种新技术,其仪器的精度评定方法还不完善,提出两种三维激光扫描单点定位精度评价方法,即外部符合精度评价方法和内部符合精度评价方法。介绍了两种方案的实施过程,并且通过实验进行了分析,得到了较好的评价结果。     

一种用于下放式ADCP的TVC增益补偿控制策略

讨论了下放式ADCP信号接收过程中的TVC增益补偿控制策略.结合下放式ADCP的工作特点,从能量节约的角度采取了同时测底测流的工作模式.针对此种工作模式,提出了按区间分段的TVC增益补偿控制策略.通过声呐方程和TVC距离一增益模型分析,进行了MATLAB仿真验证,并针对可能出现的问题,提出了以相关函数等效电压作为判据的解决方法.     

SZF型方位传感器方位定标测试方法

文中简要介绍了SZF型方位传感器的主要组成及工作原理,针对方位传感器在实验室内如何定标与测试给出了行之有效的计算机自差校正方案及实施方法,经过了大量的实际应用,该方法已经成为SZF型传感器的定标测试过程的重要步骤.     

正交解调及复自相关频率估计在海流测量中的应用

正交解调技术在使用复自相关算法进行频率估计中具有非常重要的作用,简要介绍了正交解调技术和复自相关算法在声学多普勒海流计中的应用.     

Environmental evolution of Gongwang Mountains during Holocene in northeastern Yunnan, China

This paper presents the study on two continuous glacio-lacustrine sedimentary deposits, Laotanfang （3 597 m） and Shibantang （3 689 m） located on the southern and northern sides of Hulifang peak in Yunan, China. Environmental change indexes are constructed for each deposit, based on grain size, geochemical and pollen analysis, environmental magnetic susceptibility, and 14C dating. The study of climatic environmental change since the Holocene epoch in this region shows that the climate fluctuated at different stages during the early Holocene, that is, the climate was cool and wet during 8.4-7. 7r ka, cold and wet during 7.7-6. 5 ka, cold and dry during 6. 5-4.7 ka, cool and wet during 4.7-2. 1 ka, warm and wet during 2. 1-1.0 ka, and warmer and wet since 1 ka. These findings reflect the overlapping influences of the southwest and southeast monsoons in different times during the Holocene in the north part of southwestern China are in accord with other Holocene climate change models in this part of China.