Sedimentation on the Ionian active margin (Hellenic arc) — Provenance of sediments and mechanisms of deposition

Lithological, sedimentological, mineralogical and faunal analyses of twenty cores from the western Peloponnesus margin and adjacent Matapan Trench permit the origin of the sediments and the processes of sedimentation to be defined in some detail.Except for the ash layers derived from the Ischian Province, the major part of the sediment is local in origin (Peloponnesus). Analyses of heavy, light and clay minerals enable three main provinces to be distinguished. Each of these provinces includes one or more slope basins and a portion of trench, without lateral connection between them and mixing of inputs.The diversity and complexity of sedimentary structures, the granulometric characters, the mixed fauna (molluscs and ostracods) and the variability of rates of sedimentation all testify to the prevalence of reworking phenomena and gravitative processes.These data confirm and elaborate on the model of sedimentation deduced from seismic studies in which sediments are successively trapped, released by the slope basins and transferred via channels and canyons towards the underlying trench basins. This “cascade feeding” appears characteristics of this subductive sedimentary environment.     

FORWARD MODELING IN THE FREQUENCY-SPACE DOMAIN*

Forward modeling of zero-offset data is performed in the frequency-space domain using a one-way extrapolation equation. The use of the frequency domain offers several advantages over conventional time domain methods. The greatest advantage of the frequency domain is that all time derivatives are evaluated exactly by a simple multiplication. Synthetic zero-offset sections are computed with a high degree of accuracy for arbitrary velocity and reflectivity structures. Examples are shown for realistic complicated models and compared with results from physical modeling.     

Tropospheric Ozone in a Global-Scale Three-Dimensional Lagrangian Model and Its Response to NOX Emission Controls

A three-dimensional Lagrangian tropospheric chemistry modelis used toinvestigate the impact of human activities on the tropospheric distributionofozone and hydroxyl radicals. The model describes the behaviour of 50 speciesincluding methane, carbon monoxide, oxides of nitrogen, sulphur dioxide andnineorganic compounds emitted from human activities and a range of other sources.Thechemical mechanism involves about 100 chemical reactions of which 16 arephotochemical reactions whose diurnal dependence is treated in full. The modelutilises a five minute chemistry time step and a three hour advection timestepfor the 50,000 air parcels. Meteorological data for the winds, temperatures,clouds and so on are taken from the UK Meteorological Office global model for1994 onwards. The impacts of a 50% reduction in European NO_Xemissions onglobal ozone concentrations are assessed. Surface ozoneconcentrations decrease in summertime and rise in wintertime, but to differentextents.     

A NEW APPROACH TO THE INVERSION OF SEISMIC DATA*

A new inversion method for seismic reflection data is based on impedance concepts and uses transformations to reduce the essentially non-linear problem to a linear eigenvalue formulation without approximation. A set of reflection data has been inverted using this method. The characteristic impedances of the layers so determined are compared with log data from a reference borehole.     

The effect of composition,temperature and pressure on the stability of the 1Tc and 2M polytypes of sapphirine

Microprobe analyses and structural characterisation by means of transmission electron microscopy and powder X-ray diffraction are presented for a suite of natural and synthetic sapphirines. Most sapphirines appear to consist of intergrowths of the common 2M polytype with minor amounts of the 1Tc phase, although the converse situation is found in some cases. Attempts to correlate the structural state of the mineral with other factors reveal that: (i) There is no strong relationship between mean tetrahedral cation radius or mean octahedral cation radius and the preferred polytype. The Tschermak substitution M²⁺M⁴⁺-M³⁺M³⁺ does not appreciably influence the 1Tc-2M equilibrium, (ii) However, the total content and mean oxidation state of iron in sapphirine are important in this respect. Fe²⁺ stabilises the 2M phase, whereas Fe³⁺ stabilises the 1Tc phase. (iii) P-T estimates for the host rocks, and estimates for the conditions of sapphirine crystallisation, where obtainable, suggest that the 1Tc phase is stable at lower T and higher P than the 2M phase. Some quantitative constraints are inferred.     

Stable carbon isotope variations in northwest Europe during the last glacial–interglacial transition

Stable carbon isotope data that span part of the last glacial–interglacial transition (ca. 14-9 ka ¹⁴C BP; ca. 15–11 ka cal. BP), and which derive from organ-specific plant macrofossils recovered from two lake sediment profiles in the UK and one in Norway, are compared. The recorded temporal variations show similar trends, which, over a millennial time-scale appear to parallel the main drift in δ¹⁸O as determined for the GRIP ice-core. It is postulated that some smaller scale variations in the δ¹³C profiles may reflect the shorter term oscillations in δ¹⁸O values evident in the GRIP record, although this is less certain. Overall, however, the results suggest that stable carbon isotope measurements based on organ-specific terrestrial plant macrofossils may provide (i) a means for establishing correlations between terrestrial successions and (ii) additional paleoenvironmental information, as the apparent ‘shadowing’ of the GRIP record indicates a common forcing mechanism for both Greenland δ¹⁸O and northwest European δ¹³C variations. From the evidence available we suggest that the recorded δ¹³C variations reflect fluctuations in air temperature and/or changes in water vapour pressure in the atmosphere. © 1997 John Wiley & Sons, Ltd.     

TEM study of a special grain boundary in a synthetic K-feldspar bicrystal: Manebach Twin

 A monoclinic KAlSi₃O₈ feldspar Manebach twin boundary was synthesized by diffusion bonding and examined using high-resolution transmission electron microscopy. The sharp (001) twin boundary is straight and free of strain. The boundary width is smaller than d₀₀₁. There is no rigid body shift observed at the twin boundary, and the feldspar structure is arranged symmetrically across (001). The twin boundary structure consists of bridged tetrahedral crankshafts, which are characteristic of the feldspar lattice. The grain boundary structure is in good agreement with the geometrical model of Taylor et al. (1934). The grain boundary composition of K_1/2H_1/2AlSi₃O₈ differs from their model. Received: 13 February 2002 / Accepted: 24 December 2002 Acknowledgements We thank M. Rühle, S. Hutt, J. Mayer, A. Strecker and U. Salzberger at MPI, Stuttgart, for their support and valuable advice in preparing TEM sections of bicrystals.     

Comparison of cell- and vertex-centered discretization methods for flow in a two-dimensional discrete-fracture–matrix system

Simulations of flow for a discrete-fracture model in fractured porous rocks have gradually become more practical, as a consequence of increased computer power and improved simulation and characterization techniques. Discrete-fracture models can be formulated in a lower-dimensional framework, where the fractures are modeled in a lower dimension than the matrix, or in an equi-dimensional form, where the fractures and the matrix have the same dimension.