Geodynamic evolution of the Tethyan lithosphere as recorded in the Spontang Ophiolite,South Ladakh ophiolites(NW Himalaya,India)

The Spontang Ophiolite complex represents the most complete ophiolite sequence amongst the South Ladakh ophiolites and comprises mantle rocks(depleted harzburgites,dunites and minor lherzolites)as well as crustal rocks(basalt,isotropic gabbros,layered gabbros etc.).In the present study,detailed geochemistry(whole rock as well as mineral chemistry)and Sr-Nd isotopic analyses of thirty-six ultramaficmafic samples have been attempted to constraint the evolution and petrogenetic history of the Tethyan oceanic crust.Major,trace-element and REE patterns of the peridotites and their minerals indicate that the lherzolites experienced lower degrees of partial melting resembling abyssal peridotites(at higher temperatures,TREE=$1216℃)than the harzburgites(6%–8%versus 15%–17%).Elevated eNd(t)and variable⁸⁷ Sr/⁸⁶ Sr(t)ratios along with REE patterns suggest that the Spontang mafic rocks display N-MORB affinity with negligible participation of oceanic sediments in their genesis are originated from a depleted upper mantle with little contribution from subduction-related fluids.MORB-type Neotethyan oceanic crust is associated with the earliest phase of subduction(of older Jurassic age)through which a younger intra-oceanic island arc(Spong arc)subsequently developed.Harzburgites REE display typical U-shaped patterns,suggesting that these rocks have been metasomatized by LREE-enriched fluids.On the other side,mafic rocks are characterized by heterogeneous(Nb/La)PMand(Hf/Sm)PMand relatively homogeneous eNd(t),indicating interaction of subduction-related melts with the upper mantle during the initiation of subduction,in Early Cretaceous times.     

Quaternary paleolake formation and cataclysmic flooding along the upper Yenisei River

A suite of geomorphological and sedimentological features in the catchment of the upper Yenisei River in the Sayan mountains of southern Siberia testifies to the occurrence of cataclysmic floods that flowed down the river. Evidence of large-scale high-energy flood events includes: 1) gravel dunes, up to a few meters high and spaced 50 to 80 m apart, in the Kyzyl Basin 2) landforms such as hanging valleys and paleochannels and 3) flood sediments in a tributary valley. The origins of the Yenisei floods were likely diverse due to complex hydrological processes operating in the Sayan mountains. The possibilities include failures of multiple, variably impounded (ice, sedimentary, tectonic scarp, and lava flow dams) paleolakes in the two large intermontane basins of Darkhadyn Khotgor and Todza, and other minor basins, in the upper Yenisei River catchment. Dating techniques applied to the paleolakes in the Darkhadyn Khotgor and Todza basins revealed their formation during various periods in the middle–late Pleistocene and Holocene. Flooding from the Darkhadyn Khotgor appears to explain many of the inferred flood features, although contributions by flooding from other paleolake basins cannot be ruled out. Computer simulation of the flooding caused by a Darkhadyn Khotgor paleolake ice-dam failure indicates a probable peak discharge of  3.5 × 10⁶ m³ s^− 1, approximately one-fifth that of the floods that formed the Channeled Scabland in the U.S.A. Many of the outburst events probably occurred in the late Quaternary, but earlier floods could also have occurred.     

Measurements of Rare Earth Element and Other Element Mass Fractions in Environmental Reference Materials (NIST SRM 1646a,NIST SRM 1400, IAEA‐395 and IAEA‐450) by INAA,ICP‐AES and ICP‐MS

INAA, ICP‐AES and ICP‐MS were used to elementally characterise four environmental reference materials – NIST SRM 1646a (Estuarine Sediment), NIST SRM 1400 (Bone Ash), IAEA‐395 (Urban Dust) and IAEA‐450 (Algae). An analytical scheme consisting of the three methods was first applied to NIST SRM 1646a to validate the methodology because it has been extensively analysed and has certified values for many elements. With repeated analyses of NIST SRM 1646a, the accuracy and measurement repeatability of the data obtained were evaluated based on two statistical calculations (zeta‐score and Horwitz ratio) and were observed to be good enough for the analytical scheme to be applied to similar sorts of environmental/geochemical samples. Applying the same approach to NIST SRM 1400, IAEA‐395 and IAEA‐450, enabled mass fractions of 29, 38 and 28 elements to be determined, respectively. Among these results, the data for rare earth elements are of particular interest, not only for IAEA‐450 but also for the other three reference samples. The data for Pr, Gd, Dy, Ho, Er and Tm in NIST SRM 1646a are newly reported in this study. By using small test portions (< 100 mg) for NIST SRM 1646a and IAEA‐395, and recommended minimum amounts for NIST SRM 1400 and IAEA‐450, sample homogeneity was evaluated.     

Evaluating the geothermal heat pump potential from a thermostratigraphic assessment of rock samples in the St. Lawrence Lowlands,Canada

The installation cost and the performance of geothermal heat pump systems are influenced by the thermal state and properties of the subsurface. The ground ability to transfer heat described by thermal conductivity is a dominant factor affecting the favorability of closed-loop ground heat exchangers installed in vertical boreholes. A study that aimed at evaluating the geothermal heat pump potential by mapping the thermal conductivity of rock sequences was, therefore, performed for the St. Lawrence Lowlands sedimentary basin in Canada. Thermal conductivity was measured in the laboratory on rock samples collected in outcrops and used to complete design calculations of a geothermal system with a single borehole. Results allowed the definition of thermostratigraphic units that can be linked to depositional environments. Basal quartz-rich sandstones formed in a rift environment show a high geothermal potential. Overlying dolomites, argillaceous limestones and shales deposited in a passive margin evolving to a foreland basin exhibit a transition toward the top from high to low geothermal potential. Upper turbidites and molasses have a moderate geothermal potential. The thermal conductivity of the thermostratigraphic units is dominantly influenced by the mineralogy of the sedimentary rocks. Understanding their origin is a key to improve geothermal resource assessment and system design to anticipate new installations in the area.     

Use of particulate surrogates for assessing microbial mobility in subsurface ecosystems

Mass fluxes from the ground surface can play a vital role in influencing groundwater ecosystems. Rates of delivery may influence intact ecosystem composition, while fluxes of substances associated with anthropogenic activity may critically alter the functioning of associated microbial assemblages. Field-based tracing experiments offer a valuable means of understanding mass transport rates and mechanisms, particularly in complex heterogeneous epikarst systems overlying vulnerable fissured aquifers. A short-term tracer experiment monitoring solute and particle tracer concentrations after they passed through a 10-m-thick sequence of limestone, capped by a thin soil, revealed rapid travel times and variable attenuation rates for the substances employed. Results demonstrated that particle tracers have shorter average travel times and can reach the subsurface in higher concentrations and over shorter times than non-reactive solutes. High recovery rates for the bacterial tracer Ralstonia eutropha H16 contrasted strongly with those of similarly sized fluorescent polystyrene microspheres, highlighting the importance of physico-chemical surface characteristics of particle tracers. Complementary laboratory batch experiments examined the role played by organic and inorganic soil/rock surfaces on particle tracer attenuation. Findings suggest that biofilms may significantly promote transport of particulate material below ground, i.e., the delivery of allochthonous microorganisms to karst groundwater.     

Morphology of rubbly pahoehoe (simple) flows from the Deccan Volcanic Province: Implications for style of emplacement

Lava flows with preserved bases and brecciated upper crusts constitute a morphological type that differs in character from typical pahoehoe and a'a: such flows have been reported from many provinces around the world. Previous studies had referred to these flows informally as ‘pahoehoe flows with rubbly tops’, ‘broken-top pahoehoe’ and ‘rubbly pahoehoe’. Recent studies have formally applied the latter term to describe parts of the well-studied Laki flow in Iceland as well as flows from the Columbia River Basalt province. Rubbly pahoehoe flows are abundant in the upper stratigraphic formations of the Deccan Volcanic Province (DVP), and are more commonly known as simple flows. This study presents detailed observations of such flows from various parts of the DVP and discusses their implications for understanding flow emplacement. These flows, which appear to be single units at the outcrop-scale, are generally much thicker and significantly more extensive than individual pahoehoe lobes that dominate the lower formations of the Deccan stratigraphy. They are characterised by preserved, gently undulating tachylitic bases but variably disrupted crustal zones that grade into flow-top breccias. The breccias are constituted of highly vesicular and oxidised fragments of varying sizes that appear to have been derived from previously formed pahoehoe crusts. Previous work has indicated that the morphology of these flows might be related to initial inflation, accompanied by rapid volatile exsolution and an increase in effusion rate and/or viscosity with time. This agrees reasonably well with the qualitative and quantitative models of emplacement developed for the Laki flow. The abundance of such flows in the upper formations of the Deccan stratigraphy clearly hints at a significant shift in the nature of the Deccan eruptions; this could be indicative of higher eruption rates during this period. This, in turn, raises the possibility of hazardous impact on the climate during the eruption of these flows, which is also discussed in the paper.     

Terrain complexity and reduction of topographic data

Digital terrain data are useful for a variety of applications in mapping and spatial analysis. Most available terrain data are organized in a raster format, among them being the most extensively-used Digital Elevation Models (DEM) of the U.S. Geological Survey. A common problem with DEM for spatial analysis at the landscape scale is that the raster encoding of topography is subject to data redundancy and, as such, data volumes may become prohibitively large. To improve efficiency in both data storage and information processing, the redundancy of the terrain data must be minimized by eliminating unnecessary elements. To what extent a set of terrain data can be reduced for improving storage and processing efficiency depends on the complexity of the terrain. In general, data elements for simpler, smoother surfaces can be substantially reduced without losing critical topographic information. For complex terrains, more data elements should be retained if the topography is to be adequately represented. In this paper, we present a measure of terrain complexity based on the behavior of selected data elements in representing the characteristics of a surface. The index of terrain complexity is derived from an estimated parameter which denotes the relationship between terrain representation (percentage surface representation) and relative data volume (percentage DEM elements). The index can be used to assess the required volume of topographic data and determine the appropriate level of data reduction. Two quadrangles of distinct topographic characteristics were examined to illustrate the efficacy of the developed methodology.