Fluid generation and evolution during exhumation of deeply subducted UHP continental crust: Petrogenesis of composite granite–quartz veins in the Sulu belt,China

Composite granite–quartz veins occur in retrogressed ultrahigh pressure (UHP) eclogite enclosed in gneiss at General's Hill in the central Sulu belt, eastern China. The granite in the veins has a high‐pressure (HP) mineral assemblage of dominantly quartz+phengite+allanite/epidote+garnet that yields pressures of 2.5–2.1 GPa (Si‐in‐phengite barometry) and temperatures of 850–780°C (Ti‐in‐zircon thermometry) at 2.5 GPa (~20°C lower at 2.1 GPa). Zircon overgrowths on inherited cores and new grains of zircon from both components of the composite veins crystallized at c. 221 Ma. This age overlaps the timing of HP retrograde recrystallization dated at 225–215 Ma from multiple localities in the Sulu belt, consistent with the HP conditions retrieved from the granite. The ε_Hf(t) values of new zircon from both components of the composite veins and the Sr–Nd isotope compositions of the granite consistently lie between values for gneiss and eclogite, whereas δ¹⁸O values of new zircon are similar in the veins and the crustal rocks. These data are consistent with zircon growth from a blended fluid generated internally within the gneiss and the eclogite, without any ingress of fluid from an external source. However, at the peak metamorphic pressure, which could have reached 7 GPa, the rocks were likely fluid absent. During initial exhumation under UHP conditions, exsolution of H₂O from nominally anhydrous minerals generated a grain boundary supercritical fluid in both gneiss and eclogite. As exhumation progressed, the volume of fluid increased allowing it to migrate by diffusing porous flow from grain boundaries into channels and drain from the dominant gneiss through the subordinate eclogite. This produced a blended fluid intermediate in its isotope composition between the two end‐members, as recorded by the composite veins. During exhumation from UHP (coesite) eclogite to HP (quartz) eclogite facies conditions, the supercritical fluid evolved by dissolution of the silicate mineral matrix, becoming increasingly solute‐rich, more ‘granitic’ and more viscous until it became trapped. As crystallization began by diffusive loss of H₂O to the host eclogite concomitant with ongoing exhumation of the crust, the trapped supercritical fluid intersected the solvus for the granite–H₂O system, allowing phase separation and formation of the composite granite–quartz veins. Subsequently, during the transition from HP eclogite to amphibolite facies conditions, minor phengite breakdown melting is recorded in both the granite and the gneiss by K‐feldspar+plagioclase+biotite aggregates located around phengite and by K‐feldspar veinlets along grain boundaries. Phase equilibria modelling of the granite indicates that this late‐stage melting records P–T conditions towards the end of the exhumation, with the subsolidus assemblage yielding 0.7–1.1 GPa at <670°C. Thus, the composite granite–quartz veins represent a rare example of a natural system recording how the fluid phase evolved during exhumation of continental crust. The successive availability of different fluid phases attending retrograde metamorphism from UHP eclogite to amphibolite facies conditions will affect the transport of trace elements through the continental crust and the role of these fluids as metasomatic agents interacting with the mantle wedge in the subduction channel.     

Geochemistry and petrography of basalt grindstones from the Karak Plateau,central Jordan

Seventeen basalt grindstone fragments from central Jordan's Karak Plateau were studied. Most of these artifacts are vesicular or amygdaloidal with calcite as the dominant mineral filling the voids. The major minerals are olivine (with iddingsite rims), plagioclase, clinopyroxene, magnetite, and apatite. Glass is present in some samples. One basalt fragment is quite different in appearance and composition and may have come from flows closer to the Dead Sea. Grindstone fragment compositions plot in the tephrite‐basanite and basalt fields. A plot of the concentrations of niobium, zirconium, and yttrium reveal that the sample compositions plot in the “within‐plate alkali basalt” and “within‐plate tholeiite” fields. The acquisition of basalts for preparing such implements appears to have been random. Some may have been introduced through trade and migration. Archaeological and environmental studies on the Karak Plateau are urgently needed because Jordan's population growth and economic development are destroying many sites and their environmental contexts. © 2004 Wiley Periodicals, Inc.     

Two notes on the modern theory of inverse problems in geophysics

On the basis of comparison of the approaches to the solution of inverse problems in information theory and geophysics, it is shown that results, obtained in information theory, are suitable to supplement the theory of geophysical inverse problems. The conditions of the existence and uniqueness of the solutions of inverse problems in their practical discrete statement are specified. The terms of ɛ-entropy H _ɛ and informational capacity C _ɛ, characterizing “volumes” of unknown and observed data, are introduced. It is shown, that the instability of the solution of the inverse problem decreases with increase in H _ɛ, (increase in the “complexity” of studied section), if the relation H _ɛ ≤ C _ɛ is maintained.     

Optimum absorber parameters for various combinations of response and excitation parameters

In recent papers the author has shown that when determining optimum parameters for an absorber which minimizes the vibration response of a complex system, the latter may be treated as an equivalent single degree-of-freedom system if its natural frequencies are well separated. Emphasis was on minimizing the displacement response when the excitation was a harmonic force. In the present paper simple expressions for optimum absorber parameters are derived for undamped one degree-of-freedom main systems for harmonic and white noise random excitations with force and frame acceleration as input and minimization of various response parameters. These expressions can be used to obtain optimum parameters for absorbers attached to complex systems provided that optimization is with respect to an absolute, rather than a relative, quantity. The requirement that the natural frequencies should be well separated is investigated numerically for the different cases. The effect of damping in the main system on optimum absorber parameters is investigated also.     

Morphotectonic evaluation of the Delhi region in northern India,and its significance in environmental management

This paper deals with the morphotectonic evaluation of the Delhi region in northern India to understand its impact on land use and urban development. To accommodate heavy urbanization and population rise (being the capital of India), the area has undergone tremendous environmental degradation resulting from a mismatch between adopted land use and morphotectonic considerations. The geomorphic and drainage signatures of the region have evolved out of interaction of varied geological parameters including neotectonic activities. We have evaluated the changes in the drainage pattern of the Yamuna River in the Delhi region to underline its significance in geomorphic evolution and subsequent land use and/or land suitability. The Yamuna River has shown variations both in channel position and geometry over the last two centuries. The observed migration pattern of the river (shifting of confluences, position and disposition of palaeochannels, etc.,) cannot be attributed to normal river phenomenon and appears to have been effected by neotectonic changes. In addition, some case studies are discussed to underline the significance of geomorphic factors in urban development.     

The earthquake sequence of May 1951 at Jucuapa, El Salvador

Three earthquakes that happened over two days in May 1951 caused extensive damage to villages in a small area of eastern El Salvador (Central America). Contemporary hypocentral solutions indicated focal depths, confirmed by re-calculations using available seismic data, of the order of 90 km, suggesting events associated with the subducted Cocos plate. Macroseismic observations strongly indicate that the earthquakes were of very shallow focus and this is supported by wave-form modeling and the appearance of seismograms recorded in Guatemala. A re-evaluation of the location and source characteristics for these events is presented, together with a fault plane solution and additional macroseismic evidence. The implications for seismic hazard and risk assessment in Central America, where shallow earthquakes of moderate magnitude, frequently occurring in clusters, pose the greatest threat to settlements which, like the area affected by these events, are concentrated along the axis of Quaternary volcanoes.     

Comparative toxicities of chlorinated biphenyls on sea urchin egg fertilisation and embryogenesis

The aim of this study was to compare the biological actions of selected chlorinated biphenyls (CB's) (with different degrees of chlorine substitution), using the sea urchin test system, for their ability to affect fertilisation, embryogenesis and mitotic activity. Sea urchin embryos were exposed to the test agents throughout larval development or for shorter intervals (e.g. before or after hatching). Sperm or eggs were exposed before fertilisation, thereafter the contaminants were removed from embryo cultures. The results showed maximal activities from medium-chlorinated (tetra- and hexachloro-substituted) compounds, as compared to low- and high-chlorinated biphenyls (mono-, di- and octachloro-substituted), at nominal levels ranging from 10⁻⁶m to 10⁻⁵m. This held true for the different parameters and treatment schedules. Developmental defects were only detected following post hatching exposure of embryos to CB's, whereas pre-hatching exposure failed to reveal any embryological or cytogenetic abnormalities.     

Meteorological monitoring of an active volcano: Implications for eruption prediction

Rainfall data collected on and around the Soufriere Hills Volcano, Montserrat between 1998 and 2003 were analysed to assess the impact on primary volcanic activity, defined here as pyroclastic flows, dome collapses, and explosions. Fifteen such rainfall-triggered events were identified. If greater than 20 mm of rain fell on a particular day, the probability of a dome collapse occurring on that day increased by a factor of 6.3% to 9.2%, compared to a randomly chosen day. Similarly, the probability of observing pyroclastic flows and explosions on a day with > 20 mm of rainfall increased by factors of 2.6 and 5.4, respectively. These statistically significant links increased as the rainfall threshold was increased. Seventy percent of these rainfall-induced dome collapse episodes occurred on the same calendar day (most within a few hours) as the onset of intense rainfall, but an extra 3 occurred one or two calendar days later. The state of the volcano was important, with the rainfall–volcanic activity link being strongest during periods of unstable dome growth and weakest during periods of no dome growth or after a recent major collapse.Over 50% of the heavy rain days were associated with large-scale weather systems that can potentially be forecast up to a few days ahead. However, the remaining heavy rain days were associated with small-scale, essentially unpredictable weather systems. There was significant variability in the amount of rainfall recorded by different rain gauges, reflecting topographic variations around the volcano but also the inherent small-scale variability within an individual weather system. Hence, any monitoring/warning program is recommended to use a network, rather than just a single gauge. The seasonal cycle in rainfall was pronounced, with nearly all the heavy rain days occurring in the May–December wet season. Hence, the dome was at its most vulnerable at the beginning of the wet season after a period of uninterrupted growth. Interannual variability in rainfall was related to tropical Pacific and Atlantic sea surface temperature anomalies, and holds out the prospect of some limited skill in volcanic hazard forecasts at even longer lead times.     

Spectroscopic Characterization of Organic Structures and Organic‐Inorganic Interactions in Paper Mill Sludge

The organic composition and organic‐inorganic interaction in paper mill sludge (PS) solvent extracts (hexane, ethyl acetate, acetone and ethanol) and humic fractions, humic acid (HA) and humin (HU) were studied by electron paramagnetic resonance spectroscopy (EPR), proton and carbon‐13 nuclear magnetic resonance spectroscopy (¹H NMR; ¹³C NMR), Fourier‐transformed infrared spectroscopy (FTIR), and ultraviolet‐visible spectroscopy (UV‐vis). The strategy of fractionating the PS, sequentially, with organic solvents of increasing polarity is a reliable analytical procedure for humic substance sample separation because it results in more purified fractions. FTIR, ¹H NMR and ¹³C NMR results showed that hexane extract consisted mainly of aliphatic hydrocarbon structures. Their contents in the extracts decreased as the polarity of the extracting solvent increased and the content of oxygen functional groups increased. Carboxylic and carboxylate functional groups were found in the acetone extract, and ester and ether functions were predominantly found in the ethanol extract. EPR spectra revealed some Fe³⁺ complexes with rhombic structure (g₁ = 4.3; g₂ = 9.0) in the humic fractions and in all solvent extracts, except hexane. Quasi‐octahedral Fe³⁺ complexes (g = 2.3; ΔH_pp ≤ 400 G) were found in the HU fraction and in the acetone extract. The organic free radical content in the HA fraction was higher than the non‐fractionated PS sample and HU fraction.