Perthite microstructure in magmatic alkali feldspar with oscillatory zoning; Weinsberg Granite, Upper Austria

Feldspar megacrysts from the Weinsberg granite (Moldanubian Zone) show oscillatory zoning with respect to the albite- and orthoclase components. All growth zones show perthitic exsolutions which take the form of bleb- and lens shaped albite-rich precipitates in an orthoclase-rich host. The average sizes and shapes of the precipitates show systematic variation with the integrated bulk compositions of the respective growth zones. The precipitates are abundant and relatively small in growth zones with intermediate bulk composition (Or50Ab41An09 - Or80Ab18An02), and they are less abundant and larger in more orthoclase-rich zones (Or88Ab11An01). Small precipitates have a relatively high aspect ratio, whereas the large precipitates in the potassium-rich zones are more spherical. The relation between microstructure and integrated bulk composition suggests that exsolution and subsequent growth and coarsening occurred by different mechanisms in the respective growth zones. Numerical modeling shows that rapid growth of precipitates over extended periods of time and attainment of relatively large final size is favored, if only few nuclei are formed in an oversaturated host. In contrast, precipitates can grow rapidly only over limited time intervals and remain relatively small, if abundant nuclei are present. During cooling of the oscillatorily zoned alkali-feldspar, exsolution started at relatively high temperatures in growth zones of intermediate integrated bulk composition as compared to exsolution in the more orthoclase-rich growth zones. Irrespective of whether exsolution occurred by spinodal decomposition or by nucleation at relatively high temperatures in the growth zones of intermediate integrated bulk composition, it produced abundant nuclei and resulted in relatively small precipitates. In contrast, comparatively few nuclei were formed in the orthoclase-rich growth zones resulting in large precipitates. The Na/K partitioning between precipitates and the host is independent of the integrated bulk composition of the respective growth zone reflecting re-equilibration during cooling down to relatively low temperatures (<?400°C). The shape of the precipitates probably has evolved from an initially lamellar or spindle-like geometry with high aspect ratio to more isometric, spheroidal shapes during precipitate growth and coarsening. Host/precipitate interfaces served as fluid pathways during late stage deuteric alteration.     

Soil acidity adaptive control problem

Problem of soil acidity regularization is modeled as stochastic adaptive control problem with a linear difference equation of the dynamics of a field pH level. Stochastic component in the equation represents an individual time variability of soil acidity of an elementary section. We use Bayesian approach to determine a posteriori probability density function of the unknown parameters of the stochastic transition process. The Kullback–Leibler information divergence is used as a measure of difference between true distribution and its estimation. Algorithm for the construction of an adaptive stabilizing control in such a linear control system is proposed in the paper. Numerical realization of the algorithm is represented for a problem of a field soil acidity control.     

Petrological and experimental evidence for differentiation of water-rich magmas beneath St. Kitts,Lesser Antilles

St. Kitts lies in the northern Lesser Antilles, a subduction-related intraoceanic volcanic arc known for its magmatic diversity and unusually abundant cognate xenoliths. We combine the geochemistry of xenoliths, melt inclusions and lavas with high pressure–temperature experiments to explore magma differentiation processes beneath St. Kitts. Lavas range from basalt to rhyolite, with predominant andesites and basaltic andesites. Xenoliths, dominated by calcic plagioclase and amphibole, typically in reaction relationship with pyroxenes and olivine, can be divided into plutonic and cumulate varieties based on mineral textures and compositions. Cumulate varieties, formed primarily by the accumulation of liquidus phases, comprise ensembles that represent instantaneous solid compositions from one or more magma batches; plutonic varieties have mineralogy and textures consistent with protracted solidification of magmatic mush. Mineral chemistry in lavas and xenoliths is subtly different. For example, plagioclase with unusually high anorthite content (An_≤100) occurs in some plutonic xenoliths, whereas the most calcic plagioclase in cumulate xenoliths and lavas are An₉₇ and An₉₅, respectively. Fluid-saturated, equilibrium crystallisation experiments were performed on a St. Kitts basaltic andesite, with three different fluid compositions (XH₂O = 1.0, 0.66 and 0.33) at 2.4 kbar, 950–1025 °C, and fO₂ = NNO ? 0.6 to NNO + 1.2 log units. Experiments reproduce lava liquid lines of descent and many xenolith assemblages, but fail to match xenolith and lava phenocryst mineral compositions, notably the very An-rich plagioclase. The strong positive correlation between experimentally determined plagioclase-melt Kd_Ca–Na and dissolved H₂O in the melt, together with the occurrence of Al-rich mafic lavas, suggests that parental magmas were water-rich (> 9 wt% H₂O) basaltic andesites that crystallised over a wide pressure range (1.5–6 kbar). Comparison of experimental and natural (lava, xenolith) mafic mineral composition reveals that whereas olivine in lavas is predominantly primocrysts precipitated at low-pressure, pyroxenes and spinel are predominantly xenocrysts formed by disaggregation of plutonic mushes. Overall, St. Kitts xenoliths and lavas testify to mid-crustal differentiation of low-MgO basalt and basaltic andesite magmas within a trans-crustal, magmatic mush system. Lower crustal ultramafic cumulates that relate parental low-MgO basalts to primary, mantle -derived melts are absent on St. Kitts.     

Batisite,Na2BaTi2(Si4O12)O2, from Inagli massif,Aldan, Russia: crystal-structure refinement and high-temperature X-ray diffraction study

Mineralogy and Petrology - The crystal structure of batisite, Na2BaTi2 (Si4O12)O2, from the Inagli massif (Aldan, Yakutia, Russia) was refined to R 1&nbsp;=&nbsp;0.032 for 1449 unique...     

Dynamic of Sea Water Interface using Hydrochemical Facies Evolution Diagram

This paper analyzes the results of a theoretical simulation of sea water intrusion and its dynamics. The assignment of hydrochemical facies identifies whether the aquifer is in the phase of sea water intrusion or freshening, indicating the status of the aquifer in terms of the advance or regression of the saline front. A new multi-rectangular diagram is proposed that aids interpretation of these important processes through the representation and evolution of hydrochemical facies (hydrochemical facies evolution diagram, HFE-D). As an example, the HEF-D is applied to an alluvial aquifer in the Vinaroz-Peñíscola Plain (Spain), where Ca-Cl facies characterize the sea water intrusion phase, while Na-MixHCO₃/MixSO₄ facies characterize a freshening stage.     

Bottom sediments of the oldest reservoir in Moscow region

The methodological features and results of two soil surveys of the Senezh Reservoir carried out in 1992 and 2006 as a part of multidisciplinary limnological studies of this large recreation water body with the aim to monitor its ecological state and prepare recommendations for water protection measures are analyzed     

Land Cover Change Characteristics of North-South Transect in Northeast Asia from 2001 to 2012

Northeast Asia is an area with relative concentrations of resources, a complex ecological environment pattern, and a marked human-land contrast relationship. This area has significance for analyzing land cover patterns and variations for regional sustainable development among the trans-boundary areas of China, Russia, and Mongolia. In this paper, the transect analysis research tool and transfer matrix method are used to capture the regional land cover change characteristics by using Moderate Resolution Imaging Spectroradiometer(MODIS) datasets recorded from 2001 to 2012.The spatial distribution results show that forests have increased dramatically, cropland increased marginally, and grassland and shrubs decreased totally. The inter-annual variation, results show a steady and slowly increasing trend for grassland and shrubs, dramatic fluctuation features with an increasing trend for forest land, and zigzag wave changing characteristic for cropland. The total land use dynamic degree (TLUDD)was steady, with an overall slightly increasing trend.     

Using ocean quahog (<Emphasis Type="Italic">Arctica islandica</Emphasis>) shells to reconstruct palaeoenvironment in Öresund,Kattegat and Skagerrak,Sweden

Shells of Arctica islandica collected between 1884 and 2004 from Öresund, Kattegat and Skagerrak (Swedish West Coast) were used to monitor local climate variations and the influence of human activities on the local environment. For this purpose, we analysed the growth, structure and chemical composition of these shells and compared them with shells collected from Kiel Bay, Norway and Iceland. The growth rate of the studied shells registers an NAO periodicity of ca 8 years. However, the observed signal is weak because of other environmental interferences that are either of natural or anthropogenic origin. For example, the oxygen isotope ratios show temperature fluctuation, but also the influx of low salinity water. Higher contents of S, N, Cu, Zn, As, Cd and P in shell portions formed during the last century are related to human activities such as mining and industrial development. Our study indicates that in order to use Arctica shells as archives of climate change it is necessary to study the full range of environmental data that is recorded in the shells by using a multi element and isotope approach in combination with different analytical techniques including investigation of growth rates and shell structure.     

An OLS regression model for context-aware tile prefetching in a web map cache

The increasing popularity of web map services has motivated the development of more scalable services in the spatial data infrastructures. Tiled map services have emerged as a scalable alternative to traditional map services. Instead of rendering map images on the fly, a collection of pre-generated image tiles can be served very fast from a server-side cache. However, during the start-up of the service, the cache is initially empty and users experience a poor quality of service. Tile prefetching attempts to improve hit rates by proactively fetching map images without waiting for client requests.

While most popular prefetching policies in traditional web caching consider only the previous access history to make predictions, significant improvements could be achieved in web mapping by taking into account the background geographic information.

This work proposes a regressive model to predict which areas are likely to be requested in the future based on spatial cross-correlation between an unconstrained catalog of geographic features and a record of past cache requests. Tiles that are anticipated to be most frequently requested can be pre-generated and cached for faster retrieval. Trace-driven simulations with several million cache requests from two different nation-wide public web map services in Spain demonstrate that accurate predictions and performance gains can be obtained with the proposed model.