Characterisation of carbonate minerals from hyperspectral TIR scanning using features at 14 000 and 11 300 nm

Rapid characterisation of carbonate phases in hyperspectral reflectance spectra acquired from drill core material has important implications for mineral exploration and resource modelling. Major infrared active features of carbonates lie in the thermal region around 6500 nm, 11 300 nm and 14 000 nm, with the latter two features being most useful for differentiating mineral species. A scatter diagram of the wavelength of the 14 000 nm feature vs that of the 11 300 nm feature, powerfully differentiates carbonates. Although the wavelength of the 11 300 nm peak is easily measured, the 14 000 nm trough and peak are commonly weak and their wavelengths can confidently be used only after filtering the spectra, e.g. selecting only those with the trough and peak separated by 175–230 nm, typical of common carbonates. The method is demonstrated with drillhole 120R from the Rosebery polymetallic VHMS deposit in western Tasmania, which has been scanned with the HyLogger-3 system. A 14 000–11 300 plot shows a high degree of clustering of the drillhole 120R data close to the library spectra of calcite, dolomite, Fe-dolomite, ankerite, kutnohorite, rhodochrosite, Fe-rhodochrosite and siderite. The interpreted compositions of the carbonate spectral populations strongly correlate with the chemical populations of 144 analysed carbonates and provide a highly resolved spatial framework for interpreting carbonate alteration.     

Unconsolidated sediment distribution patterns in the KwaZulu-Natal Bight,South Africa: the role of wave ravinement in separating relict versus active sediment populations

This paper examines the distribution of unconsolidated sediment in the KwaZulu-Natal Bight located along the east coast of South Africa. Results show that there is a general shelf-wide sediment distribution of coarser grain sizes between depths of 60 and 100?m, punctuated by a broad swathe of mud offshore of the Thukela River. Seasonal changes in sediment distribution patterns are small, being restricted to seaward fining on the inner shelf off the fluvial sources. Sediment distribution reflects a partitioning between sediment populations that are current- influenced and relict (palimpsest) populations associated with submerged shorelines. Wave ravinement during the deglacial transgression, the reworking of submerged shorelines during sea-level stillstands and, to a lesser extent, the Agulhas Current system, are the dominant controls on sediment distribution.     

Seasonal changes in community composition and trophic structure of fish populations of five salt marshes along the Essex coastline, United Kingdom

European intertidal salt marshes are important nursery sites for juvenile fish and crustaceans. Due to the increasing threat of habitat loss, the seasonal changes of salt marsh fish communities need to be understood in order to appreciate the ecological and economic importance of the saltmarsh habitat. This study was the first in Great Britain to investigate the seasonal changes of salt marsh fish communities and the variation in community structure between closely located marsh habitats. Between February 2007 and March 2008, five marshes on three estuaries of the Essex coastline were sampled using flume nets to block off intertidal creeks at high tide. Fourteen fish species were caught. The community overall was dominated by three species that made up 91.6% of the total catch: the common goby Pomatoschistus microps (46.2% of the total catch), juvenile herring Clupea harengus (24.3%), and juvenile and larval sea bass Dicentrarchus labrax (21.2%). Cluster analysis demonstrated clear seasonal patterns, with some community structures unique to specific marshes or estuaries. The marsh fish community shifts from a highly diverse community during spring, to a community dominated by D. labrax and P. microps in autumn, and low diversity during winter months. Gravimetric stomach content analysis of fish community identified three main trophic guilds; macroinvertivores, planktivores and omnivores. The macroinvertivore feeding guild contained D. labrax and P. microps, the two most frequently occurring species. This investigation demonstrates the importance of British salt marshes as nursery habitats for commercial fish species.     

Market access,population density,and socioeconomic development explain diversity and functional group biomass of coral reef fish assemblages

There is overwhelming evidence that many local-scale human activities (e.g. fishing) have a deleterious effect on coral reef fish assemblages. Our understanding of how broad social phenomena (e.g. socioeconomic development) affect the diversity and function of coral reef fish assemblages however, is still poor. Here, we use structural equation models to reveal how human population density, socioeconomic development, and market access affect fishing pressure and coral cover to, in turn, explain the diversity and biomass of key functional groups of reef fish assemblages within Solomon Islands. Fishing pressure is predominantly driven by both market access and local population density, and has a clear negative effect on the diversity and function of coral reef fishes. The strong positive effect of market access on fishing pressure makes clear the importance of understanding social-ecological linkages in the context of increasingly connected societies. This study highlights the need to address broad social phenomena rather than focusing on proximate threats such as fishing pressure, to ensure the continued flow of coral reef goods and services in this time of rapid global social and environmental change.     

Approaches to knowledge sharing and capacity building: The role of local information systems in marine and coastal management

This paper explores how coastal data and information can be mobilised in information systems and applied in coastal management. The concept of an Information System is defined and described, and the potential role of Local Information System (LIS) in integrated coastal management (ICM) is considered. Three examples, from the Severn Estuary, UK the coast of the North West of England and North Wales, and the Fal and Helford estuaries, are used to demonstrate the requirements of a LIS for coastal areas. The role of GIS as part of the solution is considered in detail. The paper demonstrates how ideas from the disciplines of information systems and information science can be practically applied in coastal areas. The findings promote a holistic approach for those involved in the development of technologies and dealing with data and information about coasts and oceans.     

First seismic imaging results of tectonically complex structures at shallow depths beneath the northwest Canterbury Plains,New Zealand

Seismogenic structures underlie many regions of the vast Canterbury Plains on the South Island of New Zealand. Most of these structures are hidden beneath a layer of rapidly deposited Late Pleistocene sediments, the youth and thickness of which make the general application of conventional paleoseismological studies impractical. In an attempt to improve our understanding of potentially active structures in this region, we have acquired, processed and interpreted shallow seismic reflection data across the northwest Canterbury Plains. To separate the useful reflected signals from unusually high amplitude ambient and source-generated noise, we subjected the data to a specially tailored processing scheme that included time- and space-variant spectral balancing, custom static corrections and mutes, F-X deconvolution, DMO corrections and finite-difference migration. The final stacked and migrated seismic sections supply high-resolution images of the basement and overlying layered Cretaceous- to Quaternary-age supracrustal rocks that have been complexly faulted and folded. At one location, the uppermost Late Pleistocene layers appear to have been gently buckled.     

Infrared spectroscopic investigation of hydroxyl in β-(Mg,Fe)2SiO4 and coexisting olivine: Implications for mantle evolution and dynamics

Wadsleyite (β-(Mg,Fe)₂SiO₄) is a major constituent of the Earth's transition zone and is known to accommodate OH. The portion of the transition zone between 400–550 km could be an important source or sink for hydroxyl in plumes and slabs intersecting this region. Micro-infrared spectroscopy has been carried out on the β-phase and coexisting metastable olivine synthesized in a multianvil apparatus at 14 GPa and 1550–1650 K under hydrous conditions. Single-crystal and polycrystal specimens of both phases were analyzed in the 1800–8500 cm^?1 frequency region to determine the speciation, abundances, and partitioning behavior of the hydrous components in coexisting β-phase and olivine. β-phase spectra consistently show three distinct OH bands at 3329, 3580, and 3615 cm^?1. OH concentrations range from 10000–65000 H/10⁶ Si. A strong positive correlation of grain size and extent of transformation with OH concentration in the β-phase indicates that grain-growth and transformation rates are enhanced in a hydrous environment. Olivine spectra are variable, but consistently show a prominent broad-band absorbance representing molecular H₂O, consistent with the infrared signature of the starting material. OH concentrations in olivine range from <300–1400 H/10⁶ Si. The highest OH concentrations measured for olivine and the β-phase may represent solubility limits, in which case the OH solubility ratio between these two phases is approximately 1∶40. Where both phases coexist and are undersaturated with OH, the partitioning ratio of OH between them is about 1∶100. The large solubility contrast between olivine and the β-phase suggests a mechanism for hydrating the transition zone via olivine carried down in subducting slabs. Plumes impinging on an OH-rich upper transition region could cause H₂ or H₂O to be released upon transformation of the β-phase to olivine, resulting in initiation of secondary upwellings. If dissolution of OH weakens the β-phase, and if OH is present in the mantle, the region between 400–550 km could be a zone of low viscosity.     

Coastal Massachusetts pond development: edaphic,climatic, and sea level impacts since deglaciation

Kettle ponds in the Cape Cod National Seashore in southeastern Massachusetts differ in their evolution due to depth of the original ice block, the clay content of outwash in their drainage basins, and their siting in relation to geomorphic changes caused by sea-level rise, barrier beach formation, and saltmarsh development. Stratigraphic records of microfossil, carbon isotope, and sediment changes also document late-glacial and Holocene climatic changes.The ponds are separated into 3 groups, each of which follow different development scenarios. Group I ponds date from the late-glacial. They formed in clay-rich outwash, have perched aquifers and continuous lake sediment deposition. The earliest pollen and macrofossil assemblages in Group I pond sediments suggest tundra and spruce-willow parklands before 12 000 yr B.P., boreal forest between 12 000 and 10 500 yr B.P., bog/heath initiation and expansion during the Younger Dryas between 11 000 and 10 000 yr B.P., northern conifer forest between 10 500 and 9500 yr B.P., and establishment of the Cape oak and pitch pine barrens vegetation after 9500 yr B.P. Sedimentation rate changes suggest lowered freshwater levels between 9000 and 5000 yr B.P. caused by decreased precipitation on the Atlantic Coastal Plain. Lake sediment deposition began in the middle Holocene in Group II ponds which formed in clay-poor outwash. These ponds date from about 6000-5000 yr B.P. In these ponds sediment deposition began as sea level rose and the freshwater lens intersected the dry basins. The basal radiocarbon dates of these ponds and stable carbon isotope analyses of the pond sediments suggest a sea-level curve for Cape Cod Bay. Holocene topographic changes in upland and the landscape surrounding the ponds is reconstructed for this coastal area.Group III ponds in the late Holocene landscape of the Provincelands dunes originated as interdunal bogs about 1000 yr B.P. and became ponds more recently as water-levels increased. Peat formation in the Provincelands reflects climatic changes evident on both sides of the Atlantic region.This is the 8th in a series of papers published in this special AMQUA issue. These papers were presented at the 1994 meeting of the American Quaternary Association held 19–22 June, 1994, at the University of Minnesota, Minneapolis, Minnesota, USA. Dr Linda C. K. Shane served as guest editor for these papers.     

A rapid-response 2-D drag anemometer for atmospheric turbulence measurements

A rapid response drag anemometer for measuring streamwise and lateral components of horizontal windspeed is described. Theory of operation, design and calibration are discussed with emphasis on the electronic preconditioning of signals and problems associated with using a mechanically resonant system as a sensor. Field comparisons showed half-hourly means and standard deviations of the streamwise component to be within 8% and 5% of respective values obtained from a 3-dimensional sonic anemometer. The lateral component from the drag anemometer was significantly more noisy than that from the 3-D sonic due to induced oscillations arising from vortex shedding. After mechanical and electronic filtering, half-hourly standard deviation comparisons agreed to within 6% for this component. Friction velocities obtained from the drag anemometer in combination with a 1-D sonic, agreed with measurements from the 3-D sonic anemometer to within 4% over a measured range of 0.05 to 1.2 m s^-1