Regional stratigraphy and distribution of epigenetic stratabound celestine, fluorite, barite and Pb–Zn deposits in the MVT province of northeastern Mexico

Northeastern Mexico hosts numerous epigenetic stratabound carbonate-hosted low-temperature hydrothermal deposits of celestine, fluorite, barite and zinc-lead, which formed by replacement of Mesozoic evaporites or carbonate rocks. Such deposits can be permissively catalogued as Mississippi Valley-type (MVT) deposits. The deposits studied in the state of Coahuila are associated with granitic and metasedimentary basement highs (horsts) marginal or central to the Mesozoic Sabinas Basin. These horsts controlled the stratigraphy of the Mesozoic basins and subsequently influenced the Laramide structural pattern. The Sabinas Basin consists of ~6,000-m-thick Jurassic to Cretaceous siliciclastic, carbonate and evaporitic series. The MVT deposits are mostly in Barremian and in Aptian-Albian to Cenomanian formations and likely formed from basinal brines that were mobilized during the Laramide orogeny, although earlier diagenetic replacement of evaporite layers (barite and celestine deposits) and lining of paleokarstic cavities in reef carbonates (Zn–Pb deposits) is observed. Fluid inclusion microthermometry and isotopic studies suggest ore formation due to mixing of basinal brines and meteoric water. Homogenization temperatures of fluid inclusions range from 45°C to 210°C; salinities range from 0 to 26 wt.% NaCl equiv., and some inclusions contain hydrocarbons or bitumen. Sulfur isotope data suggest that most of the sulfur in barite and celestine is derived from Barremian to Cenomanian evaporites. Regional geology and a compilation of metallogenic features define the new MVT province of northeastern Mexico, which comprises most of the state of Coahuila and portions of the neighboring states of Nuevo León, Durango and, perhaps extends into Zacatecas and southern Texas. This province exhibits a regional metal zonation, with celestine deposits to the south, fluorite deposits to the north and barite and Zn–Pb deposits mostly in the central part.     

Petrology of pumices of April 1993 eruption of Lascar (Atacama, Chile)

Lascar Volcano (Atacama, Chile) erupted on 18–20 April 1993. Several sub-Plinian explosions occurred, and some were mushroom-shaped. The highest column rose up to 23 km. Ash clouds crossed South America eastwards. Dacite pumice falls made of blocks and ashes were deposited on the flanks of the volcano as a result of collapsed columns. The pumice contains phenocrysts of plagioclase, enstatite, augite, biotite, magnetite and ilmenite and small crystals of apatite. The 1992 previous andesite dome inside the crater was destroyed. Banded blocks resulting from mingling of the dacitic pumice and andesite from the dome are found in the pumice flow. Both the lava dome and the pumice are representative of the Lascar high-K magma unit. Dacitic pumice is a product of crystal fractionation of the andesitic magma.     

Water determination in iron oxyhydroxides and iron ores by Karl Fischer titration

Protohematite (Fe_2?x/3(OH) _x O_3?x 1 ≤ x < 0.5) and hydrohematite (Fe_2?x/3(OH) _x O_3?x 0.5 ≤ x < 0) are iron-defective phases containing hydroxyl groups in their structures. These species were described in prior studies mainly with the aid of X-ray diffraction and Infrared spectroscopy. The existence of these phases in soils might have influence in redox processes, and they were considered as a possible water reservoir in Martian soils. In this study, we have used for the first time the Karl Fischer titration method to determine the amount of water released after heating several synthetic samples of goethite, hematite and natural iron ores at 105, 400, 600 and 900 °C. It was found that heating at 105 °C did not remove all moisture from the samples, and higher temperatures were necessary to completely remove all the absorbed water. The water contents determined at 400, 600 and 900 °C were found to be the same within the experimental errors, suggesting the inexistence of both protohematite and hydrohematite in the investigated samples. Therefore, the above-mentioned effects of these phases in soils might have to be reevaluated.     

Groundwater Level Prediction/Forecasting and Assessment of Uncertainty Using SGS and ARIMA Models: A Case Study in the Bauru Aquifer System (Brazil)

Natural Resources Research - Best water management practices should involve the prediction of the availability of groundwater resources. To predict/forecast and consequently manage these water...     

Sedimentary record of Late Paleozoic rift and break-up in Northern Gondwana: a case history from the Thini Chu Group and Tamba-Kurkur Formation (Dolpo Tethys Himalaya,Nepal)

The Gottero unit of the Northern Apennines, Italy, is representative of the sedimentary cover of the Ligure-Piemontese oceanic lithosphere. This unit consists of a thick sedimentary sequence that includes Valanginian-Santonian pelagic deposits and Campanian-early Paleocene turbiditic deposits. The latter are overlain by early Paleocene trench deposits related to frontal tectonic erosion of the accretionary wedge slope. This sequence is interpreted as recording trenchward motion of the oceanic lithosphere.

The Gottero unit records a pre-Late Oligocene, complex deformation history related to subduction and accretion events. This deformation history has developed through underthrusting (D1a), underplating (D1b and D1c) and later exhumation (D2a and D2b) episodes. The folding phase related to the main underplating sub-phase (D1b) is predated by a sub-phase (D1a) connected to rapid fluid escape and followed by a sub-phase dominated by the development of shear zones (D1c). The D1b sub-phase is characterized by similar folds and a slaty cleavage developed under P/T conditions of 0.4GPa/210°-270 °C. The D1c sub-phase, characterized by west-verging thrusts, is particularly signficative in understanding the dynamics of the Ligure-Piemontese accretionary wedge because it testifies active shortening of the Gottero unit also after its transfer to the prism. In addition, sub-phase D1c represents the transition from the sub-phases connected to accretion and the tectonics dominated by extension, characterized by parallel folds and low-to high-angle normal faults. The gravity driven extension is represented by the D2a and D2b sub-phases and can be interpreted as the result of the thicknening of the Ligure-Piemontese accretionary wedge, produced by continuous underplating at its base but also by shortening of the previously underplated units. These final tectonic events resulted in the exhumation of the Gottero unit to the surface during the Early Oligocene, when this Unit became one of the source areas of the conglomerates deposited in the Tertiary Piedmont basin.

This deformation history suggests the occurrence of a complex sequence of deformations during the transition from accretion to exhumation, even in the intermediate levels of the accretionary wedge.     

Improved imaging of a karst aquifer using focused source electromagnetic and differentially normalized method: a qualitative analysis

Geophysical investigations using conventional techniques applied to groundwater exploration can often present strong limitations involving high financial costs, complex acquisition logistics and high ambiguity in results. Dispersion of the electric current flow, induced polarization) effects, cultural noises and shallow lateral heterogeneities represent the main problems faced by geoelectric methods in these types of surveys. Moreover, elements such as intrusions and mineralization at different depths may be responsible for signal attenuation as well as high resistivity in unsaturated zones and complex three-dimensional formations or clayey zones cause variations in the electric current. The focused source electromagnetic and differentially normalized method approaches can help to solve some these issues. Aiming at a higher signal-to-noise ratio, the focused source electromagnetic method and approaches of the differentially normalized method, first applied to petroleum exploration, are tested on a groundwater target, in a karst environment sectioned by a diabase dyke. We performed the processing and analysis on real IP resistivity profiling data acquired with two-way dipole-dipole array, guided by magnetic data acquired on the same profile, mapping a diabase dyke. The inversion of focused source electromagnetic method/differentially normalized method was not performed, instead that we converted the induced polarization–resistivity data to a differential signal to qualitatively prove the presence of aquifer. Joint interpretation of focused source electromagnetic method curves and inverted two-dimensional induced polarization–resistivity sections allowed for precise delineation of a conductive zone associated with the karst aquifer, le magnetics allowed for the definition of a neighbour dyke. The techniques have great potential in the aid of groundwater exploration, contributing substantially to the reduction of interpretation ambiguity. Focused source electromagnetic method/differentially normalized method/ approaches show that a simple linear combination of the conventional geoelectric data is able to remove the geological noise and provide the vertical focusing of the electric current.     

Tectonic control of the Tejo river fluvial incision during the late Cenozoic, in Ródão—central Portugal (Atlantic Iberian border)

Staircases of strath terraces and strongly incised valleys are the most typical landscape features of Portuguese rivers. This paper examines the incision achieved during the late Cenozoic in an area crossed by the Tejo river between the border with Spain and the small town of Gavião. In the more upstream reach of this area, the Tejo crosses the Ródão tectonic depression, where four levels of terraces are distinguished. During the late Cenozoic fluvial incision stage, the Ródão depression underwent less uplift than the adjacent areas along the river. This is reflected by the greater thicknesses and spatial extent of the terraces; terrace genesis was promoted by impoundment of alluvium behind a quartzitic ridge and the local presence of a soft substratum. Outside this tectonic depression, the Tejo has a narrow valley incised in the Hercynian basement, with some straight reaches that probably correspond to NE–SW and NNW–SSE faults, the terraces being nearly absent. Geomorphological evidence of tectonic displacements affecting the Ródão dissected terrace remnants is described. Geochronological dating of the two younger and lower terrace levels of this depression suggests a time-averaged incision rate for the Tejo in the Ródão area, of ca. 1.0 m/ka over the last 60 thousand years. A clear discrepancy exists between this rate and the 0.1 m/ka estimated for the longer period since the end of the Pliocene. Although episodes of valley incision may be conditioned by climate and base-level changes, they may also have been controlled by local factors such as movement of small fault-bounded blocks, lithology and structure. Regional crustal uplift is considered to be the main control of the episodes of valley incision identified for this large, long-lived river. A model is proposed in which successive regional uplift events—tectonic phases—essentially determined the long periods of rapid river downcutting that were punctuated by short periods of lateral erosion and later by some aggradation, producing strath terraces.