Estimating Pile Set-up Using 24-h Restrike Resistance and Computed Static Capacity for PPC Piles Driven in Soft Lousiana Coastal Deposits

In this paper, the CPT-based predicted ultimate pile resistances (R_p) were compared with the measured pile resistances (R_m) at different elapsed time for the piles driven into saturated soft clays where piles displayed significant set-up effect. The measured pile resistances were based on 115 restrike records collected from 95 production piles, and 74 records of 9 tested piles. The predicted ultimate pile resistances were calculated from the LCPC, the Schmertmann, and the de Ruiter–Beringen methods, respectively. With the significant pile set-up effect taken into account, the relationship between measured resistances and predicted capacities at different times after pile installation were investigated. The ratios of the measured pile resistances to the predicted capacities scattered in a large spectrum. The ratios fluctuated and stayed within a range of 0.6–1.6 for different CPT methods since end of initial driving until more than 2 months after pile installation. Plots of the ratios versus the predicted pile capacities using different CPT methods have revealed that the ratio (R_m/R_p) presented a strong dependence on the predicted capacities. Great research efforts have been devoted to the analyses of the ratios of the 24-h measured resistance to the predicted capacity based on different CPT methods, in an attempt to find a feasible empirical correlation. It is found that a simple linear relationship exists between the quad root of the ratio and the predicted capacity. The developed empirical equations will give pile foundation engineers an insight into the ultimate resistances of driven piles demonstrating significant pile set-up effects. Pile set-up makes pile resistances grow with time, and it might be one of the reasons that cause the frequently reported large discrepancy between calculated static capacity and measured resistance at a certain time after pile installation.     

The Moon

Recent geochemical and geophysical data from the Moon enable a revision of earlier interpretations regarding lunar origin, structure and bulk composition. Earth and Moon show many similarities among their isotopic compositions, but they have evolved in totally dissimilar ways, probably related to the deficiency of water and volatile elements in the Moon as well as the vast differences in size and internal pressure. Some global geochemical differences from the Earth such as volatile depletion based on K/U ratios have been established. However, all current lunar samples come from differentiated regions, making the establishment of a bulk composition more reliant on bulk geophysical properties or isotopic similarities; it remains unclear how the latter arose or relate to whole Moon composition. The lack of fractionation effects among the refractory and super-refractory elements indicates that the proto-lunar material seems unlikely to have been vaporized while the presence of volatile elements may place lower limits on proto-lunar temperatures. The apparent lack of geochemical evidence of an impacting body enables other possible impactors, such as comets, to be considered. Although the origin of the Moon remains currently unknown, it is generally believed that the Moon originated as the result of a giant impact on the Earth.     

The wreck of the MV Rena: spatio-temporal analysis of ship-derived contaminants in the sediments and fauna of Astrolabe Reef

ABSTRACT

The October 2011 sinking of the container ship MV Rena on Astrolabe Reef, New Zealand, provided a rare opportunity to examine the fate of shipwreck-derived contaminants on an offshore rocky reef and food chain. Analyses of trace metals, polycyclic aromatic hydrocarbons (PAHs) and organotins indicated significant but localised contamination of Astrolabe Reef but not of nearby Mōtītī Island. Three years after the grounding, PAH concentrations were greater in sediments at Astrolabe (up to 131?mg kg^?1) than at control locations, while organotins from the ship's antifouling hull paint were found exclusively in Astrolabe Reef sediments and biota. Over 80% of Astrolabe sediment samples contained tributyltin at concentrations above guideline sediment levels (>0.07?mg kg^?1). Tributyltin and its decomposition products were also recorded in sea urchins, gastropods, lobster and fishes at concentrations up to 0.2?mg kg^?1. Wreck and cargo-derived metals, particularly copper, tin and zinc, were present in some Astrolabe sediment samples above Australia and New Zealand Environment and Conservation Council guideline concentrations. However, there appeared to be only limited transmission of metals through the food chain. Copper, tin and zinc were recorded at greater concentrations in Astrolabe sea urchins and gastropods compared to control specimens, while metal concentrations in other biota were comparable across impact and control sites. Despite over 3 years having passed since the Rena grounding, the data series does not show any upward or downward trends in contaminant concentrations on Astrolabe Reef. Consequently, there is uncertainty about the long-term implications of the Rena grounding for the ecology of Astrolabe Reef.     

In situ sampling reveals rapid uptake and depuration of polycyclic aromatic hydrocarbons by surf clams (Paphies subtriangulata) affected by the Rena oil spill

ABSTRACT

To investigate the uptake and depuration of polycyclic aromatic hydrocarbons associated with the Rena oil spill we sampled the surf clam Paphies subtriangulata at two open coast locations (6?km apart) just prior to oil coming ashore (7 October 2011), then at 1–3 week intervals for the next 4 months. Total polycyclic aromatic hydrocarbons (tPAH) increased at both sites from 1 to 96–124?µg?kg^?1 (wet weight) by 18 October before declining to low levels (<4?µg?kg^?1) by February 2012. Ongoing sampling throughout 2012–2014 included three additional sites to the north east (up to 30?km away) and a site 5?km to the south east revealing tPAH levels generally <10?µg?kg^?1 except in October 2013 where levels ranged between 39–45?µg?kg^?1 at all sites. A comparison of PAH component profiles with oil-contaminated beach sediment indicated that the high levels observed in surf clams between October–December 2011 were clearly associated with the Rena spill. However, the October 2013 peak had a PAH profile inconsistent with weathered Rena oil, suggesting an alternative source of contamination. Our results highlight the potential for P. subtriangulata as a PAH monitoring tool but recognise more study is needed to better quantify baseline levels and uptake and depuration dynamics.     

The removal kinetics of dissolved organic matter and the optical clarity of groundwater

Concentrations of dissolved organic matter (DOM) and ultraviolet/visible light absorbance decrease systematically as groundwater moves through the unsaturated zones overlying aquifers and along flowpaths within aquifers. These changes occur over distances of tens of meters (m) implying rapid removal kinetics of the chromophoric DOM that imparts color to groundwater. A one-compartment input-output model was used to derive a differential equation describing the removal of DOM from the dissolved phase due to the combined effects of biodegradation and sorption. The general solution to the equation was parameterized using a 2-year record of dissolved organic carbon (DOC) concentration changes in groundwater at a long-term observation well. Estimated rates of DOC loss were rapid and ranged from 0.093 to 0.21 micromoles per liter per day (μM d^?1), and rate constants for DOC removal ranged from 0.0021 to 0.011 per day (d^?1). Applying these removal rate constants to an advective-dispersion model illustrates substantial depletion of DOC over flow-path distances of 200 m or less and in timeframes of 2 years or less. These results explain the low to moderate DOC concentrations (20–75 μM; 0.26–1 mg L^?1) and ultraviolet absorption coefficient values (a ₂₅₄?<?5 m^?1) observed in groundwater produced from 59 wells tapping eight different aquifer systems of the United States. The nearly uniform optical clarity of groundwater, therefore, results from similarly rapid DOM-removal kinetics exhibited by geologically and hydrologically dissimilar aquifers.     

Heat tracing to examine seasonal groundwater flow beneath a low-gradient stream in rural central Illinois,USA

The thermal profile of a streambed is affected by a number of factors including: temperatures of stream water and groundwater, hydraulic conductivity, thermal conductivity, heat capacity of the streambed, and the geometry of hyporheic flow paths. Changes in these parameters over time cause changes in thermal profiles. In this study, temperature data were collected at depths of 30, 60, 90 and 150 cm at six streambed wells 5 m apart along the thalweg of Little Kickapoo Creek, in rural central Illinois, USA. This is a third-order low-gradient baseflow-fed stream. A positive temperature gradient with inflection at 90-cm depth was observed during the summer period. A negative temperature gradient with inflection at 30 cm was observed during the winter period, which suggests greater influence of stream-water temperatures in the substrate during the summer. Thermal models of the streambed were built using VS2DHI to simulate the thermal profiles observed in the field. Comparison of the parameters along with analysis of temperature envelopes and Peclet numbers suggested greater upwelling and stability in temperatures during the winter than during the summer. Upwelling was more pronounced in the downstream reach of the pool in the riffle and pool sequence.