Fluid production rate during the regional metamorphism of a pelitic schist

Phase equilibria modeling of the pressure–temperature (P–T) path of regional metamorphism and associated fluid expulsion, combined with constraints on the timescale of garnet growth by Sm–Nd geochronology, elucidates the fluid production rate and fluid flux during Barrovian metamorphism of pelitic rocks from Townshend Dam, VT, USA. This modeling builds on a published companion study that utilized Sm–Nd geochronology of concentric growth zones in multiple garnet grains, to constrain the duration of garnet growth in a large sample of schist at Townshend Dam to 3.8?±?2.2 million years (Gatewood et al., Chem Geol 401:151–168, 2015). P–T pseudosections combined with observed mineral compositions constrain garnet growth conditions, and were utilized to construct P–T path-dependent thermodynamic forward models. These models determine that garnet growth was initiated at ~?0.6 GPa and ~?525 °C, with a roughly linear loading and heating P–T trajectory to >?0.8 GPa and ~?610 °C. Loading and heating rates of 2.4 km·Myear^?1 (with a range of 1.6 to 5.8 km·million year^?1) and 23 °C·million year^?1 (with a range of 14 to 54 °C·million year^?1), respectively, are consistent with model estimates and chronologic constraints for tectono-metamorphic rates during orogenesis. Phase equilibria modeling also constrains the amount of water release during garnet growth to be ~?0.7 wt% (or >?2 vol%), largely resulting from the complete consumption of chlorite. Coupling this estimate with calculated garnet growth durations provides a fluid production rate of 5.2 kg·m^?3·million year^?1 (with a range of 3.2 to 12.2 kg·m^?3·million year^?1) and when integrated over the overlying crustal column, a regional-scale fluid flux of 0.07–0.37 kg·m^?2·million year^?1. This range of values is consistent with those derived by numerical models and theory for regional-scale, pervasive fluid flow. This study signifies the first derivation of a fluid production rate and fluid flux in regional metamorphism using a direct chronology of water-producing (garnet-forming) reactions and can provide a framework for future studies on elucidating the nature and timescales of fluid release.     

Snow measurement by GPS interferometric reflectometry: an evaluation at Niwot Ridge,Colorado

Snow is a critical storage component in the hydrologic cycle, but current measurement networks are sparse. In addition, the heterogeneity of snow requires surveying larger areas to measure the areal average. We presented snow measurements using GPS interferometric reflectometry (GPS‐IR). GPS‐IR measures a large area (~100 m²), and existing GPS installations around the world have the potential to expand existing snow measurement networks. GPS‐IR uses a standard, geodetic GPS installation to measure the snow surface via the reflected component of the signal. We reported GPS‐IR snow depth measurements made at Niwot Ridge, Colorado, from October 2009 through June 2010. This site is in a topographic saddle at 3500 m elevation with a peak snow depth of 1.7 m near the GPS antenna. GPS‐IR measurements are compared with biweekly snow surveys, a continuously operating scanning laser system and an airborne light detection and ranging (LIDAR) measurement. The GPS‐IR measurement of peak snowpack (1.36–1.76 m) matches manual measurements (0.95–1.7 m) and the scanning laser (1.16 m). GPS‐IR has RMS error of 13 cm (bias = 10 cm) compared with the laser, although differences between the measurement locations make comparison imprecise. Over the melt season, when the snowpack is more homogenous, the difference between the GPS‐IR and the laser is reduced (RMS = 9 cm, bias = 6 cm). In other locations, the GPS and the LIDAR agree on which areas have more or less snow, but the GPS estimates more snow on the ground on tracks to the west (1.58 m) than the LIDAR (1.14 m). Copyright © 2011 John Wiley & Sons, Ltd.     

Logjams as a driver of transient storage in a mountain stream

We use four stream segments along a wood-rich, pool–riffle mountain stream in the Southern Rockies of Colorado, USA to examine how spatial variations in wood load and variations in discharge during and after the snowmelt peak flow influence the magnitude of surface and subsurface transient storage. Segments range in complexity from a single channel with no large wood to an anabranching channel with closely spaced, channel-spanning logjams. Discharges at which transient storage was assessed range from base flow to snowmelt peak flow. To explore these relations, we used 10 geomorphic variables representing channel morphology and bed substrate, four wood-related variables representing wood load and associated backwater storage, and two measures of skewness from instream and bulk electrical conductivity breakthrough curves during tracer tests. Instream curves reflect surface and subsurface transient storage, whereas bulk curves primarily represent subsurface transient storage. Higher values of skewness indicate greater retention, and we used the values here as a metric of increased transient storage. Although limited sample size restricts the power of our results, our findings suggest that stream segments with greater instream large wood loads have more and larger pools, greater storage of fine sediment and particulate organic matter, and higher values of skew from instream conductivity. The results also suggest that the presence of instream wood, rather than changes in channel morphology associated with wood, is the most important driver of transient storage. This implies that river management designed to foster transient storage should focus on retaining instream large wood. We did not find significant correlations between geomorphic or wood-related variables and the skew estimated from bulk conductivity, which may reflect the relatively thin alluvium present in the field area and the prevalence of surface transient storage in this system.     

Arsenic contamination of lake sediments in Florida: evidence of herbicide mobility from watershed soils

Organic arsenical herbicides, which include monosodium methylarsonate (MSMA), have been applied to golf courses and lawns throughout Florida, USA, since the 1950s. These products convert rapidly to inorganic forms of arsenic (As) in soils and are mobilized readily. Leachates have been known to contaminate groundwater and surface waters, although past studies have not examined whether use of these products has led to significant As accumulation in lake sediments. We used paleolimnological methods to document the depositional history and inventories of total As in sediments and porewaters of Little Lake Jackson in Florida, which is adjacent to three golf courses. Six sediment cores, four of which were ²¹⁰Pb dated, showed porewater total As concentrations as high as 435 μg l⁻¹, and dry-sediment total As concentrations as high as 148 mg kg⁻¹. Approximately 537 kg of total As is present in >19,000 metric tons of sediment (dry mass), and an additional 18 kg of As is dissolved in 10.8 × 10⁴ m³ of porewaters. Total As content in surface sediments (mean = 47.3 mg kg⁻¹) exceeds the consensus-based sedimentary concentration for probable toxicity effects in freshwater benthic fauna. Surface and subsurface waters flow to the lake from topographically higher areas to the west, where golf courses and residential areas are located. Total As concentrations were elevated highly in monitoring wells and in a stream that flows between the golf courses and lake, but As was below detection limits in wells that were located at the distal perimeter of the golf courses. Subsurface and surface waters exit the lake towards topographically lower areas to the east. Nearly all As in sediments remains bound in the solid phase, indicating that As sedimentary profiles largely reflect depositional history. Sedimentary As concentrations are correlated strongly with aluminum and iron, which suggests that As was scavenged from lake waters during the past. Sedimentary As concentrations increased until the 1980s, then declined somewhat to the present time. Dissolved As was scavenged efficiently from the water column when hypolimnetic waters were oxygenated persistently, but after eutrophication led to a seasonally anoxic hypolimnion in the 1980s, apparently less As was co-precipitated, and more was lost to hydrological outflow. Arsenic accumulation in sediments might be common in areas where As derived from organic arsenical herbicide applications is directed by shallow water tables towards adjacent lakes.