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41.
Edward R.D. Scott 《Geochimica et cosmochimica acta》1978,42(9):1447-1458
The primary fractionation process in iron meteorites is that responsible for the distribution of elements between the groups, most notably Ga and Ge, which show concentration ranges of 103 and 104 respectively. To investigate the cause of the primary fractionation, concentrations of 16 elements were converted to relative abundances by dividing the element/Ni ratio by the CI chondrite ratio. These abundances were plotted on logarithmic graphs with data for each group (except IB and IIICD) and each cluster of closely related anomalous irons averaged.Co, P, Au, As, Cu, Sb, Ge and Zn are positively correlated with Ga. For most groups (except IA, IC and IIAB) relative abundances of these elements tend to decrease from about 1 in approximately the order listed above. This is the expected order in which these elements will condense into Fe, Ni during equilibrium nebular condensation. Mean relative abundances of refractory elements in groups generally lie within a narrow range of 0.5–2, and are uncorrelated with Ga. Although the equilibrium model may be only a gross approximation, it suggests that most primary fractionation did occur during nebular condensation.The anomalous irons are essential for defining many of the primary fractionation trends. On several element-Ga graphs the displacements of the anomalous irons from the primary curves indicate that these irons experienced the same secondary fractionation process (probably fractional crystallization) that produced the trends within most groups. The anomalous irons appear to be samples from over 50 minor groups, which have similar histories to the 12 major groups. 相似文献
42.
The theoretical disk brightness temperature spectra for Uranus are computed and compared with the observed microwave spectrum. It is shown that the emission observed at short centimeter wavelengths originates deep below the region where ammonia would ordinarily begin to condense. We demonstrate that this result is inconsistent with a wide range of atmospheric models in which the partial pressure of NH3 is given by the vapor-pressure equation in the upper atmosphere. It is estimated that the ammonia mixing ratio must be less than 10?6 in the 150 to 200°K temperature range. This is two orders of magnitude less than the expected mixing ratio based on solar abundances. The evidence for this depletion and a possible explanation are discussed. 相似文献
43.
The intensities of 52 EUV emission lines from each of 9 hedgerow prominences observed at the limb with the Harvard experiment on ATM-Skylab have been compared with intensities from the interior of network cells at the center of the disk, in order to compare the prominence-corona (P-C) interface with the chromosphere-corona (C-C) transition region. The intensity ratio I
cell/I
prominence for each line varies systematically (in all of the prominences observed), with the temperature of formation of the line as T
–0.6. The density sensitive C iii (formed at T 9 × 104 K) line ratio I
1175/I
977 implies an average density 1.3 × 109 electrons cm–3 in the P-C interface and 4 times this value in the C-C transition of the cells. The total optical thickness at the head of the Lyman continuum is 10 in most of the prominences studied; in two of the prominences, however, we cannot reject the possibility that o is large. Methods of analysis of these EUV data are developed assuming both a resolved and an unresolved internal prominence structure. Although the systematic differences between the P-C interface and the C-C transition are stressed, the similarities are probably more remarkable and may be a result of fine structure in the C-C transition.Currently on leave from the Institute of Astronomy, Hawaii; at the Laboratory for Atmospheric and Space Physics, University of Colorado, Boulder, Colorado, 80309. 相似文献
44.
45.
Jacco C. Kromkamp Edward P. Morris Rodney M. Forster Claire Honeywill Scott Hagerthey David M. Paterson 《Estuaries and Coasts》2006,29(2):183-196
Estimating biomass of microphytobenthos (MPB) on intertidal mud flats is extremely difficult due to their patchy occurrence,
especially at the scale of an entire mud flat. We tested two optical approaches that can be applied in situ: spectral reflectance
and chlorophyll fluorescence. These two approaches were applied in 4 European estuaries with different sediment characteristics.
At each site, paired replicate measurements of hyperspectral reflectance, chlorophyll fluorescence (after 15 min dark adaptation,
Fo
15), sediment water content, and chlorophylla concentrations were taken (including breakdown products: [chla+phaeo]). Sediments were further characterized by grain size and organic content analysis. The spectral signatures of tidal
flats dominated by benthic microalgae, mainly diatoms, could be easily distinguished from sites dominated by macrophytes;
we present a 3 waveband algorithm that can be used to detect the presence of macrophytes. The normalized difference vegetation
index (NDVI) was found to be most strongly correlated to sediment [chla+phaeo], except for the predominantly sandy Sylt stations. Fo
15 was also significantly correlated to sediment [chla+phaeo] in all but one grid (Sylt grid A). Our results suggest that the functional relationships (i.e., the slopes) between
NDVI or fluorescence and [chla+ phaeo] were not significantly different in the muddier grids, although the intercepts could differ significantly, especially
for Fo
15. This suggests a mismatch of the optical depth seen by the reflectometer or fluorometer and the depth sampled for pigment
analysis. NDVI appears to be a robust proxy for sediment [chla+phaeo] and can be used to quantify MPB biomass in muddy sediments of mid latitude estuaries. 相似文献
46.
Gerold Morrison Edward T. Sherwood Richard Boler Joe Barron 《Estuaries and Coasts》2006,29(6):926-931
In the Tampa Bay region of Florida, extreme levels of annual and seasonal rainfall are often associated with tropical cyclones and strong El Niño episodes. We used stepwise multiple regression models to describe associations between annual and seasonal rainfall levels and annual, bay-segment mean water clarity (as Secchi depth [m]), chlorophylla (μg I?1), color (pcu), and turbidity (ntu) over a 20-yr period (1985–2004) during which estimated nutrient loadings have been dominated by non-point sources. For most bay segments, variations in annual mean water clarity were associated with variations in chlorophylla concentrations, which were associated in turn with annual or seasonal rainfall. In two bay segments these associations with annual rainfall were superimposed on significant long-term declining trends in chlorophylla. Color was significantly associated with annual rainfall in all bay segments, and in one segment variations in color were the best predictors of variations in water clarity. Turbidity showed a declining trend over time in all bay segments and no association with annual rainfall, and was significantly associated with variations in water clarity in only one bay segment. While chlorophylla, color, and turbidity a affected water clarity to varying degrees, the effects of extreme rainfall events (El Niño events in 1998 and 2003, and multiple tropical cyclone events in 2004) on water clarity were relatively short-lived, persisting for periods of months rather than years. During the 20-yr period addressed in these analyses, declining temporal trends in chlorophylla and turbidity, produced in part by a long-term watershed management program that has focused on curtailing annual loadings of nitrogen and other pollutants, may have helped to prevent the bay as a whole from responding more adversely to the high rainfall periods that occurred in 1998 and 2003–2004. 相似文献
47.
Three experimental plots, covering the transition from the upper beach to the dune, on the North Sea coast of France were monitored at various intervals over a period of 18–24 months via high resolution terrain surveys in order to determine inter-site sand budget variability, as well as patterns and processes involved in sand exchanges between the upper beach and dune. The wind regime consists of a fairly balanced mix of moderate (80% of winds are below 8 m/s) onshore, offshore and shore-parallel winds. Sustained dune accretion over several years depends on the periodic local onshore welding of shoreface tidal banks that have developed in the storm- and tide-dominated setting of the southern North Sea. The only site where this has occurred in the recent past is Calais, where bank welding has created a wide accreting upper beach sand flat. At this site, significant sand supply from the subtidal sand bank reservoir to the upper beach flat occurred only once over the 18-month survey following a major storm. The bulk of the sand deposited over this large flat is not directly integrated into the adjacent embryo dunes by onshore winds but is progressively reworked in situ into developing dunes or transported alongshore by the balanced wind regime, thus resulting in alongshore stretching of the embryo dune system. The Leffrinckoucke site near Belgium shows moderate beach–dune mobility and accretion, while the Wissant site exhibits significant upper beach bedform mobility controlled by strong longshore currents that result in large beach budget fluctuations with little net budget change, to the detriment of the adjacent dunes. Accretion at these two sites, which are representative of the rest of the North Sea coast of France, is presently constrained by the absence of a shore-attached sand bank supply reservoir, while upper beach–dune sand exchanges are further limited by the narrow wave-affected upper beach, the intertidal morphology of bars and troughs which segments the aeolian fetch, and the moderate wind energy conditions. The balanced wind regime limits net sand mobilisation in favour of either the beach or the dune, and may explain the relatively narrow longshore morphology of the dune ridges bounding this coast. 相似文献
48.
Jakob Fjellanger Leif Srbel Henriette Linge Edward J. Brook Grant M. Raisbeck Franoise Yiou 《Geomorphology》2006,82(3-4):255-272
For more than hundred years it has been debated whether blockfields in mountain summit areas can be used to delimit the vertical extent of Pleistocene ice sheets. In this study the relationship between blockfields, developed in quartzites and sandstones on the Varanger Peninsula, northern Norway, and glacially derived features have been evaluated. Erratics and circular ablation moraines are superimposed on the blockfields and lateral meltwater channels are eroded into them. Glacial striations and other signs of glacial sculpturing are restricted to low-lying areas with channelled ice flow. Relative ages of the blockfields and the features in them are inferred, and the first measurements of in-situ produced cosmogenic nuclides from the Varanger Peninsula are reported. We conclude that the blockfields have survived underneath at least one thick, cold-based ice sheet. Thus, these blockfields cannot be used as indicators of ice-free conditions as previously suggested for southern Norway. Our results have implications for the potential for land surface preservation beneath ice sheets and for glacial reconstructions in northern Fennoscandia. 相似文献
49.
David W. Kelley Stefanie A. Brachfeld Edward A. Nater Herbert E. Wright Jr. 《Journal of Paleolimnology》2006,35(1):193-206
Sediments from Lake Pepin on the Mississippi River, southeastern Minnesota, are used as provenance tracers to assess variations
in hydrology and sediment-transport during the middle Holocene. Three rivers contribute sediment to Lake Pepin, and each catchment
is characterized by a distinctly different geologic terrain. The geochemical fingerprint for each drainage basin was determined
from the elemental composition of heavy minerals in the silt-sized fraction of modern sediment samples. Down-core elemental
abundances were compared with these fingerprints by use of a chemical-mass-balance model that apportions sediment to the source
areas. We observed a decreased contribution from the Minnesota River during the interval ~6700–5500 14C yr BP, which we attribute to decreased discharge of the Minnesota River, likely controlled by a combination of precipitation,
snow melt, and groundwater input to the river. This hydrologic condition coincides with the mid-Holocene prairie period recorded
by fossil pollen data. The occurrence of this feature in a proxy record for hydrologic variations supports the hypothesis
that the mid-Holocene prairie period reflects drier conditions than before or after in midwestern North America. 相似文献
50.
M. Catherine Eimers Andrew M. Paterson Peter J. Dillon Sherry L. Schiff Brian F. Cumming Roland I. Hall 《Journal of Paleolimnology》2006,35(1):99-109
Stable isotopic compositions and concentrations of total sedimentary sulphur (S) were determined in cores from 6 lakes in
the acid-sensitive Muskoka-Haliburton region of south-central Ontario. The isotopic composition of S in deep sediment (> ~
20 cm) was approximately constant in all lakes, and indicated a pre-industrial δ 34S value between +4.0 and +5.3‰, which is similar to current bulk deposition. Similarly, total S concentrations in deep sediment
were relatively low (1.9–5 mg S g−1 dwt) and approximately constant with depth within cores. All lakes exhibited up-core increases in total S and decreases in
δ 34S at a depth corresponding to the beginning of industrialization in the Great Lakes region ( ~ 1900), resulting in a generally
reciprocal depth pattern between total S concentration and δ 34S ratios. While initial shifts in total S and δ 34S were likely due to enhanced SO4 reduction of newly available anthropogenic SO4, both the magnitude and pattern of up-core S enrichment and shifts in δ 34S varied greatly among lakes, and did not match changes in S deposition post 1900. Differences between lakes in total S and
δ 34S were not related to any single hydrologic (e.g., residence time) or physical (e.g., catchment-area-to-lake area ratio) lake
characteristic. This work indicates that sediment cores do not provide consistent records of changes in post-industrial S
deposition in this region, likely due to redox-related mobility of S in upper sediment. 相似文献