A sulfur budget for the Black Sea anoxic zone

A budget for the sulfur cycle in the Black Sea is proposed which incorporates specific biogeochemical process rates. The average sulfide production in the water column is estimated to be 30–50 Tg yr⁻¹, occurring essentially in the layer between 500 and 2000 m. About 3.2–5.2 Tg sulfide yr⁻¹ form during sulfate reduction in surface sediments of the anoxic zone. Total sulfur burial in anoxic sediments of 1 Tg yr⁻¹ consists of 10–70% (ca. 40–50% is the average) water column formed (syngenetic) component, the rest being diagenetic pyrite. As a maximum, between 3 and 5 Tg yr⁻¹ contribute sulfide to the bottom water or diffuse downward in the sediment. About 20–50 Tg yr⁻¹ sulfide is oxidized mostly at the chemocline and about 10–20% of this amount (4.4–9.2 Tg yr⁻¹) below the chemocline by the oxygen of the Lower Bosphorus Current. A model simulating the vertical distribution of sulfide in the Black Sea water column shows net consumption in the upper layers down to ca. 500 m, essentially due to oxidation at the chemocline, and net production down to the bottom. On the basis of the calculated budget anoxic conditions in the Black Sea are sustained by the balance between sulfide production in the anoxic water column and oxidation at the chemocline. On average the residence time of sulfide in the anoxic zone is about 90–150 yr, comparable to the water exchange time between oxic and anoxic zones. Hydrophysical control on the sulfur cycle appears to be the main factor regulating the extent of anoxic conditions in the Black Sea water column, rather than rates of biogeochemical processes.     

On an instability mechanism in a stably stratified atmospheric layer over a moistened surface

In air stratified by a specific humidity gradient, the vertical motions result in variations in specific humidity (mixing ratio) near the underlying surface. This, in turn, causes a variation of evaporation from the surface, resulting in horizontal thermal inhomogeneities on the surface, which under certain conditions can strengthen the initial vertical motions. The linear problem of the stability of the system under consideration is solved in this paper, boundaries of the unstable region are defined, and specific values of growth rates of disturbances are investigated. The estimates show that even in a density-stratified atmospheric layer over a moist surface, rapid development of disturbances with horizontal scales of several hundred metres is possible. The horizontal sizes of the most rapidly growing modes, as a rule, are an order of magnitude larger than the vertical sizes. The possibility of observing this instability under natural conditions is discussed.     

Approximate analytical solution of the nonlinear problem of a flow over a thermally inhomogeneous underlying surface

Summary The problem of the thermal circulation over the underlying surface, has been studied analytically for the case when the temperature of the underlying surface depends linearly on one of the horizontal coordinates. A horizontal pressure gradient is specified at the upper boundary of the medium horizontal layer (that has been rotating around the vertical axis) being under consideration, and this fact provides the existence of the background horizontal flow. The problem is essentially nonlinear, since, first, the heat advection, second, the square friction and the heat exchange at the underlying surface are taken into account. The solution depends on three non-dimensional parameters that are determined by the absolute values of the specified horizontal temperature and pressure gradients and by the angle between these vectors. In dependence on the values of the above mentioned parameters the solution properties may be very different. When the horizontal temperature gradient is absent, the solution is a generalization of the Ekman boundary layer classical theory for a case of the nonlinear friction against the underlying surface. The temperature and pressure fields essentially depend on the existence or absence of the background motion velocity component in the direction of the temperature horizontal gradient.With 2 Figures     

Magnetic flux tubes — nonlinear strings in relativistic magnetohydrodynamics

A special Lagrangian coordinate system is introduced, in which the magnetic flux tube is the main object of investigation. The flux tube is shown to behave as a nonlinear relativistic string in relation to tangential force. General and particular variational principles are also discussed. With the introduction of a Lagrangian coordinate system the relativistic magnetohydrodynamic equation of motion reduces to a set of nonlinear string equations. From these results it follows that a highly conductive plasma with a frozen-in magnetic field can be considered as a gas of nonlinear strings interacting through pressure forces. A method is developed which allows the multi-dimensional nonlinear problems of RMHD (relativistic MHD) with boundary layers to be reduced to a set of two-dimensional problems for flux tubes, i.e., nonlinear strings.     

Evaluation of Simulated CO_2 Concentrations from the CarbonTracker-Asia Model Using In-situ Observations over East Asia for 2009–2013

The CarbonTracker(CT) model has been used in previous studies for understanding and predicting the sources, sinks, and dynamics that govern the distribution of atmospheric CO_2 at varying ranges of spatial and temporal scales. However, there are still challenges for reproducing accurate model-simulated CO_2 concentrations close to the surface, typically associated with high spatial heterogeneity and land cover. In the present study, we evaluated the performance of nested-grid CT model simulations of CO_2 based on the CT2016 version through comparison with in-situ observations over East Asia covering the period 2009–13. We selected sites located in coastal, remote, inland, and mountain areas. The results are presented at diurnal and seasonal time periods. At target stations, model agreement with in-situ observations was varied in capturing the diurnal cycle. Overall, biases were less than 6.3 ppm on an all-hourly mean basis, and this was further reduced to a maximum of 4.6 ppm when considering only the daytime. For instance, at Anmyeondo, a small bias was obtained in winter, on the order of 0.2 ppm. The model revealed a diurnal amplitude of CO_2 that was nearly flat in winter at Gosan and Anmyeondo stations, while slightly overestimated in the summertime. The model's performance in reproducing the diurnal cycle remains a challenge and requires improvement. The model showed better agreement with the observations in capturing the seasonal variations of CO_2 during daytime at most sites, with a correlation coefficient ranging from 0.70 to 0.99. Also, model biases were within-0.3 and 1.3 ppm, except for inland stations(7.7 ppm).     

Integrated cave drip monitoring for epikarst recharge estimation in a dry Mediterranean area,Sif Cave,Israel

Understanding recharge mechanisms and controls in karst regions is extremely important for managing water resources because of the dynamic nature of the system. The objective of this study was to evaluate water percolation through epikarst by monitoring water flow into a cave and conducting artificial irrigation and tracer experiments, at Sif Cave in Wadi Sussi, Israel from 2005 through 2007. The research is based on continuous high‐resolution direct measurements of both rainfall and water percolation in the cave chamber collected by three large PVC sheets which integrate drips from three different areas (17, 46, and 52 m²). Barrels equipped with pressure transducers record drip rate and volume for each of the three areas. The combined measured rainfall and cave data enables estimation of recharge into the epikarst and to better understand the relationship of rainfall‐recharge. Three distinct types of flow regimes were identified: (1) ‘Quick flow’ through preferential flow paths (large fractures and conduits); (2) ‘Intermediate flow’ through a secondary crack system; and (3) ‘Slow flow’ through the matrix. A threshold of ～100 mm of rain at the beginning of the rainy season is required to increase soil water content allowing later rainfall events to percolate deeper through the soil and to initiate dripping in the cave. During winter, as the soil water content rises, the lag time between a rain event and cave drip response decreases. Annual recharge (140–160 mm in different areas in the cave) measured represents 30–35% of annual rainfall (460 mm). Copyright © 2011 John Wiley & Sons, Ltd.     

Quasi-satellite orbits in the general context of dynamics in the 1:1 mean motion resonance: perturbative treatment

Our investigation is motivated by the recent discovery of asteroids orbiting the Sun and simultaneously staying near one of the Solar System planets for a long time. This regime of motion is usually called the quasi-satellite regime, since even at the times of the closest approaches the distance between the asteroid and the planet is significantly larger than the region of space (the Hill’s sphere) in which the planet can hold its satellites. We explore the properties of the quasi-satellite regimes in the context of the spatial restricted circular three-body problem “Sun–planet–asteroid”. Via double numerical averaging, we construct evolutionary equations which describe the long-term behaviour of the orbital elements of an asteroid. Special attention is paid to possible transitions between the motion in a quasi-satellite orbit and the one in another type of orbits available in the 1:1 resonance. A rough classification of the corresponding evolutionary paths is given for an asteroid’s motion with a sufficiently small eccentricity and inclination.     

Evolution of the Oort cloud angular momentum: Numerical simulation

This paper considers the evolution of a flat svarm of cometary bodies (under the effect of the passage of stars), initially moving in one direction along the circular orbits with radii 1.4×10⁴<r<2×10⁴ AU and along elliptic orbits with semi-major axes 5×10³<a<1×10⁴ AU and with perihelia within 50<q<100 AU. Numerical simulation shows that the original flat belt of comets is thermalizing. Its root-mean-squarez-coordinate grows withr. A cometary cloud forms with a dense flattened inner core and a rarefied halo (the Oort cloud proper). The value =N _core/N _halo varies within a wide range (up to the order of magnitude) depending on the model used (N _core andN _halo are the numbers of comets in the core and the halo, respectively).The hypothesis of a massive Oort cloud (Marochniket al., 1988) implies that the Oort cloud should have a large angular momentum. This paper employs numerical simulation to calculate Oort cloud models to which the initially flat located at the periphery of the solar nebula rotating cometary swarms is evolving in time. The loss of the initial angular momentum over the time of the Oort cloud evolution is not large.