NanoSIMS: Insights to biogenicity and syngeneity of Archaean carbonaceous structures

NanoSIMS is a relatively new technology that is being applied to ancient carbonaceous structures to gain insight into their biogenicity and syngeneity. NanoSIMS studies of well preserved organic microfossils from the Neoproterozoic (0.8 Ga) Bitter Springs Formation have established elemental distributions in undisputedly biogenic structures. Results demonstrate that sub-micron scale maps of metabolically important elements (carbon [C], nitrogen [measured as CN ion], and sulfur [S]) can be correlated with kerogenous structures identified by optical microscopy. Spatial distributions of C, CN, and S in individual microfossils are nearly identical, and variations in concentrations of these elements parallel one another. In elemental maps, C, CN, and S appear as globules, aligned to form remnant walls or sheaths of fossiliferous structures. The aligned character and parallel variation of C and CN are the strongest indicators of biogenicity.Nitrogen/carbon atomic ratios (N/C) of spheroids, filaments, and remnants of a microbial mat suggest that N/C may reflect original biochemical differences, within samples of the same age and degree of alteration. Silicon (Si) and oxygen (O) maps illustrate that silica is intimately interspersed with organic carbon of the microfossils. This relationship is likely to reflect the process of silica permineralization of biological remains and thus may be an indicator of syngeneity of the fossilized material with the mineral matrix.The NanoSIMS characterization of Bitter Springs microfossils can be used as a baseline for interpreting less well preserved carbonaceous structures that might occur in older or even extraterrestrial materials. An example of such an application is provided by comparison of Bitter Springs results with NanoSIMS of Archaean carbonaceous structures from Western Australia, including a spheroid in the 3 Ga Farrel Quartzite and material in a secondary vein in the 3.43 Ga Strelley Pool Chert. Results reinforce a biogenic, syngenetic interpretation for the Archaean spheroid.NanoSIMS has several advantages in the study of ancient organic materials: the technique allows characterization of extremely small structures that are present in low concentrations; organic matter does not have to be isolated by acid treatment but can be analyzed in polished thin section; preparation is simple; samples are minimally altered during analysis; results provide sub-micron scale spatial distribution coupled with concentration information for at least five elements; the biologically important elements of carbon and nitrogen can be assessed; and the ability to study organic remains in situ permits petrographic assessment of spatial relationships between organic matter and mineral constituents. These advantages could be of significant benefit for interpretation of poorly preserved and fragmentary carbonaceous remains that might occur in some of Earth's oldest samples as well as in meteorites or extraterrestrial material brought to Earth in future planetary missions.     

Influence of the amount of available K data on uncertainty about contaminant transport prediction

The effect of increasing the amount of hydraulic conductivity (K) data on the level of uncertainty about contaminant concentration predictions was examined. Contaminant concentrations were predicted using Monte Carlo numerical simulations with progressively more K information, and were compared to reference data obtained from a physical experiment. Increasing the amount of K data used in generating the aquifer's K field improved the measure of confidence in the predicted contaminant concentration. The normalized concentration interval with 95% confidence decreased from 1.29 to 0.75 when the amount of K data increased from 20 to 71. However, the trade-off is the increase in the costs of aquifer investigation. Conducting Monte Carlo numerical simulations may help design an optimal aquifer investigation scheme, so that it can provide enough input data to predict concentrations with the desired level of confidence and at the same time avoid the excessive costs of aquifer investigation.     

The large-scale solar magnetic field

The large-scale photospheric magnetic field, measured by the Mt. Wilson magnetograph, has been analyzed in terms of surface harmonics (P _n ^m )()cosm and P _n ^m ()sinm) for the years 1959 through 1972. Our results are as follows. The single harmonic which most often characterized the general solar magnetic field throughout the period of observation corresponds to a dipole lying in the plane of the equator (2 sectors, n = m = 1). This 2-sector harmonic was particularly dominant during the active years of solar cycles 19 and 20. The north-south dipole harmonic (n = 1, m = 0) was prominent only during quiet years and was relatively insignificant during the active years. (The derived north-south dipole includes magnetic fields from the entire solar surface and does not necessarily correlate with either the dipole-like appearance of the polar regions of the Sun or with the weak polar magnetic fields.) The 4-sector structure (n = m = 2) was prominent, and often dominant, at various times throughout the cycle. A 6-sector structure (n = m = 3) occasionally became dominant for very brief periods during the active years. Contributions to the general solar magnetic field from harmonics of principal index 4 n 9 were generally relatively small throughout this entire solar cycle with one outstanding exception. For a period of several months prior to the large August 1972 flares, the global photospheric field was dominated by an n = 5 harmonic; this harmonic returned to a low value shortly after the August 1972 flare events. Rapid changes in the global harmonics, in particular, relative and absolute changes in the contributions of harmonics of different principal index n to the global field, imply that the global solar field is not very deep or that very strong fluid flows connect the photosphere with deeper layers.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

Tabulation of the harmonic coefficients of the solar magnetic fields

Tables of spherical harmonic coefficients for the global photospheric magnetic field between 1959 and 1974 are now available on microfilm. (These are the same coefficients which were used to construct the maps of the coronal magnetic atlas.)The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

Coronal Flux Recycling Times

High-cadence, high-resolution magnetograms have shown that the quiet-Sun photosphere is very dynamic in nature. It is comprised of discrete magnetic fragments which are characterized by four key processes – emergence, coalescence, fragmentation and cancellation. All of this will have consequences for the magnetic field in the corona above. The aim of this study is to gauge the effect of the behavior of the photospheric flux fragments on the quiet-Sun corona. By considering a sequence of observed magnetograms, photospheric flux fragments are represented by a series of point sources and the resulting potential field arising from them is examined. It is found that the quiet-Sun coronal flux is generally recycled on time scales considerably shorter than the corresponding time scales for the recycling of photospheric flux. From the motions of photospheric fragments alone, a recycling time of coronal flux of around 3 h is found. However, it is found that the amount of reconnection driven by the motions of fragments is comparable to the amount driven by emergence and cancellation of flux, resulting in a net flux replacement time for the corona of only 1.4 h. The technique used in this study was briefly presented in a short research letter (R. M. Close et al., Astrophys. J., 612, L81, 2004); here the technique is discussed in far greater depth. Furthermore, an estimate is made of the currents required to flow along separator field lines in order to sustain the observed heating rates (assuming separator reconnection is the key mechanism by which the solar corona is heated).     

Estimating the timescale of fluvial response to anthropogenic disturbance using two generations of dams on the South River,Massachusetts, USA

Centuries-long intensive land-use change in the north-eastern United States provides the opportunity to study the timescale of geomorphic response to anthropogenic disturbances. In this region, forest-clearing and agricultural practices following EuroAmerican settlement led to deposition of legacy sediment along valley bottoms, including behind mill dams. The South River in western Massachusetts experienced two generations of damming, beginning with mill dams up to 6-m high in the eighteenth–nineteenth century, and followed by construction of the Conway Electric Dam (CED), a 17-m-tall hydroelectric dam near the watershed outlet in 1906. We use the mercury (Hg) concentration in upstream deposits along the South River to constrain the magnitude, source, and timing of inputs to the CED impoundment. Based on cesium-137 (¹³⁷Cs) chronology and results from a sediment mixing model, remobilized legacy sediment comprised % of the sediment load in the South River prior to 1954; thereafter, from 1954 to 1980s, erosion from glacial deposits likely dominated (63 ± 14%), but with legacy sediments still a substantial source (37 ± 14%). We also use the CED reservoir deposits to estimate sediment yield through time, and find it decreased after 1952. These results are consistent with high rates of mobilization of legacy sediment as historic dams breached in the early twentieth century, and suggest rapid initial response to channel incision, followed by a long decay in the second half of the century, that is likely dependent on large flood events to access legacy sediment stored in banks. Identifying sources of sediment in a watershed and quantifying erosion rates can help to guide river restoration practices. Our findings suggest a short fluvial recovery time from the eighteenth–nineteenth century to perturbation during the first half of the twentieth century, with subsequent return to a dominant long-term signal from erosion of glacial deposits, with anthropogenic sediment persisting as a secondary source. © 2020 John Wiley & Sons, Ltd.     

Complementary use of tracer and pumping tests to characterize a heterogeneous channelized aquifer system in New Zealand

The combined use of pumping and tracer test data enabled the derivation of equivalent average hydraulic conductivities (K_avg) for each test in a heterogeneous channelized alluvial aquifer, whereas K values of the preferential flow paths were two orders of magnitude higher. Greater and earlier drawdown was generally observed along preferential flow lines in a pumping test, within an array of 21 wells. The study aim was to characterize hydraulic properties of a channelized aquifer system in New Zealand by combining tracer and pumping test data. Estimates were able to be made of the percentage of highly permeable channels within the profile (～1.2%), effective porosity that reflected the maximum fraction of highly permeable channels within the aquifer (?_eff–pc ～0.0038), and flows through highly permeable channels (～98%) and the sandy gravel matrix material (～2%). Using ?_eff–pc, a tracer test K_avg value (～93 m/day) was estimated that was equivalent to pumping test values (～100 m/day), but two orders of magnitude smaller than K calculated solely from transport through permeable channels (K_pc ～8,400 m/day). Derived K values of permeable and matrix material were similar to values derived from grain size distribution using the Kozeny-Carman equation.     

On the frequency of lake-effect snowfall in the Catskill Mountains

Meltwater from snow that falls in the Catskill/Delaware watershed in the Catskill Mountains in south-central New York contributes to reservoirs that supply drinking water to approximately nine million people in and near New York City (NYC). Using the Interactive Multisensor Snow and Ice Mapping System (IMS) 4-km snow maps from the National Oceanic and Atmospheric Administration’s National Ice Center, we identified and tracked 28 lake-effect (LE) storms that deposited snow in the Catskills (2004–2017). These storms, which generally originated from Lake Ontario, but sometimes from Lake Erie, represent an underestimate of the number of LE storms that contribute snowfall to the Catskills snowpack because snowstorms are not visible on IMS maps when they travel over already-snow-covered terrain. Using satellite, meteorological (including NEXRAD and National Weather Service Cooperative Observer Program), and reanalysis data, we identified conditions that contributed to the LE snowstorms and mapped snow-cover extent (SCE) following the storms. We show that LE snow makes an important contribution to the Catskills snowpack because of the frequency of events, even though the total amount of each event may, on average, be small. The IMS 4-km maps tend to overestimate SCE compared to MODerate-resolution Imaging Spectroradiometer and Landsat snow maps. Climate change could impact LE storms and the distribution of rain versus snow in the Catskills, which may affect future reservoir operations in the NYC Water Supply System and winter recreation in the Catskills.