An experimental study of alteration of oceanic crust and terrigenous sediments at moderate temperatures (51 to 350°C): insights as to chemical processes in near-shore ridge-flank hydrothermal systems

Studies of hydrothermal circulation within partly buried basement on the eastern flank of the Juan de Fuca Ridge (JFR) have shown that ridge-flank geochemical fluxes are potentially important for the global budgets of some elements. There are major uncertainties in these flux calculations, however, because the composition of these basement fluids is strongly dependent on temperature and because they may be modified by interaction with the overlying terrigenous sediments, either by diffusive exchange with basement or during upwelling to the seafloor. To better understand the nature and temperature control of basalt-fluid and sediment-fluid reactions at the JFR flank, we have conducted laboratory experiments between 51 and 350°C and at 400 bars pressure. K, Rb, and Si are leached from basalt between 150 and 351°C, and Sr and U are taken up. The direction of exchange of Li and Ca with basalt varies with temperature. Li and Sr are removed from fluid at 150°C, but isotope studies show that there is simultaneous release of both elements from basalt, indicating that uptake is controlled by the formation of secondary minerals. Moreover, our experiments confirm that Sr isotope exchange with oceanic crust occurs at moderate temperature and is not confined to high-temperature axial hydrothermal systems. Our data and field data from the JDR flank indicate that uptake of U into basalt at moderate temperature could remove between 9.9 and 15 × 10⁶ mol U yr⁻¹ from the oceans. This is higher than a recent estimate based on measurements of U in altered ocean crust (5.7 ± 3.3 × 10⁶ mol yr⁻¹), which concords with arguments that the Δ_element/heat ratios of JDR flank fluids are too large to be representative of average global flank fluids. K, Ca, Sr, Ba, Li, Si, and B are leached from terrigenous sediments between 51 and 350°C, and U is taken up. Cs and Rb are removed from the fluid below 100°C and leached from the sediment at higher temperature. Sr isotope data show that Sr is preferentially mobilised from volcanic components within terrigenous sediments, which may lead to an overestimation of the ridge-flank Sr isotope flux at the JDR if there is exchange of sediment pore fluids with basement.     

Comparative Rates of Western Juniper Afforestation in South‐Central Oregon and the Role of Anthropogenic Disturbance*

We examine changes in canopy cover for adult western juniper from the 1960s to 1994 in central Oregon using repeat aerial photography. We compare changes at four sites with a land‐use history of minimal anthropogenic disturbance to changes on adjacent sites that have a disturbance history more typical of central Oregon rangelands. Canopy cover increased at all sites, but afforestation on sites with domestic livestock grazing was greater. The potential driving forces common to all sites include a long fire‐free interval, early twentieth‐century favorable climatic conditions, biological inertia, and atmospheric CO₂ enrichment.     

The optimum distance at which to determine the size of a giant air shower

To determine the size of an extensive air shower it is not necessary to have knowledge of the function that describes the fall-off of signal size from the shower core (the lateral distribution function). In this paper an analysis with a simple Monte Carlo model is used to show that an optimum ground parameter can be identified for each individual shower. At this optimal core distance, r_opt, the fluctuations in the expected signal, S(r_opt), due to a lack of knowledge of the lateral distribution function are minimised. Furthermore it is shown that the optimum ground parameter is determined primarily by the array geometry, with little dependence on the energy or zenith angle of the shower or choice of lateral distribution function. For an array such as the Pierre Auger Southern Observatory, with detectors separated by 1500 m in a triangular configuration, the optimum distance at which to measure this characteristic signal is close to 1000 m.     

Observations on the flow structures and transport in a simulated warm-core ring in the Gulf of Mexico

This study presents several new observations from the study of a numerically simulated warm-core ring (WCR) in the Gulf of Mexico based on the ECCO2 global ocean simulation. Using Lagrangian coherent structures (LCS) techniques to investigate this flow reveals a pattern of transversely intersecting LCS in the mixed layer of the WCR which experiences consistent stretching behavior over a large region of space and time. A detailed analysis of this flow region leads to an analytical model of the velocity field which captures the essential elements that generate the transversely intersecting LCS. The model parameters are determined from the simulated WCR and the resulting LCS show excellent agreement with those observed in the WCR. The three-dimensional transport behavior that creates these structures relies on the small radial outflow that is present in the mixed layer and is not seen below the pycnocline, leading to a sharp change in the character of the LCS at the bottom of the mixed layer. The flow behavior revealed by the LCS limits fluid exchange between the WCR and the surrounding ocean, contributing to the long life of WCRs. Further study of these structures and their associated transport behavior may lead to further insights into the development and persistence of such geophysical vortices as well as their transport behavior.     

Evaluation of a gravel transport sensor for bed load measurements in natural flows

A recent acoustic instrument （Gravel Transport Sensor, GTS） was tested for predicting sediment transport rate （bed load rate） in gravel bed streams. The GTS operation is based on the particle collision theory of submerged obstacles in fluids. When particles collide with the GTS cylinder their momentum is recorded in the form of ping rates. The GTS is attractive for further consideration here because of its potential to provide continuous unattended local bed load measurements, especially in areas found in streams that access may be difficult under extreme conditions. Laboratory experiments coupled with numerical simulations for the same flow conditions were performed in order to determine the conditions under which particles of different size will hit the GTS cylinder and be able to register a ping rate. The GTS was able to detect the number of particles with diameter in the range of 15.9 to 25.4 mm, with reasonable accuracy, if the applied Shields effective stress τ＊e = τ＊ - τ＊cr was in the range of 0.006 to 0.015. A drawback of the tested prototype GTS, however, was that it exerted increased resistance on the incoming particles. The added drag effects increased the overall resistance that was exerted by the flow on particles and thus increased the likelihood that particles will rest in the ambient region of the cylinder instead of hitting it. Numerical simulation of the flow around the GTS cylinder revealed that changing the prototype geometry from cylindrical to ellipsoid or rhomboid will increase the likelihood of the particles hitting the instrument under the same flow conditions failed by the original tested GTS cylinder.     

The giant awakes

Johannes Knapp of the Pierre Auger Collaboration reports on the first promising results from the Pierre Auger Observatory.     

Thermal expansion of gehlenite, Ca2Al[AlSiO7], and the related aluminates LnCaAl[Al2O7] with Ln = Tb, Sm

The thermal expansion of gehlenite, Ca₂Al[AlSiO₇], (up to T=830 K), TbCaAl[Al₂O₇] (up to T=1100 K) and SmCaAl[Al₂O₇] (up to T=1024 K) has been determined. All compounds are of the melilite structure type with space group Thermal expansion data were obtained from in situ X-ray powder diffraction experiments in-house and at HASYLAB at the Deutsches Elektronen Synchrotron (DESY) in Hamburg (Germany). The thermal expansion coefficients for gehlenite were found to be: α₁=7.2(4)×10⁻⁶×K⁻¹+3.6(7)×10⁻⁹ΔT×K⁻² and α₃=15.0(1)×10⁻⁶×K⁻¹. For TbCaAl[Al₂O₇] the respective values are: α₁=7.0(2)×10⁻⁶×K⁻¹+2.0(2)×10⁻⁹ΔT×K⁻² and α₃=8.5(2)×10⁻⁶×K⁻¹+2.0(3)×10⁻⁹ΔT×K⁻², and the thermal expansion coefficients for SmCaAl[Al₂O₇] are: α₁=6.9(2)×10⁻⁶×K⁻¹+1.7(2)×10⁻⁹ΔT×K⁻² and α₃=9.344(5)×10⁻⁶×K⁻¹. The expansion mechanisms of the three compounds are explained in terms of structural trends obtained from Rietveld refinements of the crystal structures of the compounds against the powder diffraction patterns. No structural phase transitions have been observed. While gehlenite behaves like a ‘proper’ layer structure, the aluminates show increased framework structure behavior. This is most probably explained by stronger coulombic interactions between the tetrahedral conformation and the layer-bridging cations due to the coupled substitution (Ca²⁺+Si⁴⁺)–(Ln ³⁺+Al³⁺) in the melilite-type structure. This article has been mistakenly published twice. The first and original version of it is available at .