Adsorptive Separation of 1, 2‐Dichloroethane from Model Wastewater by Natural Clinoptilolite

The adsorptive separation of 1, 2‐dichloroethane from model wastewater by different Slovak natural and octadecylammonium‐modified clinoptilolites has been studied. It was found that the 1, 2‐dichloroethane will be adsorbed by natural as well as by surfactant‐modified clinoptilolites; all clinoptilolites have a similar adsorption loading. There was also no remarkable difference between the natural and surfactant‐modified clinoptilolites in respect to the adsorption kinetics.     

Bridging Political Expectations and Scientific Limitations in Climate Risk Management – On the Uncertain Effects of International Carbon Sink Policies*

Despite great advances in carbon cycle research during the past decade the climatic impact of terrestrial ecosystems is still highly uncertain. Although contemporary studies suggest that the terrestrial biosphere has acted as a net sink to atmospheric carbon during the past two decades, the future role of terrestrial carbon pools is most difficult to foresee. When land use change and forestry activities were included into the Kyoto Protocol in 1997, the requirements for scientific precision increased significantly. At the same time the political expectations of carbon sequestration as climate mitigation strategy added uncertainties of a social kind to the study of land-atmosphere carbon exchange that have been difficult to address by conventional scientific methods. In this paper I explore how the failure to take into account the effects of direct human activity in scientific projections of future terrestrial carbon storage has resulted in a simplified appreciation of the risks embedded in a global carbon sequestration scheme. I argue that the social limits to scientific analysis must be addressed in order to accommodate these risks in future climate governance and to enable continued scientific authority in the international climate regime.     

Depositional rates and dating techniques of modern deposits in the Brno reservoir (Czech Republic) during the last 70 years

Facies analysis, magnetic susceptibility, and analysis of grain size, TOC content and isotopes (¹³⁷Cs, ²¹⁰Pb, ²²⁶Ra, ²²⁸Ra, and ²³⁸U concentrations) were used to determine the history of the modern deposits of the Brno reservoir. The sedimentary succession can be subdivided into two main units. The lower unit is formed predominantly by medium- to coarse-grained silty sands and is interpreted as a fluvial succession deposited before the Svratka River was dammed. The upper unit consists of brownish planar laminated silts and rarely of clayey or sandy silts and is interpreted as a product of the reservoir deposition. The concentrations of ²³⁸U reflect the history of uranium mining in the upper part of the Svratka River catchment. As a consequence, ²¹⁰Pb radionuclide concentrations cannot be used for establishing a sediment chronology. Concentrations of ¹³⁷Cs show two marked peaks, the upper of which is attributed to the Chernobyl reactor accident in 1986, and the lower one is attributed to the maximum rate of atomic weapons testing in 1963. From these peaks, mean depositional rates of 3.2 cm year⁻¹ for the time period of 1986–2007 and of 3.4 cm year⁻¹ between 1963 and 1986 are calculated. Based on the known age of the reservoir, which was constructed in 1939, we can also calculate mean depositional rate for the time period of 1939–1963, which is 3.1 cm year⁻¹.     

Interpreting maps through the eyes of expert and novice users

The experiments described in this article combine response time measurements and eye movement data to gain insight into the users' cognitive processes while working with dynamic and interactive maps. Experts and novices participated in a user study with a ‘between user’ design. Twenty screen maps were presented in a random order to each participant, on which he had to execute a visual search. The combined information of the button actions and eye tracker reveals that both user groups showed a similar pattern in the time intervals needed to locate the subsequent names. From this pattern, information about the users' cognitive load could be derived: use of working memory, learning effect and so on. Moreover, the response times also showed that experts were significantly faster in finding the names in the map image. This is further explained by the eye movement metrics: experts had significantly shorter fixations and more fixations per second meaning that they could interpret a larger part of the map in the same amount of time. As a consequence, they could locate objects in the map image more efficiently and thus faster.     

The Košice meteorite fall: Recovery and strewn field

We provide the circumstances and details of the fireball observation, search expeditions, recovery, strewn field, and physical characteristics of the Ko?ice meteorite that fell in Slovakia on February 28, 2010. The meteorite was only the 15th case of an observed bolide with a recovered mass and subsequent orbit determination. Despite multiple eyewitness reports of the bolide, only three videos from security cameras in Hungary were used for the strewn field determination and orbit computation. Multiple expeditions of professionals and individual searchers found 218 fragments with total weight of 11.3 kg. The strewn field with the size of 5 × 3 km is characterized with respect to the space distribution of the fragments, their mass and size‐frequency distribution. This work describes a catalog of 78 fragments, mass, size, volume, fusion crust, names of discoverers, geographic location, and time of discovery, which represents the most complex study of a fresh meteorite fall. From the analytical results, we classified the Ko?ice meteorite as an ordinary H5 chondrite.     

Weighted Pivot Coordinates for Compositional Data and Their Application to Geochemical Mapping

The log ratio methodology converts compositional data, such as concentrations of chemical elements in a rock, from their original Aitchison geometry to interpretable real orthonormal coordinates, thereby allowing meaningful statistical processing and visualization. However, it must be taken into account that the original concentrations can be flawed by detection limit or imprecision problems that can severely affect the resulting coordinates. This paper aims to construct such orthonormal log ratio coordinates, called weighted pivot coordinates, that capture the relevant relative information about an original component and treat the redundant information in a controlled manner. Theoretical developments are supported by a thorough simulation study. Weighted pivot coordinates are then applied to the geochemical mapping of catchment outlet sediments from the National Geochemical Survey of Australia illustrating their advantage over possible alternatives.     

Normalized evaluation of the performance,capacity and availability of catalogue services: a pilot study based on INfrastruture for SPatial InfoRmation in Europe

Geographic information has a great potential to be re-used when supported by mechanisms for its discovery. Above all, the quality of a catalogue service is the key feature supporting users in the discovery process. So far, there have been in existence various methodologies dealing with the normalized evaluation of quality with respect to catalogue services. Their biggest weakness seems to be in the depth of quality testing, i.e. some influences are beyond the scope of evaluation of these methodologies with respect to quality in catalogue services. In this study, the quality of 45 catalogue services across Europe was verified with the proposed normalized evaluation methodology originating from documents within the INfrastruture for SPatial InfoRmation in Europe (INSPIRE) framework. This paper discusses the (statistical) influence of factors that may significantly change the results of catalogue service testing. The proposals for improving the existing INSPIRE normalized evaluation procedure are applicable for any spatial data infrastructure and/or Digital Earth component using the Open Geospatial Consortium Catalogue Service for the Web as a basis.