Long Island Sound: Distributions,trends, and effects of chemical contamination

Trace metals and organic contaminants concentrations are monitored annually in surface sediments, blue mussel tissue, and winter flounder livers at multiple sites in Long Island Sound by National Oceanic and Atmospheric Administration’s National Status and Trends (NS&T) program for Marine Environmental Quality. The NS&T program is also conducting various studies on the bioeffects of contaminants in the sound. Three years of monitoring results indicate organic and elemental contaminants concentrations in sediments and biota at sites in the western portion of the sound are high on a national scale. Possible decreasing trends in cadmium and chlordane in the sound are suggested by the 1986–1988 data for their concentrations in mussels. A comparison between NS&T Mussel Watch results and those of the Environmental Protection Agency’s Mussel Watch, conducted from 1976 through 1978, indicated a decadal increase in copper concentrations and a decrease in lead in the sound. Bioeffects studies in the sound have revealed responses to contamination only in localized zones where contaminant levels are very high.     

Enhanced boulder weathering under late-lying snowpatches

A Schmidt test hammer was employed to assess the aggregate surface hardness of samples of boulders dug out from under late-lying snowpatches at sites in Switzerland, Scotland and Norway. The results were compared with an equivalent set of readings made on boulders at nearby snow-free control sites. The results in every case reveal that the aggregate surface hardness of boulders buried by late-lying snow is significantly less (at the 0·001 level) than that of boulders at the corresponding control sites. This result indicates that late-lying snow significantly enhances rock weathering, probably because boulder and rock surfaces are exposed to prolonged wetting by percolating meltwater under late-lying snowbeds.     

The influence of riparian vegetation on near‐bank turbulence: a flume experiment

Measurements from a fixed‐bed, Froude‐scaled hydraulic model of a stream in northeastern Vermont demonstrate the importance of forested riparian vegetation effects on near‐bank turbulence during overbank flows. Sections of the prototype stream, a tributary to Sleepers River, have increased in channel width within the last 40 years in response to passive reforestation of its riparian zone. Previous research found that reaches of small streams with forested riparian zones are commonly wider than adjacent reaches with non‐forested, or grassy, vegetation; however, driving mechanisms for this morphologic difference are not fully explained. Flume experiments were performed with a 1:5 scale, simplified model of half a channel and its floodplain, mimicking the typical non‐forested channel size. Two types of riparian vegetation were placed on the constructed floodplain: non‐forested, with synthetic grass carpeting; and forested, where rigid, randomly distributed, wooden dowels were added. Three‐dimensional velocities were measured with an acoustic Doppler velocimeter at 41 locations within the channel and floodplain at near‐bed and 0·6‐depth elevations. Observations of velocity components and calculations of turbulent kinetic energy (TKE), Reynolds shear stress and boundary shear stress showed significant differences between forested and non‐forested runs. Generally, forested runs exhibited a narrow band of high turbulence between the floodplain and main channel, where TKE was roughly two times greater than TKE in non‐forested runs. Compared to non‐forested runs, the hydraulic characteristics of forested runs appear to create an environment with higher erosion potential. Given that sediment entrainment and transport can be amplified in flows with high turbulence intensity and given that mature forested stream reaches are wider than comparable non‐forested reaches, our results demonstrated a possible driving mechanism for channel widening during overbank flow events in stream reaches with recently reforested riparian zones. Copyright © 2007 John Wiley & Sons, Ltd.     

The Lerokis and Kali Kuning submarine exhalative gold-silver-barite deposits, Wetar Island, Maluku, Indonesia

Wetar, an island in the southern part of the Banda Arc, is made up submarine volcanic rocks, with the oldest rocks exposed being subvolcanic intrusions and flows dated at 12 Ma. Basaltic andesite pillow lavas and intercalated volcaniclastic sedimentary rocks grade upward into more felsic volcanic lavas, tuffs and breccias, and sedimentary rocks and epiclastic mudflows cap the sequence.Gold-silver mineralization occurs at Lerokis and Kali Kuning, 3.5 km apart on the north coast of the island, in stratiform barite sand, clay or silt. The sediments are underlain by Cu-rich massive pyrite in volcanic breccias and overlain by a limestone dated at about 4 Ma. Foot wall volcanic breccias and lavas show intense clay-pyrite alteration indicating temperatures higher than 230°C.In situ geological resources, prior to the inception of mining in 1990, totalled 2.9 Mt at 3.5 g/t Au, 114 g/t Ag and 40% barite at Lerokis and 2.2 Mt at 5.5 g/t Au, 146 g/t Ag and 60% barite at Kali Kuning. Most of the Au occurs as electrum, associated with limonite, jarosite and goethite, and most of the Ag is in tetrahedrite and sulphosalts. High Pb contents, between 0.5% and 1.4% Pb on average, derive from plumbojarosite, sulphosalts and cerrussite, and there is, on average, between 200 ppm to 900 ppm Cu, 0.2% Sb, 0.1% As, 100 ppm to 200 ppm Zn, and 18 ppm Hg. Underlying massive sulphide mineralization is mainly pyrite-marcasite with zones of Cu enrichment. A significant part of the Cu is contained in enargite.Formation likely took place at less than 600 m water depth in a sea floor caldera setting similar to the Kuroko district in Japan. The ferruginous sediments hosting the Au-barite deposits may have originated through erosion like the ochres of Cyprus. These stratiform Au-barite deposits highlight a new style of sea floor mineralization not clearly recognized before. Modern-day analogues have been described from a variety of sea floor settings.     

Linking the Abundance of Estuarine Fish and Crustaceans in Nearshore Waters to Shoreline Hardening and Land Cover

Human alteration of land cover (e.g., urban and agricultural land use) and shoreline hardening (e.g., bulkheading and rip rap revetment) are intensifying due to increasing human populations and sea level rise. Fishes and crustaceans that are ecologically and economically valuable to coastal systems may be affected by these changes, but direct links between these stressors and faunal populations have been elusive at large spatial scales. We examined nearshore abundance patterns of 15 common taxa across gradients of urban and agricultural land cover as well as wetland and hardened shoreline in tributary subestuaries of the Chesapeake Bay and Delaware Coastal Bays. We used a comprehensive landscape-scale study design that included 587 sites in 39 subestuaries. Our analyses indicate shoreline hardening has predominantly negative effects on estuarine fauna in water directly adjacent to the hardened shoreline and at the larger system-scale as cumulative hardened shoreline increased in the subestuary. In contrast, abundances of 12 of 15 species increased with the proportion of shoreline comprised of wetlands. Abundances of several species were also significantly related to watershed cropland cover, submerged aquatic vegetation, and total nitrogen, suggesting land-use-mediated effects on prey and refuge habitat. Specifically, abundances of four bottom-oriented species were negatively related to cropland cover, which is correlated with elevated nitrogen and reduced submerged and wetland vegetation in the receiving subestuary. These empirical relationships raise important considerations for conservation and management strategies in coastal environments.     

Seismic properties of gabbroic sections in oceanic core complexes: constraints from seafloor drilling

Marine Geophysical Research - The physical properties of rock within Oceanic Core Complexes (OCC) provide information about the history of magmatism, deformation and alteration associated with...     

Last glacial aggradation and postglacial sediment production from the non-glacial Waipaoa and Waimata catchments, Hikurangi Margin, North Island, New Zealand

The sediment flux generated by postglacial channel incision has been calculated for the 2150 km², non-glacial, Waipaoa catchment located on the tectonically active Hikurangi Margin, eastern North Island, New Zealand. Sediment production both at a sub-catchment scale and for the Waipaoa catchment as a whole was calculated by first using the tensioned spline method within ARC MAP to create an approximation of the aggradational Waipaoa-1 surface (contemporaneous with the Last Glacial Maximum), and second using grid calculator functions in the GIS to subtract the modern day surface from the Waipaoa-1 surface. The Waipaoa-1 surface was mapped using stereo aerial photography, and global positioning technology fixed the position of individual terrace remnants in the landscape. The recent discovery of Kawakawa Tephra within Waipaoa-1 aggradation gravels in this catchment demonstrates that aggradation was coincidental with or began before the deposition of this 22 600 ¹⁴C-year-old tephra and, using the stratigraphic relationship of Rerewhakaaitu Tephra, the end of aggradation is dated at ca 15 000 ¹⁴C years (ca 18 000 cal. years BP). The construction of the Waipaoa-1 terrace is considered to be synchronous and broadly correlated with aggradation elsewhere in the North Island and northern South Island, indicating that aggradation ended at the same time over a wide area. Subsequent downcutting, a manifestation of base-level lowering following a switch to postglacial incision at the end of glacial-age aggradation, points to a significant Southern Hemisphere climatic warming occurring soon after ca 15 000 ¹⁴C years (ca 18 000 cal. years BP) during the Older Dryas interval. Elevation differences between the Waipaoa-1 (c.15 ka) terrace and the level of maximum channel incision (i.e. before aggradation since the turn of the 20th century) suggest about 50% of the topographic relief within headwater reaches of the Waipaoa catchment has been formed in postglacial times. The postglacial sediment flux generated by channel incision from Waipaoa catchment is of the order of 9.5 km³, of which ~ 6.6 km³ is stored within the confines of the Poverty Bay floodplain. Thus, although the postglacial period represented a time of high terrigenous sediment generation and delivery, only ~ 30% of the sediment generated by channel incision from Waipaoa catchment probably reached the marine shelf and slope of the Hikurangi Margin during this time. The smaller adjacent Waimata catchment probably contributed an additional 2.6 km³ to the same depocentre to give a total postglacial sediment contribution to the shelf and beyond of ~ 5.5 km³. Sediment generated by postglacial channel incision represents only ~ 25% of the total sediment yield from this landscape with ~ 75% of the estimated volume of the postglacial storage offshore probably derived from hillslope erosion processes following base-level fall at times when sediment yield from these catchments exceeded storage.     

A multi‐scale statistical approach to assess the effects of connectivity of road and stream networks on geomorphic channel condition

Roads in rural, upland landscapes are important sources of runoff and sediment to waterways. The downstream effects of these sources should be related to the connectivity of roads to receiving waters. Recent studies have explored this idea, but only simple metrics have been used to characterize connectivity and few studies have quantified the downstream effects of road–stream connectivity on sediment or solute budgets and channel morphology. In this study, we evaluated traditional and newly developed connectivity metrics that utilized features of landscape position and delivery pathway to characterize road–stream connectivity in upland settings. Using data on stream geomorphic conditions developed by the Vermont Agency of Natural Resources (Montpelier, VT), we related road connectivity metrics to channel condition on a set of 101 forested, upland streams with minimal development other than predominantly gravel road networks. Logistic regression indicated that measures of road density, proximity and orientation successfully distinguished among categories of stream geomorphic condition at multiple geographic scales. Discriminant function analysis using a set of inherent channel characteristics combined with road connectivity metrics derived at the reach corridor scale successfully distinguished channel condition for over 70% of the channels evaluated. This research contributes to efforts to evaluate the cumulative downstream effects of roads on stream channels and aquatic resources and provides a new means of watershed assessment to derive metrics that can be used to predict channel condition. Copyright © 2014 John Wiley & Sons, Ltd.     

Seasonality and growth patterns using isotope sclerochronology in shells of the Pliocene scallop Chesapecten madisonius

Growth lines and variation in oxygen and carbon isotope ratios (δ¹⁸O and δ¹³C) in shells of the Pliocene scallop Chesapecten madisonius preserve seasonal chronologies of biological and environmental change. This study evaluated whether (1) prominent growth lines were formed annually, and (2) growth rates estimated using isotope sclerochronology were comparable to rates estimated using visual inspection (measuring the width between external growth lines). We compared both techniques for estimating growth rates and age on three late to mid-Pliocene C. madisonius shells. The first approach located prominent growth lines on the δ¹⁸O time series, and differentiated between annual and non-annual (disturbance) growth lines. The second approach assumed all prominent lines were annual. This comparison showed that visual inspection underestimated growth rates and overestimated age. Seasonal timing of annual growth line formation using isotope sclerochronology provided unexpected results. Because this region fell within the warm-temperate paleobiogeographic province, we predicted annual lines formed during summers (most negative δ¹⁸O values). Instead, annual growth lines coincided with the most positive δ¹⁸O values (winter), typical of bivalves from cold-temperate regions. Moreover, shells recorded seasonal temperatures ranging from 3.2–20.8°C, a range lower than the thermal regime defined for warm-temperate environments (8–25°C). Possibly, the Sea Slope Gyre, which mixed eddies and cold filaments of the Labrador Current and warm waters of the Gulf Stream, penetrated the warm-temperate environment in this region. Alternatively, warm-water fauna from the zoogeographic Carolinian subprovince migrated northward and endured by virtue of warm summer temperatures. Regardless of the explanation, our findings provide a glimpse of mid-latitude seasonal temperature range for a warm climate episode during the mid-Pliocene.     

Petrogenesis and structural petrology of high-pressure metabasalt pods,Sivrihisar, Turkey

Lawsonite eclogite pods ranging in size from 3 cm to 6 m occur in lawsonite blueschist and eclogite facies metasedimentary and metabasaltic rocks in the Sivrihisar Massif, Turkey. Some pods have a core of lawsonite eclogite surrounded by alternating, centimeter-scale layers of lawsonite blueschist, eclogite, and transitional eclogite–blueschist, all with similar basaltic bulk composition. These pods also contain texturally late lawsonite-rich veins and layers. Most eclogites and blueschists within the pods lack reaction textures, but some blueschists near pod margins contain texturally complex garnet as well as glaucophane rims on omphacite, suggesting retrogression of eclogite to blueschist. Phase diagrams (pseudosections) calculated for the lawsonite eclogite core of a meter-scale pod indicate that the eclogite equilibrated at ∼22–24 kbar, ∼520°C. Lawsonite eclogite and blueschist at the tectonized margin of the same pod equilibrated at similar temperatures and slightly lower pressures. The composite eclogite–blueschist pod is foliated, lineated, and folded. An earlier generation of lineated omphacite in the pod core has a different spatial orientation than the lineation at the pod margin, although electron backscattered diffraction data show that core and rim omphacite have similar lattice preferred orientation patterns. Petrologic and structural data are consistent with mechanical formation of pods by folding and dissection of eclogite layers at high-P, and localized retrogression at pod margins during initial stages of exhumation at P–T conditions >425°C, 16 kbar.