Estimation of unrecorded groundwater abstractions in Jordan through regional groundwater modelling

Jordan suffers from water scarcity and groundwater covers the majority of Jordan’s water supply. Therefore, there is an urgent need to manage this resource conscientiously. A regional numerical groundwater flow model, developed as part of a decision support system for the country of Jordan, allows for quantification of the overexploitation of groundwater resources and enables determination of the extent of unrecorded agricultural groundwater abstraction. Groundwater in Jordan is abstracted from three main aquifers partly separated by aquitards. With updated geological, structural, and hydrogeological data available in the country, a regional numerical groundwater flow model for the whole of Jordan and the southernmost part of Syria was developed using MODFLOW. It was first calibrated for a steady-state condition using data from the 1960s, when groundwater abstraction was negligible. After transient calibration using groundwater level measurements from all aquifers, model results reproduce the large groundwater-level declines experienced in the last decades, which have led to the drying out of numerous springs. They show a reversal of groundwater flow directions in some regions, due to over-abstraction, and demonstrate that documented abstractions are not sufficient to cause the observed groundwater-level decline. Only after considering irrigation water demand derived from remote sensing data, the model is able to simulate these declines. Illegal abstractions can be quantified and predictive scenarios show the potential impact of different management strategies on future groundwater resources.

     

Neoproterozoic Volhynia-Brest magmatic province in the western East European craton: Within-plate magmatism in an ancient suture zone

The reasons for the isotopic and geochemical heterogeneity of magmatism of the Neoproterozoic large Volhynia-Brest igneous province (VBP) are considered. The province was formed at 550 Ma in response to the break up of the Rodinia supercontinent and extends along the western margin of the East European craton, being discordant to the Paleoproterozoic mobile zone that separates Sarmatia and Fennoscandia and the Mesoproterozoic Volhynia-Orsha aulacogen. The basalts of VBP show prominent spatiotemporal geochemical zoning. Based on petrographic, mineralogical, geochemical, and isotopic data, the following types of basalts can be distinguished: olivine-normative subalkaline basalts consisting of low-Ti (sLT, < 1.10–2.0 wt % TiO₂; ε_Nd(550) from ?6.6 to ?2.7) and medium-Ti (sMT, 2.0–3.0 wt % TiO₂, occasionally up to 3.6 wt % TiO₂; ε_Nd(550) from ?3.55 to + 0.6) varieties; normal quartz-normative basalts (tholeiites) including low-Ti (tLT, < 1.75–2.0 wt % TiO₂) and medium-to-high-Ti (tHT1, 2.0–3.6 wt % TiO₂, ε_Nd(550) from ?1.3 to + 1.0) varieties. The hypabyssal bodies are made up of subalkaline low-Ti olivine dolerites (LT, 1.2–1.5 wt % TiO₂; ε_Nd(550) = ?5.8) and subalkaline high-Ti olivine gabbrodolerites (HT2, 3.0–4.5 wt % TiO₂; ε_Nd(550) = ?2.5). Felsic rocks of VBP are classed as volcanic rocks of normal (andesidacites, dacites, and rhyodacites) and subalkaline (trachyrhyodacites) series with TiO₂ 0.72–0.77 wt% and ε_Nd(550) of ?12. The central part of VBP is underlain by a Paleoproterozoic domain formed by continent-arc accretion and contains widespread sills of HT2 dolerites and lavas of LT basalts; the northern part of the province is underlain by the juvenile Paleoproterozoic crust dominated by MT and HT1 basalts. MT and LT basalts underwent significant AFC-style upper crustal contamination. During their long residence in the upper crustal magmatic chambers, the basaltic melts fractionated and caused notable heating of the wall rocks and, correspondingly, nonmodal melting of the upper crustal protolith containing high-Rb phase (biotite), thus producing the most felsic rocks of the province. The basalts of VBP were derived from geochemically different sources: probably, the lithosphere and a deep-seated plume (PREMA type). The HT2 dolerites were generated mainly from a lithospheric source: by 3–4% melting of the geochemically enriched garnet lherzolite mantle. LT dolerites were obtained by partial melting of the modally metasomatized mantle containing volatile-bearing phases. The concepts of VBP formation were summarized in the model of three-stage plume-lithosphere interaction.     

Comparison of 2D versus 3D modeling approaches for the analysis of the concrete faced rock‐fill Cokal Dam

This paper's primary purpose is to compare the 2D and 3D analysis methodologies in investigating the performance of a concrete faced rock‐fill dams under dynamic loading conditions. The state of stress on the face plate was obtained in both cases using a total strain based crack model to predict the spreading of cracks on the plate and the corresponding crack widths. Results of the 2D and 3D analyses agree well. Although significantly more demanding, 3D analyses have the advantage of predicting the following: (i) the opening of the vertical construction joints; (ii) the cracking at the valley sides; and (iii) the crushing of the plate during the seismic action. During the earthquake loading, the cracking predicted at the base of the face plate after the impounding spread significantly towards the crest of the dam; however, the crack widths are obtained relatively small. Crushing of the face plates at the construction joints is the primary cause of the large scale cracking predicted on the face plate for high intensity earthquakes. Earthquake induced permanent deformation of the fill increases the compressive stresses on the face plate, thereby reducing the minute cracking on the plate. However, this effect also leads to significant increases in the residual openings at the construction joints and at the plinth level. Copyright © 2013 John Wiley & Sons, Ltd.     

Stable isotope evidence for the atmospheric origin of CO2 involved in carbonation of MSWI bottom ash

Stable isotopes were used to constrain the origin of CO₂ involved in the ageing process of municipal solid waste incineration (MSWI) bottom ash under open-air conditions. The δ¹³C and δ¹⁸O values of CaCO₃ occurring in MSWI bottom ash samples of variable age and the δ¹³C of the residual organic matter content were measured, and laboratory assessments made of the isotopic fractionation accompanying CaCO₃ neo-formation during accelerated carbonation experiments of bottom ash or pure lime with atmospheric or industrial CO₂. The results indicate that stable isotopic compositions exhibited by fresh and aged bottom ash samples reflect non-equilibrium processes resembling those described in the carbonation of concrete and mortar. They also lead to conclusions on the prevalent involvement of atmospheric CO₂ in the open-air carbonation of MSWI bottom ash.     

Rothenberg scoria cone,East Eifel: a complex Strombolian and phreatomagmatic volcano

Rothenberg scoria cone Eifel formed by an alternation of three Strombolian and three phreatomagmatic eruptive phases. Eruptions took place from up to six vents on a 600 m-long fissure, building an early tuff ring and then two coalescing scoria cones. Strombolian volcanism dominated volumetrically, as the supply of external water was severely limited. Magma/water interaction only occurred during the opening stages of eruption at any vent, when discharge rates were low and the fragmentation surface was below the water table. The phreatomagmatic deposits consist of relatively well-sorted fall beds and only minor surge deposits. They contain juvenile clasts with a wide range of vesicularity and grain size, implying considerable heterogeneity in the assemblage of material ejected by the phreatomagmatic explosions. the transition from phreatomagmatic to Strombolian eruption at any vent was rapid and irreversible, and Strombolian volcanism persisted even when eruption rates are inferred to have waned at the close of each eruptive phase as, by then, the fragmentation surfaces were high in the growing cones and water was denied access to the magma. The Strombolian deposits are relatively homogenous, consisting of alternating coarser- and finer-grained, well-sorted fall beds erupted during periods of open-vent eruption and partial blockage of the vent respectively. The intervals of Strombolian eruption were always a delicate balance between discharge of freely degassing magma and processes such as ponding of degassed magma in the vent, collapse of the growing cones, and repeated recycling of clasts through the vent. Clear evidence of the instability of the Rothenberg cones is preserved in numerous unconformities within deposits of the inner walls of the cones. The close of Strombolian phases was probably marked by a decreasing supply of magma to the vents accompanied by ponding and stagnation of lava in the craters.     

The concentration and distribution of dimethyl sulfide in the marine atmospheric boundary layer near the equator

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Hydrogeologic assessment of escalating groundwater exploitation in the Indus Basin, Pakistan

Groundwater development has contributed significantly to food security and reduction in poverty in Pakistan. Due to rapid population growth there has been a dramatic increase in the intensity of groundwater exploitation leading to declining water tables and deteriorating groundwater quality. In such prevailing conditions, the hydrogeological appraisal of escalating groundwater exploitation has become of paramount importance. Keeping this in view, a surface water–groundwater quantity and quality model was developed to assess future groundwater trends in the Rechna Doab (RD), a sub-catchment of the Indus River Basin. Scenario analysis shows that if dry conditions persist, there will be an overall decline in groundwater levels of around 10 m for the whole of RD during the next 25 years. The lower parts of RD with limited surface water supplies will undergo the highest decline in groundwater levels (10 to 20 m), which will make groundwater pumping very expensive for farmers. There is a high risk of groundwater salinization due to vertical upconing and lateral movement of highly saline groundwater into the fresh shallow aquifers in the upper parts of RD. If groundwater pumping is allowed to increase at the current rate, there will be an overall decline in groundwater salinity for the lower and middle parts of RD because of enhanced river leakage.     

A search for soft X-ray emission from stellar sources

With the soft X-ray detector (0.2–0.284 keV) aboard the Astronomical Netherlands Satellite (ANS) we have searched for X-ray emission from hot star coronae and peculiar stars. On Sirius ( CMa) and Capella ( Aur) X-ray emission has been measured at 6 and 5 level, respectively, above background. In all other cases the search revealed no evidence for soft X-ray emission. Upper limits to the luminosities of about 25 star coronae (main-sequence stars, (sub)giants, and supergiants) and of 4 peculiar stars ( Sco, Lyr, P Cyg, and Car) have been obtained.Paper presented at the COSPAR/IAU Symposium on Fast Transients in X-and Gamma-Rays, held at Varna, Bulgaria, 29–31 May, 1975.     

Thermal and topographic tests of Europa chaos formation models from Galileo E15 observations

Stereo topography of an area near Tyre impact crater, Europa, reveals chaos regions characterised by marginal cliffs and domical topography, rising to 100-200 m above the background plains. The regions contain blocks which have both rotated and tilted. We tested two models of chaos formation: a hybrid diapir model, in which chaos topography is caused by thermal or compositional buoyancy, and block motion occurs due to the presence of near-surface (1-3 km) melt; and a melt-through model, in which chaos regions are caused by melting and refreezing of the ice shell. None of the hybrid diapir models tested generate any melt within 1-3 km of the surface, owing to the low surface temperature. A model of ocean refreezing following melt-through gives effective elastic thicknesses and ice shell thicknesses of 0.1-0.3 and 0.5-2 km, respectively. However, for such low shell thicknesses the refreezing model requires implausibly large lateral density contrasts (50-100 kg m⁻³) to explain the elevation of the centres of the chaos regions. Although a global equilibrium ice shell thickness of ≈2 km is possible if Europa's mantle resembles that of Io, it is unclear whether local melt-through events are energetically possible. Thus, neither of the models tested here gives a completely satisfactory explanation for the formation of chaos regions. We suggest that surface extrusion of warm ice may be an important component of chaos terrain formation, and demonstrate that such extrusion is possible for likely ice parameters.     

Metamorphic veining and mass transfer in a chemically closed system: a case study in Alpine metabauxites (western Vanoise)

In western Vanoise (French Alps), karstic pockets of Triassic‐to‐Jurassic metabauxites embedded in carbonate rocks and containing several generations of metamorphic veins were studied. During blueschist facies metamorphism, a cumulative amount of ～13 vol% of water is inferred to have been produced locally by successive dehydration reactions, and part of this fluid remained in the bauxitic lenses during most of the metamorphic cycle. Field and geochemical evidence show that these rocks have been isolated from large‐scale fluid flow (closed‐system behaviour). It is proposed that the internally derived fluid has promoted the opening of fluid‐filled open spaces (as attested by the euhedral habits of vein minerals) and served as medium for mass transfer from rock to vein. Indeed, the vein infill is obviously the result of chemical interactions, at the millimetre‐to‐centimetre scale, between the rock minerals and the locally produced aqueous fluid. Two vein types can be distinguished based on mineralogical and textural features: (i) some veins are filled with newly formed products of either prograde (chloritoid) or retrograde (chlorite) metamorphic reactions; in this case, fluid‐filled open spaces seem to offer energetically favourable nucleation/growth sites; (ii) the second vein type is infilled with cookeite or pyrophyllite, that were present in the host rock prior to the vein formation. In this closed chemical system, the components for the vein infill minerals have been transferred from rock to vein through the fluid, in a dissolution–transport–precipitation process, possibly stress‐assisted. These different vein generations all contain Al‐rich mineral infills, suggesting that Al was a mobile element (cm scale) during metamorphism. In these HP rocks, fluid flow may have been restricted, and if so mass transfer occurred by diffusion in an almost stagnant fluid. Metamorphic veins can be seen as witnesses of fluid and mass redistribution that partly accommodate the rock deformation (lateral segregation).