Melting equilibria in multicomponent systems and liquidus/solidus convergence in mantle peridotite

The melting of undepleted mantle peridotite proceeds through a temperature interval which decreases with increasing pressure. If liquidus and solidus actually meet in the range 100–150 Kb, as suggested by Herzberg (1983), peridotite must transform there directly to a melt of its own composition. Thermodynamic analysis shows that such a liquidus/solidus meeting would be very unlikely in a system as chemically complex as mantle peridotite and would require that unanticipated phase equilibrium relations suppress all incongruent melting behavior. But Takahashi and Scarfe's (1985) preliminary experiments suggest that the upper mantle itself may indeed have a special composition with respect to phase equilibrium relations between liquids and solids at very high pressure. If so, mantle peridotite composition cannot be generated as a crystal accumulate or melting residue, because these two popular theories of origin are difficult to reconcile with a supposed eutecticlike composition. If upper mantle peridotite were itself a solidified liquid composition produced either as a partial melt or, more likely, as a crystallization residue of some more primitive melt composition representative of the whole mantle, an approach of liquidus to solidus might be expected at high pressure although the phase relations of Herzberg (1983) and Herzberg and O'Hara (1985) remain implausible.     

A preliminary investigation into the use of ochre as a remedial amendment in arsenic-contaminated soils

Ochre is an unwanted waste product that accumulates in wetlands and streams draining abandoned coal and metal mines. A potential commercial use for ochre is to remediate As contaminated soil. Arsenic contaminated soil (605 mg kg⁻¹) was mixed with different ochres (A, B and C) in a mass ratio of 1:1 and shaken in 20 mL of deionised water. After 72 h As concentration in solution was ca. 500 μg kg⁻¹ in the control and 1–2.5 μg kg⁻¹ in the ochre treated experiments. In a second experiment soil:ochre mixtures of 0.05–1:1 were shaken in 20 mL of deionised water for 24 h. For Ochres A and C, as solution concentration was reduced to ca. 1 μg kg⁻¹ by 0.2–1:1 ochre:soil mixtures. For Ochre B, as concentration only reached ca. 1 μg kg⁻¹ in the 1:1 ochre:soil mix. Sorption of As was best modelled by a Freundlich isotherm using As sorption per mass of goethite in the ochre (log K = 1.64, n = 0.79, R² = 0.76, p 0.001). Efficiency of ochre in removing As from solution increased with increasing total Fe, goethite, citrate dithionite extractable Fe and surface area.     

Age and source material of the Kingash ultramafic-mafic massif,East Sayan

The REE distribution patterns and Nd whole-rock and mineral isotope ratios of the Kingash ultramafic-mafic massif enabled us to propose a multistage history for its evolution at 1410 and 875 Ma. These stages reflect the magmatic evolution of the Siberian paleocontinent margin during the Late Precambrian. The age of metamorphism of the massif during collision and accretion in the Early Paleozoic (∼500 Ma) was obtained based on a Sm-Nd mineral isochron from rheomorphic veined albitite. The Nd and Sr isotopic compositions of rocks from the Kingash massif suggest mantle sources for picritic and basic magmas, which are thought to have originated by mixing of different proportions of depleted (PREMA or DM) and enriched (EM) melts. The initial isotope ratios of the parental melts transformed during interaction with Sr-rich material from the host metasedimentary complexes.     

Estimating water balance components of tropical wetland lakes in the Pantanal dry season,Brazil

Abstract

Water balance studies with stable water isotopes have rarely been conducted in remote and tropical wetland areas. As such, little is known regarding the water balance and groundwater–surface water interaction in the Pantanal, one of the largest and most pristine wetlands in the world. We applied MINA TrêS, a water balance model utilizing stable water isotopes (δ¹⁸O, δ²H) and chloride (Cl^-) to assess the dry-season hydrological processes controlling groundwater–surface water interactions and the water balance of six floodplain lakes in the northern Pantanal, Brazil. Qualitatively, all lakes exhibited similarity in hydrological controls. Quantitatively, they differed significantly due to morphological differences in controlling groundwater inflow and lake volume. Our approach is readily transferable to other remote and tropical wetland systems with minimal data input requirements, which is useful in regions with sparse hydrometric monitoring.

Editor Z.W. Kundzewicz     

Uranium and lead gain of detrital zircon studied by isotopic analyses and fission-track mapping

Besides Pb and U loss and mixing of crystals of different age, U gain is considered a possible cause of discordant U-Pb ages of zircons. However, whether U gain without new zircon growth occurs in nature had not been proven, so far. In order to test this possibility, two detrital zircon populations were studied for which the absence of later zircon overgrowth after deposition could be demonstrated. The samples were separated from a metaquartzite near a large pegmatite body and from metaquartzite inclusions found in the pegmatite (Martell Valley, Italian Alps). The distribution of neutron-induced fission tracks reveals distinct accumulation of U in the rims of more than 90% of the zircon grains of the inclusions (total U in the crystals: 540–850 ppm), whereas in the country rock only some of the grains show similar but weaker patterns (total U: 155–320 ppm). From the isotopic data and from additional U-Pb and Rb-Sr analyses of minerals and whole-rock samples of the pegmatite, the marginal accumulation and the higher concentration of U in the zircon grains of the inclusions are interpreted as the result of episodic U gain during the intrusion of the pegmatite and/or during a later metamorphism. From the concentration levels of common Pb, an addition of Pb - and possibly other elements - to the zircon grains is inferred.     

A detection method of subrecent to recent tectonic activity in the anticlinal system of the northern Negev,Israel

Geomorphological and geophysical methods combined with borehole information were employed to search for possible subrecent small-scale vertical movement along the anticlinal fold belt of the central Negev, Israel. Such tectonic deformation might indicate displacement on the buried reverse faults underneath the anticlines. Variations in the thickness of the alluvial fill in the study area, which are in accordance with the fold structures, could be an indication of recent folding activity along the anticlinal system. In order to detect these thickness variations in the alluvial fill, seismic refraction and electrical resistivity measurements were carried out along the valley of Nahal Besor, which crosses the anticlinal belt. The thickness variations of the alluvial fill along the valley were not found to indicate any significant tectonic movement along the anticlines during the Pleistocene. The thickest alluvium was found overlying a karst bedrock, hence karst relief is suggested to be responsible for these variations.     

Longshore variations in nearshore wave processes at magilligan point,northern ireland

Magilligan Point is a recurved cuspate foreland at the mouth of Lough Foyle. Two wave regimes intersect in the estuary mouth and the manner of their interplay controls shoreline changes. Ocean swell waves from the N and NE are refracted around the recurve, losing both height and energy longshore. Width of the surf zone decreases and waves tend to steepen, although both these changes and wave refraction owe something to nearshore geometry. Angle of wave approach becomes more acute and a westerly flowing longshore current moves sand S and SW along the beach. Estuary waves from the S and SW are wind-driven with high-frequencies and steepnesses. They generate a northeasterly current which returns material N, but dies out as the waves become obliterated by nearshore attenuation and breaking of swell. It is possible to identify a time-averaged null-point where shoreline wave power is balanced, although this tends to shift over short periods causing rapid morphological changes. The existence of two independent, but counteractive cells ensures the long-term maintenance of the foreland, without requiring major or continuous supplies of fresh sediment.     

Variability in bedform morphology and kinematics with transport stage

Bedform geometry is widely recognized to be a function of transport stage. Bedform aspect ratio (height/length) increases with transport stage, reaches a maximum, then decreases as bedforms washout to a plane bed. Bedform migration rates are also linked to bedform geometry, in so far as smaller bedforms in coarser sediment tend to migrate faster than larger bedforms in finer sediment. However, how bedform morphology (height, length and shape) and kinematics (translation and deformation) change with transport stage and suspension have not been examined. A series of experiments is presented where initial flow depth and grain size were held constant and the transport stage was varied to produce bedload dominated, mixed‐load dominated and suspended‐load dominated conditions. The results show that the commonly observed pattern in bedform aspect ratio occurs because bedform height increases then decreases with transport stage, against a continuously increasing bedform length. Bedform size variability increased with transport stage, leading to less uniform bedform fields at higher transport stage. Total translation‐related and deformation‐related sediment fluxes all increased with transport stage. However, the relative contribution to the total flux changed. At the bedload dominated stage, translation‐related and deformation‐related flux contributed equally to the total flux. As the transport stage increased, the fraction of the total load contributed by translation increased and the fraction contributed by deformation declined because the bedforms got bigger and moved faster. At the suspended‐load dominated transport stage, the deformation flux increased and the translation flux decreased as a fraction of the total load, approaching one and zero, respectively, as bedforms washed out to a plane bed.