Dolomite textures in the Upper Cretaceous carbonate-hosted Pb–Zn deposits,Zakho, Northern Iraq

In the northeast of Zakho City, Northern Iraq, the host rocks of Pb–Zn deposits are composed predominantly of dolomites with subordinate dolomitic limestone intervals. This study is focused on the dolomites of the Bekhme Formation (Upper Campanian) carbonate-hosted Pb–Zn deposits. The amount of dolomites, however, increases toward the mineralized zone. Dolomites are dominated by replacement dolomite with minor dolomite cements. Petrography study allowed identification of six different dolomite textures. These are (1) fine crystalline, planar-s (subhedral) dolomite, RD1; (2) medium to coarse crystalline, planar-e (euhedral) to planar-s (subhedral) dolomites, RD2; (3) medium crystalline, planar-s (subhedral) to nonplanar-a (anhedral) dolomites, RD3; (4) coarse crystalline, planar-s (subhedral) to nonplanar-a (anhedral) dolomites, RD4; (5) planar (subhedral) void-filling dolomite cements, CD1; and (6) nonplanar (saddle) void-filling dolomite, CD2. The RD1, RD2, RD3, and RD4 dolomite textures are replacive in origin and are volumetrically the most important types, whereas CD1 and CD2 dolomites with sparry calcite are commonly cements that fill the open spaces. Although the dolomites of the Bekhme Formation are not macroscopically observed in the field, their different types are easily distinguished by petrographic examination and scanning electron microscopy. It was observed that the dolomites of the Bekhme Formation are formed in two different diagenetic stages: the early diagenetic from mixing zone fluids at the tidal–subtidal (reef) environments and the late diagenetic from basinal brines which partially mixed with hydrothermal fluids at the shallow-deep burial depths. The latter occurs often with sphalerite, galena, and pyrite within mineralized zone. These dolomite types are associated base-metal mineralization (Mississippi Valley type).     

Biomarkers in croakers Micropogonias furnieri (Teleostei: Sciaenidae) from polluted and non-polluted areas from the Patos Lagoon estuary (Southern Brazil): evidences of genotoxic and immunological effects

Biomarkers of exposure and effect of pollutants were analyzed in croakers Micropogonias furnieri (Teleostei: Sciaenidae) captured in winter and summer in a polluted and in a non-polluted site at the Patos Lagoon estuary (Southern Brazil). Catalase and glutathione S-transferase activities (exposure biomarkers) and lipid peroxidation (effect biomarker) were analyzed in liver samples. Other two effect biomarkers were also studied: blood cells DNA damage (through comet assay and micronucleus test) and respiratory burst measurements. In a broad view, results point to an important seasonal variation of the biochemical biomarkers analyzed. However, data obtained clearly indicate that croakers collected in winter at the polluted site were subjected to a level of clastogenic agents sufficient to generate irreversible genetic damages (mutations) and impair the fish immune system.     

Assessing the impacts of uncontrolled artesian flows on the management of groundwater resources in the Jordan Valley

The deep wells drilled along the eastern escarpment of the Jordan Valley penetrate confined aquifers that produce thermal and mineralized artesian water. Uncontrolled flows from poorly constructed and uncapped artesian wells over the last 30 years have caused the deterioration of the quality of shallow groundwater and surface water. They also have been accelerating the discharge of saline water from deep aquifers and have caused the loss of shallow fresh groundwater resources through the downward percolation of fresh water to replace the extracted deep salty groundwater. A lack of adequate controls on the construction and maintenance of artesian wells is leading to widespread water quality problems in the region, which limits the ability of future generations to access high-quality water, a clear breach of the principle of intergenerational equity.