Development and application of a spatially‐distributed Arctic hydrological and thermal process model (ARHYTHM)

A process‐based, spatially distributed hydrological model was developed to quantitatively simulate the energy and mass transfer processes and their interactions within arctic regions (arctic hydrological and thermal model, ARHYTHM). The model first determines the flow direction in each element, the channel drainage network and the drainage area based upon the digital elevation data. Then it simulates various physical processes: including snow ablation, subsurface flow, overland flow and channel flow routing, soil thawing and evapotranspiration. The kinematic wave method is used for conducting overland flow and channel flow routing. The subsurface flow is simulated using the Darcian approach. The energy balance scheme was the primary approach used in energy‐related process simulations (snowmelt and evapotranspiration), although there are options to model snowmelt by the degree‐day method and evapotranspiration by the Priestley–Taylor equation. This hydrological model simulates the dynamic interactions of each of these processes and can predict spatially distributed snowmelt, soil moisture and evapotranspiration over a watershed at each time step as well as discharge in any specified channel(s). The model was applied to Imnavait watershed (about 2·2 km²) and the Upper Kuparuk River basin (about 146 km²) in northern Alaska. Simulated results of spatially distributed soil moisture content, discharge at gauging stations, snowpack ablations curves and other results yield reasonable agreement, both spatially and temporally, with available data sets such as SAR imagery‐generated soil moisture data and field measurements of snowpack ablation, and discharge data at selected points. The initial timing of simulated discharge does not compare well with the measured data during snowmelt periods mainly because the effect of snow damming on runoff was not considered in the model. Results from the application of this model demonstrate that spatially distributed models have the potential for improving our understanding of hydrology for certain settings. Finally, a critical component that led to the performance of this modelling is the coupling of the mass and energy processes. Copyright © 2000 John Wiley & Sons, Ltd.     

The acute and chronic effects of wastes associated with offshore oil and gas production on temperate and tropical marine ecological processes

A review of the acute and chronic effects of produced formation water (PFW), drilling fluids (muds) including oil-based cutting muds, water-based cutting muds, ester-based cutting muds and chemical additives, and crude oils associated with offshore oil and gas production was undertaken in relation to both temperate and tropical marine ecological processes. The main environmental effects are summarized, often in tabular form. Generally, the temporal and spatial scales of these studies, along with the large levels of inherent variation in natural environments, have precluded our ability to predict the potential long-term environmental impacts of the offshore oil and gas production industry. A series of critical questions regarding the environmental effects of the offshore oil and gas production industry that still remain unanswered are provided for future consideration.     

False drainage anomalies (?) in a granite area, Kvalöya in Troms, Norway — a case study

An anomalous area (100 km²) revealed by a previous regional overbank sediment sampling survey by the Geological Survey of Norway was followed-up for Ti, Nb, Y, Zr, La and Ce by drainage and lithogeochemical sampling and analyses. The drainage samples were anomalous in the same elements as in the overbank samples and contained similar concentrations. The lithogeochemical results did not indicate mineralization and showed only a small enhancement of Ti, Zr, La and Ce in mylonitic rocks.Mineralogical studies of the drainage samples revealed, apart from proportions of quartz and feldspars, that stream sediments and heavy mineral concentrates are similar in mineralogy, with epidote predomination and several vol% of fine-grained titanite and zircon. Drainage samples contained amounts of Nb, Y, and Zr up to ten times larger than average contents of rock samples. Enhanced light REE (La and Ce) and Nb reflect host minerals, titanite, and enhanced Y possibly zircon and/or allanite.Anomalies in both media do not relate to mineralization. The overbank samples and the drainage samples provide comparable geochemical data.     

Streambank dewatering for increased stability

Streambank erosion is often the dominant source of sediment leaving modified watersheds. Mass failure of high, steep banks is one of the most serious forms of streambank erosion. The risk of a given bank experiencing mass failure is a function of bank height, angle, and soil strength, which is governed by soil moisture. Two methods for bank dewatering were tested in adjacent sections of streambank bordering a deeply incised channel in northern Mississippi: a low‐cost pump system and subsurface horizontal drains. Pore water pressures (both positive and negative pressures, or matric suction) were continuously monitored for 2 years at the pumped site, at an adjacent untreated control section, and for 1 year at the site stabilized with horizontal drains. Resulting data were used to calculate a time series of the factor of safety using a computer model. Over the course of two wet seasons, average bank retreats for the control and pumped plots were 0·43 and 0·21 m, respectively. More limited monitoring revealed that the site with passive drains retreated about 0·23 m. At the pumped site pore water pressure was 3–4 kPa lower than at the control site during the most critical periods. Accordingly, computed factors of safety were above the failure threshold at the pumped site, but fell below unity at the control site on 11 occasions over the period of observation. Similarly, the drained site displayed generally lower pore water pressure and higher safety factors except for two events when drains were evidently overwhelmed with the volume of local surface and subsurface flows. These results suggest, but do not prove, that bank dewatering promoted lower rates of bank retreat and higher levels of stability since the three sites had slight differences in soils, geometry and boundary conditions. Initial cost of the dewatering treatments were significantly less than orthodox bank stabilization measures, but operation and maintenance requirements may be greater. Published in 2009 by John Wiley & Sons, Ltd.     

Conceptual framework for assessing the response of delta channel networks to Holocene sea level rise

Recent research has identified two fundamental unit processes that build delta distributary channels. The first is mouth-bar deposition at the shoreline and subsequent channel bifurcation, which is driven by progradation of the shoreline; the second is avulsion to a new channel, a result of aggradation of the delta topset. The former creates relatively small, branching networks such as Wax Lake Delta; the latter generates relatively few, long distributaries such as the Mississippi and Atchafalaya channels on the Mississippi Delta. The relative rate of progradation to aggradation, and hence the creation of accommodation space, emerges as a controlling parameter on channel network form. Field and experimental research has identified sea level as the dominant control on Holocene delta growth worldwide, and has empirically linked channel network changes to changes in the rate of sea level rise. Here I outline a simple modeling framework for distributary network evolution, and use this to explore large-scale changes in Holocene channel pattern that have been observed in deltas such as the Rhine-Meuse and Mississippi. Rapid early- to mid-Holocene sea level rise forced many deltas into an aggradational mode, where I hypothesize that avulsion and the generation of large-scale branches should dominate. Slowing of sea level rise in the last ～6000 yr allowed partitioning of sediment into progradation, facilitating the growth of smaller-scale distributary trees at the shorelines of some deltas, and a reduction in the number of large-scale branches. Significant antecedent topography modulates delta response; the filling of large incised valleys, for example, caused many deltas to bypass the aggradational phase. Human effects on deltas can be cast in terms of geologic controls affecting accommodation: constriction of channels forces rapid local progradation and mouth-bar bifurcation, while accelerated sea level rise increases aggradation and induces more frequent channel avulsion.     

The source of calcium in wet atmospheric deposits: Ca-Sr isotope evidence

Tracing the origin of calcium in wet atmospheric deposits is important for environmental studies since it is a dominant acid neutralising cation and an essential nutrient. Here we present the first calcium isotope ratio measurements for rain and snow. Samples from northeastern and southern locations (France, Switzerland, Luxembourg, California and Japan) suggest a carbonate origin. Only at a local scale in a forested watershed (Vosges mountains, France) the Ca isotopic compositions of rainwater indicate that the rainwater becomes admixed with throughfall solution, which is a mixing product of Ca from dissolved atmospheric dust particles and leave excretions. If this proves to be widely true, the contribution of Ca from the canopy could be very important for the neutralisation of acid rain and of the corresponding soil system in forested watersheds. In such cases Ca and Sr cycles are decoupled in the lower atmosphere. In contrast to Sr isotopes, Ca isotopes can be applied to tracing processes occurring in the biosphere.     

Electron Temperatures and Flow Speeds of the Low Solar Corona: MACS Results from the Total Solar Eclipse of 29 March 2006 in Libya

An experiment was conducted in conjunction with the total solar eclipse on 29 March 2006 in Libya to measure both the electron temperature and its flow speed simultaneously at multiple locations in the low solar corona by measuring the visible K-coronal spectrum. Coronal model spectra incorporating the effects of electron temperature and its flow speed were matched with the measured K-coronal spectra to interpret the observations. Results show electron temperatures of (1.10±0.05) MK, (0.70±0.08) MK, and (0.98±0.12) MK, at 1.1 R _⊙ from Sun center in the solar north, east and west, respectively, and (0.93±0.12) MK, at 1.2 R _⊙ from Sun center in the solar west. The corresponding outflow speeds obtained from the spectral fit are (103±92) km s⁻¹, (0+10) km s⁻¹, (0+10) km s⁻¹, and (0+10) km s⁻¹. Since the observations were taken only at 1.1 R _⊙ and 1.2 R _⊙ from Sun center, these speeds, consistent with zero outflow, are in agreement with expectations and provide additional confirmation that the spectral fitting method is working. The electron temperature at 1.1 R _⊙ from Sun center is larger at the north (polar region) than the east and west (equatorial region).     

Effects of organic pollutants on methanogenesis,sulfate reduction and carbon dioxide evolution in salt marsh sediments

Anaerobic salt marsh sediments were amended with a variety of organic pollutants and the effects on methanogenesis, sulfate reduction and carbon dioxide evolution were examined. Addition of 1000 μg g^?1 (dry weight sediment) Arochlor 1221, lindane, endrin, benzene and phenanthrene resulted in no significant effects on the activities studied. Methanogenesis was inhibited by 1000 μg g^?1toxaphene, PCP, chlordane, naphthalene, DDT, Kepone and heptachlor and by 100 μg g^?1 PCP and toxaphene. At 1000 μg g^?1 naphthalene and toxaphene and 100 μg g^?1 PCP, a period of initial inhibition of methanogenesis was followed by stimulation relative to controls. Arochlor 1254 (1000 μg g^?1) and Temik (500 and 10 μg g^?1) stimulated methanogenesis from the outset. Temik at 500 μg g^?1 gave the greatest stimulation of methanogenesis (900% of controls) of any of the compounds studied. Sulfate reduction was inhibited by 1000 μg g^?1 PCP, toxaphene, naphthalene and chlordane and by 500 μg g^?1 atrazine and 100 μg g^?1 heptachlor. Sustained inhibition of sulfate reduction by naphthalene, toxaphene and PCP may have contributed to the stimulation of methanogenesis. Carbon dioxide evolution was not significantly affected by most of the compounds studied except for 100 μg g^?1 PCP and 1000 μg g^?1 aphthalene, each of which gave significant inhibition in only one of three experiments.Concentrations of individual organic pollutants required to cause observable effects were high. It is concluded that, except for highly polluted sediments, methanogenesis, sulfate reduction and CO₂ evolution would not be affected by the compounds studied here at concentrations typically found in the environment.     

The structure of Neptune's upper atmosphere: The stellar occultation of 24 May 1981

Observations of the 24 May 1981 occultation of an uncatalogued star by Neptune made at the Cerro Tololo Inter-American Observatory have been analyzed to yield temperature profiles of Neptune's upper atmosphere for number densities near 5 × 10¹³ cm^?3. The mean temperatures at immersion (latitude ?56°) and emersion (latitude ?16°) obtained by numerical inversion were 140 ± 10°K and 154 ± 10°K, respectively. The immersion and emersion profiles are remarkably similar in overall shape, suggestive of global atmospheric layering. From the astrometry of the event, precise relative positions of Neptune and the occulted were obtained.