Correspondence analysis applied to volcanic aerosols

A statistical analysis of volcanic aerosol based on 1,083 variables including concentration, grain-size and site variabilities establishes correlations between sites and among chemical elements.Variation curves of element concentration show parallel behaviour. High coefficients of correlation between anions and cations confirm associations between elements.     

The axial momentum balance of Earth and its fluid envelope

The emergence of greatly improved data sets over the past decade has heightened awareness of the close relationship between changes in the axial component of the angular momentum of the atmosphere and that of the solid Earth, the latter being reflected in small, though detectable, changes in the planet's rate of rotation. Changes in the large-scale wind field, and hence in atmospheric angular momentum, on intraseasonal through interannual time scales can be associated with a number of identifiable meteorological phenomena, whose further study has been given new impetus by the discovery of their signals in Earth's rotation. Future advances in the subject are apt to occur in connection with new data sets that will help address questions remaining about rapid changes in Earth rotation and the torques responsible for the momentum changes. Also in the coming decade, both new data and modeling approaches should help clarify the role of the oceanic portion of Earth's fluid envelope in the planetary momentum balance.     

New data on the Albian-Cenomanian radiolarians from the Karai Formation (South India)

Radiolarians from the lower part of the Karai Formation (upper Albian-middle Cenomanian) are studied in detail for the first time. Among over 50 radiolarian species identified in the formation, there are Acaeniotyle amplissima (Foreman), Savaryella novalensis (Squinabol), S. quadra (Foreman), Vitorfus campbelli Pessagno, Archaeodictyomitra montisserei (Squinabol), Holocryptocanium barbui Dumitrica, Pseudoeucyrtis sp. cf. Ps. spinosa (Squinabol), Stichomitra communis Squinabol, Tubilustrionella transmontanum (O’Dogherty), and others. The discovered radiolarians are divided into the Halesium triacanthum-Orbiculiforma nevadaenis (late Albian-early Cenomanian), Crucella latum-Cryptamphorella micropora (late Albian?-early Cenomanian), and Becus sp. B-Godia concava (terminal Albian-middle Cenomanian) assemblages. In general, the Albian-Cenomanian radiolarians of South India are comparatively less diverse than the concurrent assemblages of the Mediterranean region and California. In taxonomic composition and morphological peculiarities, they are comparable with the Aptian-Albian radiolarians of Western Australia (Ellis, 1993). Consequently it can be postulated that sea basins of South India were situated during the Albian-Cenomanian in the temperate latitudes of the Southern Hemisphere.     

Melanterite and szomolnokite as weathering products of pyrite from the Bazhenovo Formation

Weathering of pyrite in the core recovered from black shales of the Bazhenovo Formation (Upper Jurassic-Lower Cretaceous) in the West Siberian marine basin promoted the successive formation of melanterite (FeSO₄ · 7H₂O) and szomolnokite (FeSO₄ · H₂O). Szomolnokite was detected in West Siberia for the first time.     

Weathering of ilmenite from Chavara deposit and its comparison with Manavalakurichi placer ilmenite,southwestern India

The magnetic fractions of ilmenite from the beach placer deposit of Chavara, southwest India have been studied for mineralogical and chemical composition to assess the range of their physical and chemical variations with weathering. Chavara deposit represents a highly weathered and relatively homogenous concentration. Significant variation in composition has been documented with alteration. The most magnetic of the fractions of ilmenite, separated at 0.15 Å, and with a susceptibility of 3.2 × 10^?6 m³ kg^?1, indicates the presence of haematite–ilmenite intergrowth. An iron-poor, titanium-rich component of the ilmenite ore has been identified from among the magnetic fractions of the Chavara ilmenite albeit with an undesirably high Nb₂O₅ (0.28%), Cr₂O₃ (0.23%) and Th (149 ppm) contents. The ilmenite from Chavara is compared with that from the nearby Manavalakurichi deposit of similar geological setting and provenance. The lower ferrous iron oxide (2.32–14.22%) and higher TiO₂ (56.31–66.45%) contents highlight the advanced state of alteration of Chavara. This is also evidenced by the relatively higher Fe³⁺/Fe²⁺ ratio compared to Manavalakurichi ilmenite. In fact, the ilmenite has significantly been converted to pseudorutile/leucoxene.     

3d transition metal L-edge X-ray absorption studies of the dichalcogenides of Fe, Co and Ni

The X-ray absorption spectra of the transition metal L_3,2-edges of the dichalcogenides FeS₂ (pyrite), FeSe₂, FeTe₂, CoS₂, CoSe₂, CoTe₂, NiS₂, NiSe₂ and NiTe₂ have been studied. These spectra are compared with theoretical simulations make using the atomic multiplet approach assuming on octahedral site for the metal atoms. The Ni spectra can be closely simulated using this approach but the Fe and Co spectra show less good fits to the experimental data. The reasons for this and its implications for the use of L-edge spectra in the study of such minerals are discussed in terms of the covalency and the ground states of the compounds; these results indicate the mixing of the ground states increases in the order Ni<Co<Fe.