Sedimentary regimes in Arctic's Amerasian and Eurasian Basins: Clues to differences in sedimentation rates

A standard lithostratigraphic model based on cores retrieved 1963–1973 from the ice island T-3 was developed by Clark et al. [Stratigraphy and glacial-marine sediments of the Amerasian Basin, central Arctic Ocean. Geological Society of America Special Paper, 181, 1–57, 1980] for the Amerasian Basin of the Arctic Ocean. We have investigated whether or not it is possible to apply this lithostratigraphy to cores from the Lomonosov Ridge, which can be correlated to Eurasian Basin cores, for the purpose of correlating the Amerasian and Eurasian stratigraphies. Published averaged sedimentary proxies from a selected set of T-3 cores are used to correlate with the identical published proxies for the included Lomonosov Ridge cores. The standard lithostratigraphic classification could not be applied to the Lomonosov Ridge cores, which is interpreted to result from differences in sedimentary regimes in the Amerasian and Eurasian Basins. These differences also apply to the barrier between the two basins, the Lomonosov Ridge. The general sedimentation rates are three to four times lower in the Amerasian Basin than in the Eurasian Basin if the first down-core paleomagnetic inclination change is used to correlate between the two basins whereas correlation based on sediment coarse fraction suggests only two times lower rates in the Amerasian Basin.     

The role of aluminium in the preservation of microbial biosignatures

Demonstrating the biogenicity of presumptive microfossils in the geological record often requires supporting chemical signatures, including isotopic signatures. Understanding the mechanisms that promote the preservation of microbial biosignatures associated with microfossils is fundamental to unravelling the palaeomicrobiological history of the material. Organomineralization of microorganisms is likely to represent the first stages of microbial fossilisation and has been hypothesised to prevent the autolytic degradation of microbial cell envelope structures. In the present study, two distinct fossilisation textures(permineralised microfossils and iron oxide encrusted cell envelopes)identified throughout iron-rich rock samples were analysed using nanoscale secondary ion mass spectrometry(NanoSIMS). In this system, aluminium is enriched around the permineralised microfossils, while iron is enriched within the intracellularly, within distinct cell envelopes. Remarkably,while cell wall structures are indicated, carbon and nitrogen biosignatures are not preserved with permineralised microfossils. Therefore, the enrichment of aluminium, delineating these microfossils appears to have been critical to their structural preservation in this iron-rich environment. In contrast,NanoSIMS analysis of mineral encrusted cell envelopes reveals that preserved carbon and nitrogen biosignatures are associated with the cell envelope structures of these microfossils. Interestingly, iron is depleted in regions where carbon and nitrogen are preserved. In contrast aluminium appears to be slightly enriched in regions associated with remnant cell envelope structures. The correlation of aluminium with carbon and nitrogen biosignatures suggests the complexation of aluminium with preserved cell envelope structures before or immediately after cell death may have inactivated autolytic activity preventing the rapid breakdown of these organic, macromolecular structures.Combined, these results highlight that aluminium may play an important role in the preservation of microorganisms within the rock record.     

Spatiotemporal variations of extreme sea levels around the South China Sea: assessing the influence of tropical cyclones,monsoons and major climate modes

With sea levels projected to rise as a result of climate change, it is imperative to understand not only long-term average trends, but also the spatial and temporal patterns of extreme sea level. In this study, we use a comprehensive set of 30 tide gauges spanning 1954–2014 to characterize the spatial and temporal variations of extreme sea level around the low-lying and densely populated margins of the South China Sea. We also explore the long-term evolution of extreme sea level by applying a dynamic linear model for the generalized extreme value distribution (DLM-GEV), which can be used for assessing the changes in extreme sea levels with time. Our results show that the sea-level maxima distributions range from ~?90 to 400 cm and occur seasonally across the South China Sea. In general, the sea-level maxima at northern tide gauges are approximately 25–30% higher than those in the south and are highest in summer as tropical cyclone-induced surges dominate the northern signal. In contrast, the smaller signal in the south is dominated by monsoonal winds in the winter. The trends of extreme high percentiles of sea-level values are broadly consistent with the changes in mean sea level. The DLM-GEV model characterizes the interannual variability of extreme sea level, and hence, the 50-year return levels at most tide gauges. We find small but statistically significant correlations between extreme sea level and both the Pacific Decadal Oscillation and El Niño/Southern Oscillation. Our study provides new insight into the dynamic relationships between extreme sea level, mean sea level and the tidal cycle in the South China Sea, which can contribute to preparing for coastal risks at multi-decadal timescales.

     

Vertical distribution of living mangrove foraminifera from KwaZulu-Natal,South Africa

Modern foraminiferal assemblage zones can be used to reconstruct palaeo sea levels when applied to fossil foraminifera down a sediment core. Previous intertidal foraminiferal studies have predominantly focused on assemblages in surface sediments (0–1 cm), with the rationale that surface assemblages reflect the modern-day environment. Foraminifera live infaunally and therefore there is a need to document the infaunal vertical distribution of living foraminifera to fully capture the modern environment. Infaunal foraminiferal populations may compositionally differ from or be similar to those in the uppermost 1 cm of a core sample, but abundance is variable vertically, making it very complex to reconstruct and interpret past sea levels. This can have implications for the choice of assemblages to use as modern analogues for past sea-level reconstructions. This study documents the vertical infaunal distribution of living foraminifera, to allow for more informed interpretations of palaeo-reconstructions in mangrove environments. The down-core vertical distribution and abundance of living foraminifera, along with grain size and organic content, were documented using sediment cores along an elevational transect. Nine taxa were recorded as living at the time of collection, six of which were restricted to the top 4 cm. The majority of these were calcareous and found in the cores situated closer to the intertidal channel. Therefore, we argue that the diversity of living calcareous and agglutinated foraminifera could be restricted by grain size, with coarser grain sizes associated with lower species diversity. The findings suggest that foraminiferal species inhabiting the top 4 cm represent deeper living foraminiferal populations. Therefore, the top 4-cm interval can be used to establish a modern training set upon which reconstructions can be based. The findings from this study will provide guidance on the use of South African mangrove environments for future sea-level reconstructions.     

Rare Earth Element Determination in Olivine by Laser Ablation‐Quadrupole‐ICP‐MS: An Analytical Strategy and Applications

Olivine offers huge, largely untapped, potential for improving our understanding of magmatic and metasomatic processes. In particular, a wealth of information is contained in rare earth element (REE) mass fractions, which are well studied in other minerals. However, REE data for olivine are scarce, reflecting the difficulty associated with determining mass fractions in the low ng g^?1 range and with controlling the effects of LREE contamination. We report an analytical procedure for measuring REEs in olivine using laser ablation quadrupole‐ICP‐MS that achieved limits of determination (LOD) at sub‐ng g^?1 levels and biases of ~ 5–10%. Empirical partition coefficients (D values) calculated using the new olivine compositions agree with experimental values, indicating that the measured REEs are structurally bound in the olivine crystal lattice, rather than residing in micro‐inclusions. We conducted an initial survey of REE contents of olivine from mantle, metamorphic, magmatic and meteorite samples. REE mass fractions vary from 0.1 to double‐digit ng g^?1 levels. Heavy REEs vary from low mass fractions in meteoritic samples, through variably enriched peridotitic olivine to high mass fractions in magmatic olivines, with fayalitic olivines showing the highest levels. The variable enrichment in HREEs demonstrates that olivine REE patterns have petrological utility.     

Hydraulic,physical and rheological characteristics of rain‐triggered lahars at Semeru volcano,Indonesia

Lahars (volcanic debris flows) have been responsible for 40% of all volcanic fatalities over the past century. Mount Semeru (East Java, Indonesia) is a persistently active composite volcano that threatens approximately one million people with its lahars and pyroclastic flows. Despite their regularity, the behaviour and the propagation of these rain‐triggered lahars are poorly understood. In situ samples were taken from lahars in motion at two sites in the Curah Lengkong River, on the southeast flank of Semeru, providing estimates of the particle concentration, grain size spectrum, grain density and composition. This enables us to identify flow sediment from three categories of lahars: (a) hyperconcentrated flow, (b) non‐cohesive, clast‐ and matrix‐supported debris flow, and (c) muddy flood. To understand hyperconcentrated flow sediment transport processes, it is more appropriate to sample the active flows than the post‐event lahar deposits because in situ sampling retains the full spectrum of the grain‐size distribution. Rheometrical tests on materials sampled from moving hyperconcentrated flows were carried out using a laboratory vane rheometer. Despite technical difficulties, results obtained on the <63, <180, and <400 µm fractions of the sampled sediment, suggest a purely frictional behaviour. Importantly, and contrary to previous experiments conducted with monodisperse suspensions, our results do not show any transition towards a viscous behaviour for high shear rates. These data provide important constraints for future physical and numerical modelling of lahar flows. Copyright © 2010 John Wiley & Sons, Ltd.     

The causes and petrological significance of cathodoluminescence emissions from alkali feldspars

The cathodoluminescence (CL) of a variety of alkali feldspars from South Greenland has been examined in an attempt to understand the causes of the CL and its petrological significance. Analytical methods have included CL spectroscopy, secondary ion mass spectrometry (SIMS) and electron paramagnetic resonance (EPR) to correlate the presence of certain CL emissions to the presence of certain trace element and point defects. Where possible, blue and red luminescent fractions of the same rock samples have been separated and analysed separately. Blue CL appears to relate to the presence of electron holes on bridging oxygens, particularly on the Al-O-Al bridge, as determined from EPR studies. No correlation with other proposed activators for blue CL such as Eu²⁺, Ga³⁺ or Ti⁴⁺ was observed. Some blue luminescent feldspars also have an emission in the infra-red (IR), invisible during normal visible CL petrography. The red and IR CL emissions correspond to features in EPR spectra attributed to Fe³⁺ and support previous suggestions that Fe³⁺ is related to this emission. However, our studies indicate that the visible red CL relates specifically to Fe³⁺ on the T1 site, whereas the equivalent CL from disordered feldspars lies in the IR. The difference between red and IR CL emissions therefore relates to the state of Fe³⁺ order across the tetrahedral sites. These data allow more meaningful interpretations of CL as a petrographic tool in alkali feldspar-bearing rocks. Received: 5 March 1998 / Accepted: 23 November 1998