An acidification model (MAGIC) with organic acids evaluated using whole-catchment manipulations in Norway

The results from two whole-catchment manipulation experiments in Norway are used to evaluate MAGIC (Model of Acidification of Groundwater In Catchments), a model of ecosystem biogeochemical response to acid deposition. MAGIC is an aggregated catchment-scale model of acidification that has been widely used in assessment activities in Europe and North America. The experiments involved artificial decrease (Reversing Acidification In Norway, RAIN) and increases (Humid Lake Acidification Experiment, HUMEX) in acidic deposition. Runoff from both sites is influenced by moderate levels of organic acids. At each site the model was calibrated to the control catchment and then applied to the manipulated catchments with only minor adjustments. The major responses in runoff chemistry to the manipulations were closely simulated by the model. Differences between simulated and observed volume-weighted annual average concentrations of all major ions were less than ±6 μequiv 1⁻¹ for the entire 4–8 year period of prediction. Trends in response to the manipulations were correctly simulated. Most of the residual error resulted from an inability of the model to reproduce the year-to-year variability (noise) around the trends. Although such model evaluations cannot ‘prove’ the correctness of the model structure, good fits to experimental data increase confidence in model applications for assessment and management purposes. Evaluations of this sort can also identify aspects of the model that need further development. For MAGIC, these are primarily a need for improvement in the calibration of aluminium solubility and a better process basis for nitrogen dynamics.     

The Cerchar Abrasivity Index and its relation to rock mineralogy and petrography

SummaryThe Cerchar Abrasivity Index and Its Relation to Rock Mineralogy and Petrography To evaluate the relation between the Cerchar Abrasivity Index (a parameter used in calculating advance rates of full face tunnelling machines) and the petrography of the rocks, measurements were made on minerals and monomineralic rocks. From these data a theoretical abrasivity (quartz equivalence) can be calculated for every rock composition. From the comparison of the theoretical and experimentally determined abrasivity the influence of fabric and other factors besides mineralogical composition were deduced.With 2 Figures     

Hydrothermal synthesis of pyroxenoids in the system MnSiO3-CaSiO3 at Pf=2 kb

Pyroxenoids on the join MnSiO₃-CaSiO₃ were synthesized from (Mn, Ca)-carbonate solid solutions and SiO₂ in CO₂-H₂O mixtures at a total pressure of 2 kb. The type of structure found (pyroxmangite, rhodonite, bustamite or wollastonite) is mainly dependent on the Mn/Ca ratio, but also to a lesser extent on temperature. Johannsenite-type structures were encountered at low temperatures over a wide compositional range. It has been possible to convert the pyroxenoids pyroxmangite → rhodonite, rhodonite → bustamite, bustamite → wollastonite, and johannsenite → bustamite or wollastonite with increase of temperature, but not the reverse. The compositional ranges of the synthetic pyroxenoids are very similar to those found in natural pyroxenoids.     

Elimination of the water-layer response from multi-component source and receiver marine electromagnetic data

This paper presents the theory to eliminate from the recorded multi‐component source, multi‐component receiver marine electromagnetic measurements the effect of the physical source radiation pattern and the scattering response of the water‐layer. The multi‐component sources are assumed to be orthogonally aligned above the receivers at the seabottom. Other than the position of the sources, no source characteristics are required. The integral equation method, which for short is denoted by Lorentz water‐layer elimination, follows from Lorentz' reciprocity theorem. It requires information only of the electromagnetic parameters at the receiver level to decompose the electromagnetic measurements into upgoing and downgoing constituents. Lorentz water‐layer elimination replaces the water layer with a homogeneous half‐space with properties equal to those of the sea‐bed. The source is redatumed to the receiver depth. When the subsurface is arbitrary anisotropic but horizontally layered, the Lorentz water‐layer elimination scheme greatly simplifies and can be implemented as deterministic multi‐component source, multi‐component receiver multidimensional deconvolution of common source gathers. The Lorentz deconvolved data can be further decomposed into scattering responses that would be recorded from idealized transverse electric and transverse magnetic mode sources and receivers. This combined electromagnetic field decomposition on the source and receiver side gives data equivalent to data from a hypothetical survey with the water‐layer absent, with idealized single component transverse electric and transverse magnetic mode sources and idealized single component transverse electric and transverse magnetic mode receivers. When the subsurface is isotropic or transverse isotropic and horizontally layered, the Lorentz deconvolution decouples into pure transverse electric and transverse magnetic mode data processing problems, where a scalar field formulation of the multidimensional Lorentz deconvolution is sufficient. In this case single‐component source data are sufficient to eliminate the water‐layer effect. We demonstrate the Lorentz deconvolution by using numerically modeled data over a simple isotropic layered model illustrating controlled‐source electromagnetic hydrocarbon exploration. In shallow water there is a decrease in controlled‐source electromagnetic sensitivity to thin resistors at depth. The Lorentz deconvolution scheme is designed to overcome this effect by eliminating the water‐layer scattering, including the field's interaction with air.     

Biochemical biomarkers in adult female perch (Perca fluviatilis) in a chronically polluted gradient in the Stockholm recipient (Sweden)

A battery of biochemical biomarkers and the SigmaPCB concentration in adult female perch (Perca fluviatilis) verified an aquatic pollution gradient with the city of Stockholm (Sweden) as a point source of anthropogenic substances. The investigation included both an upstream gradient, 46 km westwards through Lake M?laren, and a downstream gradient, 84 km eastwards through the Stockholm archipelago. Besides the main gradient from Stockholm, there were strong indications of pollution coming from the Baltic Sea. The results indicated a severe pollution situation in central Stockholm, with poor health status of the perch, characterised by increased specific EROD activity in the liver, increased liver EROD somatic index, decreased AChE activity in the muscle, increased amount of DNA adducts in the liver, and a high concentration of biliary 1-pyrenol. In addition, laboratory exposure to common EROD inducers elicited an abnormal response, suggestive of chronic intoxication.     

Recent sediments, sediment accumulation and carbon burial at Goban Spur, N.W. European Continental Margin (47–50°N)

To quantify recent sediment accumulation, carbon fluxes and cycling, three N.W. European Continental Margin transects on Goban Spur and Meriadzek Terrace were extensively studied by repeated box- and multicore sampling of bottom sediments. The recent sediment distribution and characteristics appear directly related to the near-bed hydrodynamic regime on the margin, which at the upper slope break on the Goban Spur results in along-slope and periodic off-slope directed transport of particles, possibly by entrainment of particles in a detached bottom or intermediate nepheloid layer. From the shelf to the abyssal plain the surface sediments on the Goban Spur change from terrigenous sandy shelf sediments into clayey silts. ²¹⁰Pb activity decreases exponentially down core, reaching a stable background value at 10 cm (shallower stations) to 5 cm (deeper stations) sediment depth. ²¹⁰Pb profiles of repeatedly sampled stations indicate negligible annual variability of mixing and flux. The ²¹⁰Pb_xs flux to the sediment shows a decreasing trend with increasing water depth. Below about 2000 m the average ²¹⁰Pb_xs flux is about 0.3 dpm cm⁻² y⁻¹, a third of the fluxes measured on the shelf and upper slope stations. Sediment mixing rates (D_b) correlate with macro- and meiofaunal density changes and are within the normal oceanic ranges. Lower mixing rates on the lower slope likely reflect lower organic carbon fluxes there. Mass accumulation rates on Meriadzek Terrace are at maximum 80 g m⁻² y⁻¹, almost twice as high as at Goban Spur stations of comparable depth. A minimum accumulation rate of 16.6 g m⁻² y⁻¹ is found at the Goban Spur upper slope break. Organic carbon burial rates are low compared to other margins and range from a lowest value of 0.05 g m⁻² y⁻¹ at the upper slope break to 0.11 g m⁻² y⁻¹ downslope. A maximum organic carbon burial rate of 0.41 g m⁻² y⁻¹ is found on Meriadzek Terrace. Carbonate burial rates increase along the northern transect from the shelf (13 g m⁻² y⁻¹) via a low (9.3 g m⁻² y⁻¹) on the upper slope break to the deep sea (30.7 g m⁻² y⁻¹). Carbonate burial is highest on Meriadzek Terrace (44.5 g m⁻² y⁻¹). The N.W. European Margin at Goban Spur and Meriadzek Terrace cannot be considered a major carbon depocenter.     

Climate variability and physical forcing of the food webs and the carbon budget on panarctic shelves

Brief overviews of the Arctic’s atmosphere, ice cover, circulation, primary production and sediment regime are given to provide a conceptual framework for considering panarctic shelves under scenarios of climate variability. We draw on past ‘regional’ studies to scale-up to the panarctic perspective. Within each discipline a synthesis of salient distributions and processes is given, and then functions are noted that are critically poised and/or near transition and thereby sensitive to climate variability and change. The various shelf regions are described and distinguished among three types: inflow shelves, interior shelves and outflow shelves. Emphasis is on projected climate changes that will likely have the greatest impact on shelf-basin exchange, productivity and sediment processes including (a) changes in wind fields (e.g. currents, ice drift, upwelling and downwelling); (b) changes in sea ice distribution (e.g. radiation and wind regimes, enhanced upwelling and mixing, ice transport and scour resuspension, primary production); and (c) changes in hydrology (e.g. sediment and organic carbon delivery, nutrient supplies). A discussion is given of the key rate-controlling processes, which differ for different properties and shelf types, as do the likely responses; that is, the distributions of nutrients, organic carbon, freshwater, sediments, and trace minerals will all respond differently to climate forcing.A fundamental conclusion is that the changes associated with light, nutrients, productivity and ice cover likely will be greatest at the shelf-break and margins, and that this forms a natural focus for a coordinated international effort. Recognizing that the real value of climate research is to prepare society for possible futures, and that such research must be based both on an understanding of the past (e.g. the palaeo-record) as well as an ability to reliably predict future scenarios (e.g. validated models), two recommendations emerge: firstly, a comprehensive survey of circumpolar shelf-break and slope sediments would provide long-term synchronous records of shelf-interior ocean exchange and primary production at the shelf edge; secondly, a synoptic panarctic ice and ocean survey using heavy icebreakers, aircraft, moorings and satellites would provide the validation data and knowledge required to properly model key forcing processes at the margins.     

A new approach to interpreting Rock-Eval S2 and TOC data for kerogen quality assessment

A simple method for application in source potential mapping is used to assess the original oil and gas potentials in source rock horizons based upon Rock-Eval potential (S₂) and total organic carbon (TOC) values. The method assumes that kerogens consist of mixtures of end-members with assigned hydrogen index values. Based on suggested algorithms, the average amounts of oil-prone, gas-prone and inert organic material over source rock intervals are determined in TOC units. The method uses regression lines from plots of remaining hydrocarbon potentials (S₂) versus total organic carbon (TOC), and “quick-look” transparent overlays are used to read the appropriate kerogen mixture.Mineral matrix effects during pyrolysis, when strong, can cause erroneous results. This effect which occurs for oil-prone kerogens and adsorptive minerals can cause problems particularly for lean samples (S₂ = 0–3 mg HC/g rock) whilst the errors for richer samples are less.The method is applied on three sections of Upper Jurassic organic-rich rocks from the Danish North Sea sector, which are at different maturity stages. One of these sections is dominated by gas-prone material, one is dominated by oil-prone material and the third section contains a mixture of oil- and gas-prone material.The method has been compared with other methods that split kerogens in oil and gas generating potential and has given reasonable results.Experience using the method and a presented example suggest that sedimentological, system tract information may be derived from S₂ to TOC cross-plots. A constructed modelling example suggests that the end-member concept used in this approach may be used in forward type source rock prediction models when combined with sedimentological models. The resulting S₂–TOC plots can be used in order to check the forward modelling results against observed values.