Aerobic respiration in riparian exchange zones of regulated river corridors

River stage fluctuations drive surface water-groundwater exchanges within river corridors. This study evaluates how repeated daily stage fluctuations, representative of hydropeaking conditions, influence aerobic respiration of river-sourced dissolved organic carbon (DOC) in the riparian exchange zone using reactive flow and transport simulations. Over 50 hypothetical scenarios were modelled to evaluate how the duration of the daily flood signal, river DOC concentration, aquifer hydraulic conductivity and ambient groundwater flow condition affect the fate and transport of DOC and DO in the riparian aquifer. Time series subsurface snapshots highlight how the various factors influence the subsurface distribution of DOC and DO. The total mass of DOC respired per meter of river had a wide range depending on the parameters, spanning from 1.4 to 71 g over 24-h, with high hydraulic conductivity and losing ambient groundwater flow conditions favouring the largest amount of DOC respired. The ratio of DOC mass entering the riparian zone with the mass returning to the river showed that as little as 5% to as much as 76% of the DOC that enters the bank during stage fluctuations returns to the river. This return ratio is dependent on river DOC concentration, hydraulic conductivity and ambient groundwater flow. The results illustrate that stage variations due to river regulation can be a significant control on aerobic respiration in riparian exchange zones.     

Geomorphology and ancient settlements of the Southern Flank of MT. Cairo,lower Liri valley,Italy

The southern flank of Mt. Cairo in southern Lazio edges a valley which forms one of the major passageways from central to southern Italy. The mountainous landscape has affected the settlement pattern, as have historical events such as the Roman conquests and recent socio-economic evolution, which has led to industrialization of a traditional pastoral- agricultural setting. The slopes of calcareous Mt. Cairo are characterized by a cascade of normal faults which delimit landscape units such as the “uplands,” “steep slopes,” and the “mountain rise,” which contains well developed alluvial and colluvial fans. Along the lower mountain slopes, Bronze and Iron Age sites are consistently located higher than Roman ones. Archaeological remains and historical documents indicate that only after the Roman conquest was the agricultural potential of the flatter lower areas fully exploited. Roman villas were characteristically placed on the upper parts of the fans, where both access to different types of land and elevation above the mists of the valley were enjoyed. The Medieval period brought a trend back to higher sites and fortified villages. The uplands remained in use through the ages.     

Fertilization and pH effects on processes and mechanisms controlling dissolved inorganic phosphorus in soils

We used of a set of mechanistic adsorption models (1-pK TPM, ion exchange and Nica-Donnan) within the framework of the component additive (CA) approach in an attempt to determine the effect of repeated massive application of inorganic P fertilizer on the processes and mechanisms controlling the concentration of dissolved inorganic phosphorus (DIP) in soils. We studied the surface layer of a Luvisol with markedly different total concentrations of inorganic P as the result of different P fertilizer history (i.e. massive or no application for 40 years). Soil pH was made to vary from acid to alkaline. Soil solutions were extracted with water and CaCl₂ (0.01 M). The occurrence of montmorillonite led us to determine the binding properties of P and Ca ions for this clay mineral.Satisfactory results were obtained using generic values for model parameters and soil-specific ones, which were either determined directly by measurements or estimated from the literature. We showed that adsorption largely controlled the variations of DIP concentration and that, because of kinetic constrains, only little Ca-phosphates may be precipitated under alkaline conditions, particularly in the P fertilized treatment. The mineral-P pool initially present in both P treatments did not dissolve significantly during the course of the experiments. The adsorption of Ca ions onto soil minerals also promoted adsorption of P ions through electrostatic interactions. The intensity of the mechanism was high under neutral to alkaline conditions. Changes in DIP concentration as a function of these environmental variables can be related to changes in the contribution of the various soil minerals to P adsorption. The extra P adsorbed in the fertilized treatment compared with the control treatment was mainly adsorbed onto illite. This clay mineral was the major P-fixing constituent from neutral to alkaline pH conditions, because the repulsion interactions between deprotonated hydroxyl surface sites and P ions were sufficiently counterbalanced by Ca ions. The drastic increase of DIP observed at acid pH was due to the effect of the lower concentration of surface sites of Fe oxides and kaolinite.In addition to confirming the validity of our approach to model DIP concentrations in soils, the present investigation showed that adsorption was the predominant geochemical process even in the P fertilized soil, and that Ca ions can have an important promoting effect on P adsorption. However the influence of the dissolution of the mineral-P pool under field conditions remained questionable.     

A speleothem record of Holocene climate variability from southwestern Mexico

A paleoclimate reconstruction for the Holocene based upon variations of δ¹⁸O in a U-Th dated stalagmite from southwestern Mexico is presented. Our results indicate that the arrival of moisture to the area has been strongly linked to the input of glacial meltwaters into the North Atlantic throughout the Holocene. The record also suggests a complex interplay between Caribbean and Pacific moisture sources, modulated by the North Atlantic SST and the position of the ITCZ, where Pacific moisture becomes increasingly more influential through ENSO since ~ 4.3 ka. The interruption of stalagmite growth during the largest climatic anomalies of the Holocene (10.3 and 8.2 ka) is evidenced by the presence of hiatuses, which suggest a severe disruption in the arrival of moisture to the area. The δ¹⁸O record presented here has important implications for understanding the evolution of the North American Monsoon and climate in southwestern Mexico, as it represents one of the most detailed archives of climate variability for the area spanning most of the Holocene.     

Spatial patterns of soil δC reveal grassland-to-woodland successional processes

Many grasslands and savannas around the world have experienced woody plant encroachment in recent history. In the Rio Grande Plains of southern Texas, subtropical woodlands dominated by C₃ trees and shrubs have become significant components of landscapes once dominated almost exclusively by C₄ grasslands. In this study, spatial variation of soil δ¹³C to was used to investigate patterns of transformation. Previous research has shown that grassland-to-shrubland transitions are initiated when discrete, multi-species shrub clusters organized around a honey mesquite (Prosopis glandulosa) tree nucleus established in grassland. It is inferred from space-for-time substitution and modeling studies that as new shrub clusters are initiated and existing clusters enlarge, coalescence will occur, leading to the formation of groves; and that groves will eventually merge to form woodlands. The hypothesis that present-day mesquite groves represent areas where individual discrete shrub clusters have proliferated and coalesced was evaluated by comparing patterns of soil δ¹³C within isolated shrub clusters (n = 6) to those in nearby groves (n = 3). Mean soil δ¹³C within discrete clusters was lowest in the center (−23.3‰), increased exponentially toward the dripline (−20.1‰), and stabilized at a relatively high value approximately 15 cm beyond the dripline (−18.9‰). The spatial structure of soil δ¹³C in groves was consistent with that which would be expected to occur if present-day grove communities were a collection of what once were individual discrete clusters that had fused. As such, it provides direct evidence in support of conceptual and mathematical models derived from indirect assessments. However, spatial patterns of soil δ¹³C suggest that groves are not simply a collection of clusters with respect to primary production and SOC turnover. This study illustrates how soil δ¹³C values can be used to reconstruct successional processes accompanying vegetation compositional change, and its consequences for ecosystem function.     

Modelling of hydrogeochemical potential of three lake catchments in Polesie region (Eastern Poland)

Total dissolved solids (TDS) in lake and catchment water is a result of geological structure, as well as duration of rock and water contact and human activity. In this paper, a potential dissolved solids (PtDS) in three ??czna–W?odawa Lake catchments was determined using extraction and computer software (GIS and AquaChem). Human pressure on water quality was estimated as a difference of the TDS and a catchment hydrogeochemical potential (TPtDS, total potential dissolved solids). TPtDS coefficient included hydrogeological features of the aquifer, soil cover impact on infiltrated water quality, and sediments susceptibility to denudation. The main advantage of the model is a possibility of its employment for every catchment or other areas (e.g. administrative) on both microscale and mesoscale. The highest TPtDS occurred in the catchment, favoured with underground supply, which was located in the vicinity of the Cretaceous mesoregional unit (Che?m Hills). The lowest value was observed in the catchment built with organogenic sediments and coarse material. A seasonal constancy of TPtDS values proved a stability of the lake‐catchment systems under study. Copyright © 2012 John Wiley & Sons, Ltd.     

Incorporating Groundwater-Surface Water Interaction into River Management Models

Accurate representation of groundwater-surface water interactions is critical to modeling low river flows in the semi-arid southwestern United States. Although a number of groundwater-surface water models exist, they are seldom integrated with river operation/management models. A link between the object-oriented river and reservoir operations model, RiverWare, and the groundwater model, MODFLOW, was developed to incorporate groundwater-surface water interaction processes, such as river seepage/gains, riparian evapotranspiration, and irrigation return flows, into a rule-based water allocations model. An explicit approach is used in which the two models run in tandem, exchanging data once in each computational time step. Because the MODFLOW grid is typically at a finer resolution than RiverWare objects, the linked model employs spatial interpolation and summation for compatible communication of exchanged variables. The performance of the linked model is illustrated through two applications in the Middle Rio Grande Basin in New Mexico where overappropriation impacts endangered species habitats. In one application, the linked model results are compared with historical data; the other illustrates use of the linked model for determining management strategies needed to attain an in-stream flow target. The flows predicted by the linked model at gauge locations are reasonably accurate except during a few very low flow periods when discrepancies may be attributable to stream gaging uncertainties or inaccurate documentation of diversions. The linked model accounted for complex diversions, releases, groundwater pumpage, irrigation return flows, and seepage between the groundwater system and canals/drains to achieve a schedule of releases that satisfied the in-stream target flow.     

Carbon stable isotopes ratios of pelagic and littoral communities in Alchichica crater-lake, Mexico

Carbon stable isotope ratios were determined in dominant biotic components of pelagic and littoral systems in Alchichica crater-lake. Results showed that carbon signatures were significantly different between both systems. The pelagic environment was more depleted (−26.15 to −15.14 per mille) than the littoral zone (−21.03 to −17.91 per mille). The potential source end-point in the simplified pelagic community was established to be diatomaceous phytoplankton; its predicted value was −21.7 per mille. There is a clear evidence thatNodularia does not sustain the pelagic food chain. In contrast, the highly diverse littoral community was sustained by epiphytes. No allochthonous sources seemed to influence this food web.¹³C enrichment was observed along the components of both systems with fractionations of 0.8 to 1.4 per mille. The contribution of the seagrassRuppia maritima is probably associated with the detritus pathway. Carbon source partitioning between both systems was not recorded. The δ¹³C in Alchichica crater-lake was more enriched than in other saline lakes and could be attributed to different salinity and CO₂ concentrations among lakes.     

Climate change,intergenerational equity and international law: An introductory note

The change in the Earth's climate caused by the accumulation of greenhouse gases in the atmosphere may be the most important environmental legacy that we leave to our descendants.Global change raises difficult issues of equity between our generation and future generations, and between different communities within future generations. International law is accustomed to addressing the effects of intentional environmental change on people who are already alive. It needs to be augmented by principles of intergenerational equity. We have certain obligations to future generations to pass on a planet in no worse condition than we received it and to give them equitable access to its resources.This requires a global strategy for climate change which will prevent excessively rapid climate change, prevent or mitigate the damage caused by climate change, and help countries to adapt to climate change. We need to avoid imposing major costs on future generations for our own benefit.To implement this strategy will require enforceable norms of behavior, which should be embodied in a Declaration of Planetary Rights and Obligations to Future Generations, and implemented in appropriate treaties and national and local legislation. Agreements should be drafted in such a way that they can incorporate increases in scientific understanding, for example by the creation of scientific advisory committees.