The Effectiveness of Arsenic Remediation from Groundwater in a Private Home

Private wells are the source of drinking water for approximately 15% of households in the United States, but these wells are not regulated or monitored by government agencies. The well waters can contain arsenic, a known carcinogen that occurs in groundwater throughout the nation at concentrations that can exceed the Maximum Contaminant Level defined by the U.S. Environmental Protection Agency (10 ppb). In order to reduce arsenic exposure, homeowners can either rely on bottled water for drinking or install in-house water treatment systems for arsenic removal. Here, we document the arsenic levels associated with these options. We examined 24 different major bottled water brands and found that all have arsenic levels <1.5 parts per billion (ppb), and more than half have levels below our measurement detection limit of 0.005 ppb. For in-house treatment systems, we examined the performance of arsenic removal by point-of-use reverse osmosis filtration, and by whole-house and point-of-use filters containing granulated ferric oxide. Our results show that long-term (2 years) filtration with granulated ferric oxide reduced arsenic in well water from an initial concentration of 4 to 9 ppb down to <0.005 ppb, validating this technology as an effective form of arsenic remediation for private homes.     

Socio-economic and management implications of range-shifting species in marine systems

Climate change is leading to a redistribution of marine species, altering ecosystem dynamics as species extend or shift their geographic ranges polewards with warming waters. In marine systems, range shifts have been observed in a wide diversity of species and ecosystems and are predicted to become more prevalent as environmental conditions continue to change. Large-scale shifts in the ranges of marine species will likely have dramatic socio-economic and management implications. Australia provides a unique setting in which to examine the range of consequences of climate-induced range shifts because it encompasses a diverse range of ecosystems, spanning tropical to temperate systems, within a single nation and is home to global sea surface temperature change ‘hotspots’ (where range shifts are particularly likely to occur). We draw on global examples with a particular emphasis on Australian cases to evaluate these consequences. We show that in Australia, range shifts span a variety of ecosystem types, trophic levels, and perceived outcomes (i.e., negative versus positive). The effect(s) of range shifts on socio-economic change variables are rarely reviewed, yet have the potential to have positive and/or negative effects on economic activities, human health and ecosystem services. Even less information exists about potential management responses to range-shifting species. However, synthesis of these diverse examples provides some initial guidance for selecting effective adaptive response strategies and management tools in the face of continuing climate-mediated range shifts.     

DMS and SO2 Measurements in the Tropical Marine Boundary Layer

Dimethyl sulfide (DMS) and sulfur dioxide (SO₂) mixing ratios were measured in the boundary layer on Oahu, Hawaii in April and May 2000. Average DMS and SO₂ levels were 22 ± 7 (n = 488) pmol/mol and 23 ± 7 (n = 471) pmol/mol respectively. Anti-correlated DMS and SO₂ diurnal cycles, consistent with DMS + OH oxidation were observed on most days. Photochemical box model simulations suggest that the yield of SO₂ and total SO₂ sink are ∼85% and ∼2 × 10⁴ molec cm^{− 3} s^{− 1} respectively. On several days the rate of decrease in DMS and increase in SO₂ levels in the early morning were larger that predicted by the model. Dynamical and chemical causes for the anomalous early morning data are explored.     

Transformation of Trichloroethylene to Predominantly Non‐Regulated Products under Stimulated Sulfate Reducing Conditions

Anaerobic microcosms containing sediment and water were amended to generate a range of mass loadings of FeS. Microcosms were then spiked with trichloroethylene (TCE) and the concentration of TCE and possible volatile reaction products monitored over time. The lowest yields of TCE, as well as the lowest yields of reaction products regulated under the Safe Drinking Water Act (i.e., dichloroethylene isomers and vinyl chloride), were observed at FeS mass loadings at or above 20 g/L. Sixty eight days after spiking with TCE, selected microcosms were amended with sulfate and lactate, or sulfate, Fe(II), and lactate, and the effect of these amendments on TCE transformation and yield of regulated products was compared to microcosms that did not receive any amendments. Addition of sulfate, Fe(II), and lactate led to the greatest improvement on TCE depletion rates and the lowest yields of regulated reaction products compared with addition of sulfate and lactate, or no amendments. Analysis of kinetic modeling suggests that microbial and abiotic processes acted in concert to promote TCE transformation to a relatively low yield of regulated products in microbially active microcosms that contained high mass loadings of FeS.     

Finite element analysis of the seismic response of ancient columns

This paper presents a numerical study of the response to earthquake actions of eight ancient Greek multidrum columns, which were chosen as representative of a broad spectrum of the ancient columns preserved to date. The study was conducted using the FE software Abaqus, in three steps. At first, the software efficiency to predict the rocking response of dry-stone structures was verified. Afterwards, various numerical models of one typical ancient multidrum column were seismically excited. Records of four real earthquakes differing in frequency content were used for the excitation of the models. Each column model was different from the others at least in one geometric or modeling parameter. Although the examined parameters affected the numerical results, their variation did not alter significantly the overall behavior of the column. In the last step of the study, numerical models of eight columns were seismically excited using four seismic records. In these analyses, among the simulation approaches tested in the second step, the simpler one was adopted. On the basis of the numerical results, conclusions were drawn regarding the seismic resistance of the columns and its correlation with the dynamic characteristics of the columns (size, slenderness, and frequency parameter) and with the basic intensity measures and frequency content indicator of the seismic motions (PHA, PHV, PHD, and T_g). Thus, criteria of seismic collapse for the multidrum columns are proposed, which can be used for the approximate assessment of the seismic vulnerability of free-standing ancient columns, provided that the columns are in good preservation state.     

18O/16O studies of fossil fissure fumaroles from the Valley of Ten Thousand Smokes, Alaska

At three sample sites where there are good exposures of the upper 15 m of the 1912 ash-flow sheet in the Valley of Ten Thousand Smokes (VTTS), Alaska, ¹⁸O/¹⁶O studies indicate that fumarolic activity produced a very wide range of δ¹⁸O values (?0.1 to +12.6; n=32) in the groundmass adjacent to fossil fissure fumaroles. This contrasts sharply with the uniformity of δ¹⁸O in the groundmass away from fumarolic conduits (δ¹⁸O=+5.9 to +7.1; n=7) and in all of the feldspar phenocrysts (δ¹⁸O=+6.11 to +7.5 1 for 11 samples from this study and Hildreth 1987), independent of whether these were collected from fossil fumaroles or from unaltered tuff. Only one sample contained feldspars that were even slightly ¹⁸O-enriched relative to the others (cloudy plagioclase δ¹⁸O=+8.45). and this sample also contained the most ¹⁸0-enriched groundmass of any of those analyzed (δ¹⁸O=+12.6). This preservation of primary magmatic δ¹⁸O values in the VTTS feldspar phenocrysts is clearly a consequence of the extremely short time span (i.e., 1912 to ≈1923) of vigorous, high-temperature, fumarolic activity in the 1912 ash-flow sheet. These ¹⁸O/^l6O systematica are strikingly similar to those discovered in the 2.8-Ma intracaldera Chegem Tuff (Gazis et al. 1996) and in the fossil fumaroles in the outflow sheet of the 0.76 Ma Bishop Tuff (Holt and Taylor 1998), thus confirming that a similar type of fumarolic meteoric-hydro-thermal activity occurred above the zone of intense welding in all three of these ash-flow tuffs. This is particularly important, because it provides a direct linkage between the older tuffs and the actual observations at the VTTS of steam chemistry, water/rock interaction, circulation geometry, flow velocities, and fumarolic temperatures (up to 645°C). The ¹⁸O/^l6O effects in the VTTS can all be explained in terms of a two-stage history: (a) an early, 10- to 15-year-long, high-temperature (τ;450°C), fumarolic ¹⁸O-depletion event (groundmass δ¹⁸O=?0.1 to +4.8); and (b) a subsequent, much longer-lived, low-temperature (<150°C), ¹⁸O-enrichment episode (groundmass as high as δ¹⁸O=+12.6). Steam in these low-temperature fumaroles probably passed through various parts of the same hydrothermal system associated with the earlier, higher-temperature, fumarolic activity, and a weakened form of this low-temperature hydrothermal circulation continues to the present day (Keith et al. 1992; Lowell and Keith 1991). This low-temperature ¹⁸O/¹⁶O exchange probably occurred in combination with mineralogical alteration of both the groundmass and the calcium-rich portions of feldspar phenocrysts during the waning (<150°C) stages of fumarolic activity (Spilde et al. 1993). The slight ¹⁸O enrichment of apparently pristine, transparent feldspar phenocrysts (δ¹⁸O=+7.51) in one of the ¹⁸O-depleted, meteoric-hydrothermally altered fumarolic samples (whole-rock δ¹⁸O=+4.8) probably indicates that this sample was incipiently altered at low temperatures as fumarolic activity waned, and thus may have had a whole-rock δ¹⁸O value much lower than +4.87‰ prior to 1923.     

Coastal Impacts of the March 11th Tohoku, Japan Tsunami in the Galapagos Islands

On March 11, 2011 at 5:46:23 UTC (March 10 11:46:23 PM Galapagos Local Time), the M_w 9.0 Great East Japan Earthquake occurred near the Tohoku region off the east coast of Japan, spawning a Pacific-wide tsunami. Approximately 12,000 km away, the Galapagos Islands experienced moderate tsunami impacts, including flooding, structural damage, and strong currents. In this paper, we present observations and measurements of the tsunami effects in the Galapagos, focusing on the four largest islands in the archipelago; (from west to east) Isabela, Santiagio, Santa Cruz, and San Cristobal. Access to the tsunami affected areas was one of the largest challenges of the field survey. Aside from approximately ten sandy beaches open to tourists, all other shoreline locations are restricted to anyone without a research permit; open cooperation with the Galapagos National Park provided the survey team complete access to the Islands coastlines. Survey locations were guided by numerical simulations of the tsunami performed prior to the field work. This numerical guidance accurately predicted the regions of highest impact, as well as regions of relatively low impact. Tide-corrected maximum tsunami heights were generally in the range of 3–4 m with the highest runup of 6 m measured in a small pocket beach on Isla Isabela. Puerto Ayora, on Santa Cruz Island, the largest harbor in the Galapagos experienced significant flooding and damage to structures located at the shoreline. A current meter moored inside the harbor recorded relatively weak tsunami currents of less than 0.3 m/s (0.6 knot) during the event. Comparisons with detailed numerical simulations suggest that these low current speed observations are most likely the result of data averaging at 20-min intervals and that maximum instantaneous current speeds were considerably larger. Currents in the Canal de Itabaca, a natural waterway between Santa Cruz Island and a smaller island offshore, were strong enough to displace multiple 5.5-ton navigation buoys. Numerical simulations indicate that currents in the Canal de Itabaca exceeded 4 m/s (~8 knots), a very large flow speed for a navigational waterway.     

New light on a dark subject: comment

In their article, “New light on a dark subject: On the use of fluorescence data to deduce redox states of natural organic matter,” Macalady and Walton-Day (2009) subjected natural organic matter (NOM) samples to oxidation, reduction, and photochemical transformation. Fluorescence spectra were obtained on samples, which were diluted “to bring maximum uvvisible absorbance values below 1.0.” The spectra were fit to the Cory and McKnight (2005) parallel factor analysis (PARAFAC) model, and consistent variation in the redox state of quinone-like moieties was not detected. Based on these results they concluded that fitting fluorescence spectra to the Cory and McKnight (2005) PARAFAC model to obtain information about the redox state of quinone-like moieties in NOM is problematic. Recognizing that collection and correction of fluorescence spectra requires consideration of many factors, we investigated the potential for inner-filter effects to obscure the ability of fluorescence spectroscopy to quantify the redox state of quinone-like moieties. We collected fluorescence spectra on Pony Lake and Suwannee River fulvic acid standards that were diluted to cover a range of absorbance wavelengths, and fit these spectra to the Cory and McKnight (2005) PARAFAC model. Our results suggest that, in order for the commonly used inner-filter correction to effectively remove inner-filter effects, samples should be diluted such that the absorbance at 254 nm is less than 0.3 prior to the collection of fluorescence spectra. This finding indicates that inner-filter effects may have obscured changes in the redox signature of fluorescence spectra of the highly absorbing samples studied by Macalady and Walton-Day (2009).