Raman scattering study of the high-temperature vibrational properties and stability of CaGeO3 perovskite

The vibrational properties of metastable Ca-GeO₃ perovskite are investigated as a function of temperature using Raman scattering. Mode-assignments are derived from polarized spectra of optically oriented single crystals. Neither symmetry-breaking structural transformations nor soft-mode behavior is revealed in the Raman spectra between room temperature and 650° C. Only a small decrease in the local static octahedral tilt angles can be inferred from the Raman data over this temperature range. A Landau extrapolation of the lowest frequency A_g modes suggests that these modes become critical near 2000° C, a temperature that is above the extrapolated zero pressure melting point.     

Measurements of flow over an elongated ridge and its thermal stability dependence: The mean field

Measurements of mean wind flow and turbulence parameters have been made over Cooper's Ridge, a 115 m high elongated ridge with low surface roughness. This paper describes measurements of the streamwise and vertical variations in the mean field for a variety of atmospheric stability conditions. In near-neutral conditions, the normalised speedup over the ridge compares well with measurements from Askervein (Mickleet al., 1988). The near-neutral results are also compared to an analytical flow model based on that of Huntet al. (1988a). Measured streamwise variations show less deceleration at the foot of the hill and slightly more acceleration at the crest of the hill than does the model. In non-neutral conditions, the speedup over the ridge reduces slightly in unstable conditions and increases by up to a factor of two in stable conditions. The model is modified to allow boundary-layer stability to change the upwind wind profile and the depths of the inner and middle layers. Such a modification is shown to describe the observations of speedup well in unstable and weakly stable conditions but to overestimate the speedup in moderate to strongly stable conditions. This disagreement can be traced to the model's overestimation of the upstream scaling velocity at the height of the middle layer through its use of a stable wind profile form which has greater shear than that of the observed profiles, in possible combination with the three-dimensionality of the ridge which would allow enhanced flow around, rather than over, the feature in more stable conditions.     

A surface instability detection apparatus

Summary A surface instability detection apparatus for investigating axial splitting and spalling phenomena in rocks and rock-like materials is described. The apparatus simulates the conditions under which these phenomena occur and allows one to accurately measure them. Experimental results from tests on Berea sandstone are presented where the successive formation of spalling fractures was monitored with an acoustic emission system and the location of the seismic events was mapped. The test results show the potential for benchmark tests in determining the spalling tendency and characteristics of different rocks.     

Couplage des équations de transfert de masse et des lois d''interactions solution-solide par l''utilisation des lanthanides comme traceurs — Approche expérimentale

In underground flow tracing studies, the estimation of the nature and the importance of interactions undergone by the substance used very often constitutes an obstacle to good modeling of mass-transfer processes in solution.

We propose a method to quantify these phenomena by the use of lanthanides as tracers.

For this study, we set up an analytical methodology adapted to routine measurements. The quality of five lanthanides as indicators has been examined. We have demonstrated the formation, by substitution, of a carbonate complex which is extremely stable in the natural environment. The field experiments carried out demonstrated the efficiency of those tracers and confirmed their great stability.

Tracer recovery graphs show that, in accord with our hypothesis, convection and dispersion are identical for all the lanthanide elements. Moreover, we have established a direct relation between their fixing rate on earth materials and the value of their stability constants.

Thus, we demonstrate the possibility of correlative multitracing, with known and quantifiable interelement relations.

Résumé

Dans les études de circulations souterraines par traceur, l'estimation de la nature et de l'importance des interactions subies par la substance utilisée constitue, bien souvent, un obstacle à une bonne modélisation des processus de transfert de masse en solution.

Nous proposons une méthode de quantification de ces phénomènes par l'utilisation des lanthanides comme traceurs.

Pour cette étude, nous avons mis au point une méthodologie analytique adaptée aux mesures de routine. Les qualités, en tant qu'indicateurs, de cinq lanthanides ont été examinées. Nous avons démontré la formation, par substitution, d'un complexe carbonaté extrèment stable en milieu naturel. Les expériences de terrain réalisées ont prouvé l'efficacité de ces traceurs et confirmé leur grande stabilité.

Les courbes de restitution obtenues ont montré que, conformément à nos hypothèses, la convection et la dispersion sont identiques pour l'ensemble de ces éléments. De plus, il a été établi une relation directe entre leurs taux de fixation sur le terrain et la valeur de leurs constantes de stabilité.

On dispose ainsi d'une possibilité de multitraçage corrélatif, avec des relations interélémentaires connues et quantifiables.     

Contribution à la surveillance de l'activité de l'Etna à partir de l'étude des zones fumerolliennes

Resume La convection de la vapeur d'eau formée en profondeur dans une zone fumerollienne crée en surface une anomalie hydrique, thermique et électrique, cette dernière pouvant être la plus sensible à une variation de l'activité thermique profonde. L'amplitude des anomalies dépend de la position du site par rapport à la configuration de l'activité magmatique, mais aussi des conditions hydrogéologiques locales. La surveillance spatiale et temporelle des éruptions à partir du phénomène convectif hydrique doit tenir compte de ces conditions.

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The water steam convection existing below a fumarolic area creates hydraulic, thermal and electric anomalies, the electric anomaly being probably the most correlated to a change of the deep thermal activity. The anomaly range depends on the position of the site connected with the configuration of the magmatic activity, but also on the local hydrogeologic conditions. The spatial and temporal surveillance of the eruptions based on these convective data should take into consideration these conditions.