Impact of the 11 March 2011, Great East Japan earthquake and tsunami on the chemical industry

The Great East Japan earthquake and tsunami damaged or destroyed many industrial facilities housing or processing hazardous substances, such as refineries, petrochemical facilities and other types of chemical industry. This showed that also generally well prepared countries are at risk of suffering natural hazard triggered technological (Natech) accidents. An analysis of data collected from open sources and through interviews with authorities was performed to understand the main reasons for the industrial damage and downtime as well as the extent of hazardous-materials releases and the associated impact on society. The analysis of the data set confirmed the findings from other studies with respect to main damage and failure modes, as well as hazardous-materials release paths. In addition, gaps in Natech risk management were identified. Based on the data analysis and interviews lessons learned in support of a more far-reaching Natech risk management are presented.     

Heat budget of Flakevatn,a subpolar lake

Zusammenfassung Durch Kenntnis von Sommer- und Wintertemperaturen in dem südnorwegischen Gebirgssee Flakevatn (Meeresh?he 1448 m) konnte die Thermik des subpolaren Seetypus charakterisiert werden. Im Sommer herrscht in Flakevatn wiederholte Isothermie bei relativ hohen Temperaturen, im Winter wird der See ganz ausserordentlich abgekühlt (Fig. 1, Tabelle). Die sommerliche W?rmespeicherung betr?gt +5800, die winterliche −22500 cal/cm².      

Some physical and chemical properties of lakes in north-eastern Norway

Summary Chemical and physical properties in 12 lakes in the north-easternmost part of Norway are studied. Geologically the lakes are situated on the pre-cambrian “Baltic shield”, with metamorphic and intrusive rocks that are not easily soluble. Vertical series of temperature, pH, O₂ and x₁₈ together with colour measurements and transparency indicate that the lakes are temperate and fundamentally oligotrophic, some with a dystrophic character. Some individual differences are discussed, with special reference to the surroundings, flow-through rate and morphometry. In accordance with the geology of the area the amount of electrolytes is small. Major ions (Ca, Mg, Na, K, HCO₃, SO₄ and Cl) are analysed. The greatest differences in the composition of these ions in the lakes are shown to be due mainly to the varying proximity to the sea and to geological differences. Rain is shown to be the most important factor in supplying major ions toat least some of the lakes. Individual variations are discussed, and comparisons are made with the ionic composition of water in other districts.

---

Zusammenfassung An 12 im n?rdlichesten Teil von Norwegen, auf dem pr?kambrischen Baltischen Schild gelegenen Seen werden die chemischen und physikalischen Eigenschaften studiert. Das Einzugsgebiet besteht aus schwerl?slichem, metamorphem und intrusivem Gestein. Die vertikale Verteilung von Temperatur, pH, O₂ und x₁₈ samt Farbmessungen und Transparenz zeigt, dass die Seen dem temperierten Typus angeh?ren und im wesentlichen oligotroph sind, einige von dystrophem Charakter. Einige individuelle Unterschiede werden er?rtert mit besonderer Berücksichtigung der Umgebung, der Durchflutungszeit und der Morphometrie. In übereinstimmung mit der geologischen Beschaffenheit der Umgebung ist der Elektrolytgehalt neigdrig. Die dominierenden Ionen (Ca, Mg, Na, K, HCO₃, SO₄ und Cl) werden analysiert. Es wird nachgewiesen, dass die gr?ssten Unterschiede in der Zusammensetzung dieser Ionen in den Seen auf die verschiedene Entfernung vom Meer und auf geologische Unterschiede zurückzuführen sind. Für einige der Seen wird nachgewiesen, dass der Regen als wichtigster Faktor für ihre Versorgung mit Ionen anzusehen ist. Es werden individuelle Unterschiede er?rtert und Vergleiche mit der ionalen Zusammensetzung von Gew?ssern anderer Gegenden gezogen.

     

Hypersthene-ilmenite(/magnetite) symplectites in coronitic olivine-gabbronorites

Symplectitic intergrowths of hypersthene (host) with ilmenite and minor magnetite (vermicules) in a gabbroic sill from the Precambrian of southwest Sweden occur as replacement products of olivine, and are thought to have formed simulataneously with the replacement of nearby crystals of ilmenite and Timagnetite by biotite and hornblende (and spinel). These interrelated replacement processes may have taken place during, or immediately after, the final stages of the magmatic crystallization, at temperatures of about 660–680°C, as part of the inherent metamorphism of the gabbroic rock. Another expression of this metamorphic imprint is the occurrence of two-tiered corona shells of hypersthene/hornblende (+spinel) at the interface of olivine and plagioclase crystals.     

Encounters with an unearthly mudstone: Understanding the first mudstone found on Mars

The Sheepbed mudstone forms the base of the strata examined by the Curiosity rover in Gale Crater on Mars, and is the first bona fide mudstone known on another planet. From images and associated data, this contribution proposes a holistic interpretation of depositional regime, diagenesis and burial history. A lake basin probably received sediment pulses from alluvial fans. Bed cross‐sections show millimetre to centimetre‐scale layering due to distal pulses of fluvial sediment injections (fine‐grained hyperpycnites), fall‐out from river plumes, and some aeolian supply. Diagenetic features include mineralized synaeresis cracks and millimetre‐scale nodules, as well as stratiform cementation. Clay minerals were initially considered due to in situ alteration, but bulk rock chemistry and mineralogy suggests that sediments were derived from variably weathered source rocks that probably contained pre‐existing clay minerals. X‐ray diffraction analyses show contrasting clay mineralogy in closely spaced samples, consistent with at least partial detrital supply of clay minerals. A significant (ca 30 wt%) amorphous component is consistent with little post‐depositional alteration. Theoretical modelling of diagenetic reactions, as well as kinetic considerations, suggest that the bulk of diagenetic clay mineral formation occurred comparatively late in diagenesis. Diagenetic features (synaeresis cracks and nodules) were previously thought to reflect early diagenetic gas formation, but an alternative scenario of synaeresis crack formation via fabric collapse of flocculated clays appears more likely. The observed diagenetic features, such as solid nodules, hollow nodules, matrix cement and ‘raised ridges’ (synaeresis cracks) can be explained with progressive alteration of olivine/glass in conjunction with centrifugal and counter diffusion of reactive species. Anhydrite‐filled fractures in the Sheepbed mudstone occurred late in diagenesis when fluid pressures built up to exceed lithostatic pressure. Generating fluid overpressure by burial to facilitate hydraulic fracturing suggests a burial depth of at least 1000 m for the underlying strata that supplied these fluids.     

Chemical and structural relations of epitaxial xenotime and zircon substratum in sedimentary and hydrothermal environments: a TEM study

Xenotime overgrowths on detrital zircon in siliciclastic sediments have been reported in numerous studies. However, in natural samples, solid solution of zircon and xenotime is limited to near-end-member compositions. In order to characterize the interface region between both minerals and to draw inferences on the growth mechanisms of authigenic xenotime, we studied xenotime overgrowths on detrital zircon grains from two Phanerozoic sandstone samples with contrasting post-depositional histories. In one sample, the small (≤10 μm), pyramidal xenotime overgrowths are of diagenetic origin and grew without major discontinuity on the detrital zircon grain. The second sample shows up to >50-μm-wide, porous and inclusion-rich, hydrothermal xenotime overgrowths on detrital zircon, whereas the transition zone between both minerals is accompanied by large pore volume. Chemical compositions of the xenotime precipitates from the two samples differ particularly in Y, REE, Th and Sc concentrations, whereas high MREE availability in the diagenetic sample and the presence of Sc in the hydrothermal sample, respectively, appear to have promoted xenotime growth. Transmission electron microscopy on electron-transparent foils cut from the interface region shows that both the diagenetic xenotime and the hydrothermal xenotime are crystalline and grew in optical and crystallographic continuity to their detrital zircon substrata. Only a narrow transition zone (≤90 nm—diagenetic sample, 200–300 nm—hydrothermal sample) between zircon and xenotime is in part made up of nanometre-scale crystalline domains that are slightly distorted and may have formed from dissolution–re-precipitation processes at the zircon rim along with precipitation from the respective fluid.     

Neotectonics of the Pontides: implications for ‘incompatible’ structures along the North Anatolian fault

Data for the post-Serravallian, ‘neotectonic’ evolution of the Pontides in northern Turkey indicate predominant ENE-WSW shortening with complementary NNW-SSE extension. We present a new fault plane solution for the Bartin earthquake (3 September 1968) and compare its mechanism with the movement picture of other neotectonic faults in the Pontides and northern Greece together with that of the Thessaloniki earthquake (20 May 1978). The general strain pattern exhibited by these structures agrees remarkably well with that inferred from early Tortonian-early Pleistocene structures reported from within the North Anatolian fault zone, which have been interpreted as indicating a possible reversal of the sense of movement along the North Anatolian transform fault. Here, we argue that such ‘incompatible’ structures may be related to the overall E-W shortening of Anatolia and the southern parts of the Black Sea resulting from the sideways continental escape from around the African and the Arabian promontories, rather than to hypothetical reversal of motion along the North Anatolian fault, for which there is no evidence other than the above-mentioned ‘incompatible’ structures. This new model also has important implications for seismicity and earthquake risk in regions contained within the southern part of the Black Sea plate.     

Experimental studies on the phase systems Fe-Ni-Pd-S and Fe-Pt-Pd-As-S applied to PGE deposits

Summary In the present paper current results of experimental investigation of the phase system Pd-Fe-Ni-S at 900°C, 725°C, 550°C and 400°C as well as of the phase system Pt-Fe-As-S at 850°C and 470°C are summarized. A preliminary note on the system Pt-Pd-As-S is added. Individual phase assemblages are presented, data on solubility of PGE in base metal sulphides/arsenides or alloys are given and solid solution ranges of important minerals are described as a function of temperature and phase assemblage. The extent and role of sulphide/arsenide melts in these systems are presented together with hints for, and examples of the application of the current experimental results for the explanation of ore-geological processes.

---

Bisherige Ergebnisse experimenteller Untersuchungen in den Systemen Fe-Ni-Pd-S und Fe-Pt-Pd-As-S und ihre Bedeutung für Lagerstätten der Platin-Gruppen-Elemente

Zusammenfassung In der vorliegenden Arbeit werden bisherige Ergebnisse experimenteller Untersuchungen in den Phasensystemen Pd-Fe-Ni-S bei 900°C, 725°C, 550°C sowie 400°C, bzw. Pt-Fe-As-S bei 850°C und 470°C zusammengefasst. Vorläufige Anmerkungen zum System Pt-Pd-As-S werden gegeben. Die Phasenbeziehungen und die Löslichkeitsdaten von PGE's in Buntmetall-Sulfiden/Arseniden sowie deren Verbindungen werden präsentiert. Die Mischungsbereiche der wichtigsten Minerale werden als Funktion von Temperatur und Phasenvergesellschaftung diskutiert. Die Rolle von Sulfid/Arsenid Schmelzen in diesen Systemen und Beispiele für die Anwendung dieser experimentellen Ergebnisse zur Erklärung lagerstättenkundlicher Prozesse werden beschrieben.

---

---

With 6 Figures     

Comparison of isotope pairing and N2:Ar methods for measuring sediment denitrification—Assumption, modifications, and implications

Denitrification has been measured during the last few years using two different methods in particular: isotope pairing measured on a triple-collector isotopic ratio mass spectrometer and N₂:Ar ratios measured on a membrane inlet mass spectrometer (MIMS). This study compares these two techniques in short-term batch experiments. Rates obtained using the original N₂∶Ar method were up to 3 to 4 times higher than rates obtained using the isotope pairing technique due to O₂ reacting with the N₂ during MIMS analysis. Oxygen combines with N₂ within the mass spectrometer ion source forming NO⁺ which reduces the N₂ concentration. The decrease in N₂ is least at lower O₂ concentrations and since oxygen is typically consumed during incubations of sediment cores, the result is often a pseudo-increase in N₂ concentration being interpreted as denitrification activity. The magnitude of this ocygen effect may be instrument specific. The reaction of O₂ with N₂ and the subsequent decrease in N₂ was only partly correctly using an O₂ correction curve for the relationship between N₂ and O₂ concentrations. The O₂ corrected N₂∶Ar denitrification rates were lower, but still did not match the isotope pairing rates and the variability between replicates was much higher. Using a copper reduction column heated to 600°C to remove all of the O₂ from the sample before MIMS analysis resulted in comparable rates (slightly lower), and comparable variability between replicates, to the isotope pairing technique. The N₂:Ar technique determines the net N₂ production as the difference between N₂ production by denitrification and N₂ consumption by N-fixation, while N-fixation has little effect on the isotope pairing technique which determines a rate very close to the gross N₂ production. When the two different techniques were applied on the same sediment, the small difference in rates obtained by the two methods seemed to reflect N-fixation as also supported from measurements of ethylene production in acetylene enriched sediment cores. The N₂:Ar and isotope pairing techniques may be combined to provide simultaneous measurements of denitrification and N-fixation. Both techniques have several assumptions that must be met to achieve accurate rates; a number of tests are outlined that can be applied to demonstrate that these assumptions are being meet.     

Tveitite,a new calcium yttrium fluoride

Tveitite is a new mineral with formula of the type $\text{Ca}{}_{\mathrm{1?x}}\text{(}\text{Y, RE}\text{)}{}_{\mathrm{x}}\text{F}{}_{\mathrm{2+x}}\text{where}\text{x}$ is approximately 0.3. It is found in a cleavelandite pegmatite at Høydalen in Tørdal, Telemark, S. Norway. The sub-cell is thought to be monoclinic, $\text{a}\text{′=3.924,}\text{b}\text{′=3.893,}\text{c}\text{′=5.525, ß=90°26′,}\text{Z}\text{=2}$. The structure is very similar to that of fluorite and can be described in terms of a pseudo-cubic cell $\text{[1}\text{1}\text{0]}{}_0\text{= 5.527, [110]}{}_0\text{= 5.527,}\text{c}\text{= 5.525, α = 90°18′, γ = 89°37′}$ which contains approximately 1[YCa₃F₉]. The mineral shows twinning in at lest three different directions giving a grating structure probably due to high-low inversion. DTA studies show an inversion point at about 670°C. Material heated above this temperature gives X-ray diffraction patterns corresponding to yttrofluorite (a₀ 5.528). The effect of trivalent ions on the stability of fluorite is discussed.