S. J. Shahtaheri  H. Assilian  R. Karimi-Kia 《International Journal of Environmental Science and Technology》2004,1(3):171-176

Respiratory system disorders occur in aluminum potroom workers despite pre-employment medical examinations. The aims of this study were to measure fluoride and its compounds in the potroom workplace atmosphere as well as workers’ breathing zone air, examine the blood eozinophile cells count in the workers exposed to the fluoride compounds, and evaluate the respiratory symptoms and dysfunctions caused during the occupational exposure in potroom workers. To achieve these objectives, a study was carried out in 10 workplaces (potrooms) of Aluminum Producing Plants in Arak city located at Central Iran. Through this study, the data obtained from 160 workers (100 cases and 60 controls) were statically processed. The selected controls were matched for age, year of starting employment, smoking habit, and body mass index (BMI). The total fluoride compounds concentration of potroom, mean concentration of workers’ breathing zone air at different job positions were measured showed high concentration compared to the Threshold Limit Value-Time Weighted Average (TLV-TWA). The incidence of respiratory symptoms, the number of blood eozinophile, and WBC counts were higher than normal range in case group. During this study, the susceptible aluminum potroom workers to occupational asthma were also identified. Through this study, it was concluded that, workers employing in the potroom in aluminum industries are at risk for respiratory disorders and a continuous workplace monitoring is needed to evaluate workers exposures.  相似文献   

    

Gleb S Pokrovski  Jacques Schott  Jean-Louis Hazemann 《Geochimica et cosmochimica acta》2003,67(19):3559-3573

The influence of aqueous silica on the hydrolysis of iron(III) nitrate and chloride salts in dilute aqueous solutions (m_Fe ∼ 0.01 mol/kg) was studied at ambient temperature using X-ray absorption fine structure (XAFS) spectroscopy at the Fe K-edge. Results show that in Si-free iron nitrate and chloride solutions at acid pH (pH < 2.5), Fe is hexa-coordinated with 6 oxygens of H₂O- and/or OH-groups in the first coordination sphere of the metal, at an Fe-O distance of 2.00 ± 0.01 Å. With increasing pH (2.7 < pH < 13), these groups are rapidly replaced by bridging hydroxyls (-OH-) or oxygens (-O-), and polymerized Fe hydroxide complexes form via Fe-(O/OH)-Fe bonds. In these polymers, the first atomic shell of iron represents a distorted octahedron with six O/OH groups and Fe-O distances ranging from 1.92 to 2.07 Å. The Fe octahedra are linked together by their edges (Fe-Fe distance 2.92-3.12 Å) and corners (Fe-Fe distance ∼3.47 ± 0.03 Å). The Fe-Fe coordination numbers (N_edge = 1-2; N_corner = 0.5-0.7) are consistent with the dominant presence of iron dimers, trimers and tetramers at pH 2.5 to 2.9, and of higher-polymerized species at pH > 3.At pH > 2.5 in the presence of aqueous silica, important changes in Fe(III) hydrolysis are detected. In 0.05-m Si solutions (pH ∼ 2.7-3.0), the corner linkages between Fe octahedra in the polymeric complexes disappear, and the Fe-Fe distances corresponding to the edge linkages slightly increase (Fe-Fe_edge ∼ 3.12-3.14 Å). The presence of 1 to 2 silicons at 3.18 ± 0.03 Å is detected in the second atomic shell around iron. At basic pH (∼12.7), similar structural changes are observed for the iron second shell. The Fe-Si and Fe-Fe distances and coordination numbers derived in this study are consistent with (1) Fe-Si complex stoichiometries Fe₂Si_1-2 and Fe₃Si_2-3 at pH < 3; (2) structures composed of Fe-Fe dimers and trimers sharing one or two edges of FeO₆-octahedra; and (3) silicon tetrahedra linked to two neighboring Fe octahedra via corners. At higher Si concentration (0.16 m, polymerized silica solution) and pH ∼ 3, the signal of the Fe second shell vanishes indicating the destruction of the Fe-Fe bonds and the formation of different Fe-Si linkages. Moreover, ∼20 mol.% of Fe is found to be tetrahedrally coordinated with oxygens in the first coordination shell (R_Fe-O = 1.84 Å). This new finding implies that Fe may partially substitute for Si in the tetrahedral network of the silica polymers in Si-rich solutions.The results of this study demonstrate that aqueous silica can significantly inhibit iron polymerization and solid-phase formation, and thus increase the stability and mobility of Fe(III) in natural waters. The silica “poisoning” of the free corner sites of iron-hydroxide colloids should reduce the adsorption and incorporation of trace elements by these colloids in Si-rich natural waters.  相似文献   

  总被引：1，自引：0，他引：1  

HOLNESS  M. B.; HUMPHREYS  M. C. S. 《Journal of Petrology》2003,44(11):1961-1976

Field evidence points to localization of magma flowing in aTertiary doleritic sill on the Isle of Mull, Inner Hebrides,Scotland. Regions of the sill in which flow was short-livedhave chilled margins, a narrow or absent metamorphic aureole,and alignment of plagioclase crystals resulting in pronounced,flow-parallel, lineations on fracture surfaces (Type I regions).Prolonged flow resulted in blocky, coarse-grained dolerite withno chilled margins, and an extensive metamorphic aureole (TypeII regions). The distribution of Type I and Type II regionsshows no spatial pattern, with stagnant solidifying sectionsimmediately adjacent to sections with contemporaneous activeand sustained flow. The transition between Type I and Type IIregions occurs as the sill thickness exceeds 3·5 m. Ourobservation that sustained flow was only possible in regionsof the sill thicker than 3.5 m is consistent with previouslypublished theoretical models which predict a critical sill thicknessin the range 2·2–5 m. Regions of the sill narrowerthan this experienced a single injection of magma. Simple modelsto determine flow duration from the width of the metamorphicaureole demonstrate that progressive focusing of flow into widerparts of the conduit created discrete channels active for upto 5 months. KEY WORDS: flow localization; magma; Mull; sill; Traigh Bhàn na Sgùrra  相似文献   

    

Martin J Siegert  Richard C.A HindmarshGordon S Hamilton 《Quaternary Research》2003,59(1):114-121

Internal isochronous ice sheet layers, recorded by airborne ice-penetrating radar, were measured along an ice flowline across a large (>1 km high) subglacial hill in the foreground of the Transantarctic Mountains. The layers, dated through an existing stratigraphic link with the Vostok ice core, converge with the ice surface as ice flows over the hill without noticeable change to their separation with each other or the ice base. A two-dimensional ice flow model that calculates isochrons and particle flowpaths and accounts for ice flow over the hill under steady-state conditions requires net ablation (via sublimation) over the stoss face for the predicted isochrons to match the measured internal layers. Satellite remote sensing data show no sign of exposed ancient ice at this site, however. Given the lack of exposed glacial ice, surface balance conditions must have changed recently from the net ablation that is predicted at this site for the last 85,000 years to accumulation.  相似文献   

  总被引：1，自引：0，他引：1  

S. J. Davies  M. R. Gibling† 《Sedimentology》2003,50(3):415-439

Abstract The Joggins Formation was deposited in the Cumberland Basin, which experienced rapid mid‐Carboniferous subsidence on bounding faults. A 600 m measured section of coastal and alluvial plain strata comprises cycles tens to hundreds of metres thick. The cycles commence with coal and fossiliferous limestone/siltstone intervals, interpreted as widespread flooding events. These intervals are overlain by coarsening‐upward successions capped by planar‐based sandstone mounds, up to 100 m in width that represent the progradation of small, river‐generated delta lobes into a standing body of open water developed during transgression. The overlying strata contain sand‐rich heterolithic packages, 1–8 m thick, that are associated with channel bodies 2–3 m thick and 10–50 m wide. Drifted plant debris, Calamites groves and erect lycopsid trees are preserved within these predominantly green‐grey heterolithic sediments, which were deposited on a coastal wetland or deltaic plain traversed by channel systems. The cycles conclude with red siltstones, containing calcareous nodules, that are interbedded with thin sandstones and associated with both single‐storey channel bodies (1–1·5 m thick and 2–3 m wide) and larger, multistorey channels (3–6 m thick) with incised margins. Numerous channel bodies at the same level suggest that multiple‐channel, anastomosed river systems were developed on a well‐drained floodplain. Many minor flooding surfaces divide the strata into parasequences with dominantly progradational and aggradational stacking patterns. Multistorey channel bodies are relatively thin, fine grained and modestly incised, and palaeosols are immature and cumulative. The abundance and prominence of flooding surfaces suggests that base‐level rise was enhanced, whereas the lack of evidence for abrupt basinward stepping of facies belts, coupled with the absence of strong fluvial incision and mature palaeosols, suggests that base‐level fall was suppressed. These architectural features are considered to reflect a tectonic architectural signature, in accordance with the high‐subsidence basinal setting. Evidence for restricted marine influence and variation in floral assemblages suggests modulation by eustatic and climatic effects, although their relative importance is uncertain.  相似文献   

    

S. P. Johnson  H. N. C. Cutten  S. Muhongo  B. De Waele 《Tectonophysics》2003,375(1-4):125

U–Pb sensitive high resolution ion microprobe (SHRIMP) dating of zircons from charnockitic and garnet–biotite gneisses from the central portion of the Mozambique belt, central Tanzania indicate that the protolith granitoids were emplaced in a late Archaean, ca. 2.7 Ga, magmatic event. These ages are similar to other U–Pb and Pb–Pb ages obtained for other gneisses in this part of the belt. Zircon xenocrysts dated between 2.8 and 3.0 Ga indicate the presence of an older basement. Major and trace element geochemistry of these high-grade gneisses suggests that the granitoid protoliths may have formed in an active continental margin environment. Metamorphic zircon rims and multifaceted metamorphic zircons are dated at ca. 2.6 Ga indicating that these rocks were metamorphosed some 50–100 my after their emplacement. Pressure and temperature estimates on the charnockitic and garnet–biotite gneisses were obscured by post-peak metamorphic compositional homogenisation; however, these estimates combined with mineral textures suggest that these rocks underwent isobaric cooling to 800–850 °C at 12–14 kbar. It is considered likely that the granulite facies mineral assemblage developed during the ca. 2.6 Ga event, but it must be considered that it might instead represent a pervasive Neoproterozoic, Pan African, granulite facies overprint, similar to the ubiquitous eastern granulites further to the east.  相似文献   

    

Azm S. Al-Homoud  T. Fouad  A. Mokhtar 《Geotechnical and Geological Engineering》2003,21(1):47-62

The axial base and skin capacities of piles bored in cohesion less soils are often estimated using empirical, semi-empirical and theoretical methods. The aim of this paper is to assess the applicability and evaluate the accuracy of different predictions methods available in the literature, via comparison with data from 43 field pile load tests conducted on shafts drilled in the region of the United Arab Emirates. Janbu's theoretical method (1989) with the parameter (=75°) and Vesics theoretical method (1975) yielded accurate predictions for the base resistances. Burlands approach (1973) overpredicts the skin capacities with an average predicted-to-estimated ratio (q_p/q_e) of three times greater than the unity while using values of the coefficient of earth pressure (k=05k_o) and the angle of soil-pile friction (=23).  相似文献   

    

D. S. Wiebe  A. V. Tutukov  B. M. Shustov 《Astronomy Reports》2001,45(11):854-860

Various origins for the formation of the heavy-element abundance gradients observed in nearly all disk galaxies are analyzed in the framework of evolutionary models. In an isolated galaxy, there is a radial gradient of the abundance of heavy elements only early in its evolution (the first several billion years), which subsequently practically disappears. The gradients of chemical compositions of young objects and the interstellar gas require that typical disk galaxies be open systems (i.e., that they eject some heavy elements into circumgalactic space and/or accrete intergalactic gas) and that the rates of both processes be dependent on galactocentric distance.  相似文献   

    

Jeff L. Doebrich  Timothy S. Hayes  Alim A. Siddiqui  Yasin Saleh  Peter R. Johnson  Fayek H. Kattan  Craig H. Mackay  Bandar Shaikan  Mabrouk Basahal  Hani Zahran 《Gondwana Research》2001,4(2):162-163

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  总被引：2，自引：0，他引：2  

G. Dal Piaz  G. Cortiana  A. Del Moro  S. Martin  G. Pennacchioni  P. Tartarotti 《International Journal of Earth Sciences》2001,90(3):668-684

The Austroalpine Sesia-Lanzo inlier and upper Austroalpine Dent Blanche, Mt. Mary and Pillonet outliers occur on top of the western-Alpine orogenic wedge and, as a whole, override the structurally composite ophiolitic Piemonte zone. Instead, the Mt. Emilius, Glacier-Rafray, Etirol-Levaz and other lower Austroalpine eclogitic outliers are inserted within the Piemonte zone, between its upper (Combin) and lower (Zermatt-Saas) tectonic elements, or within the latter. Rb-Sr dating on phengitic micas show that the eclogitic imprint in the lower Austroalpine outliers, conventionally regarded as Late Cretaceous by comparison with the Sesia-Lanzo inlier, is of Eocene age (49-40 Ma), like the underlying Zermatt-Saas ophiolite (45-42 Ma) between the Aosta valley and Gran Paradiso massif. ⁴⁰Ar-³⁹Ar plateau ages on the same mica concentrates of the ophiolitic Zermatt-Saas nappe (46-43 Ma) are consistent with Rb-Sr dating, whereas that on the Austroalpine Glacier-Rafray klippe (92 Ma) is influenced by argon excess. The lower Austroalpine outliers underwent the subduction metamorphism concurrently with the Zermatt-Saas nappe, 20-25 Ma later than the eclogitic Sesia-Lanzo inlier and blueschist Pillonet klippe. The temporal gap and present intra-ophiolitic position mean that the lower Austroalpine outliers were probably derived from an intraoceanic extensional allochthon (Mt. Emilius domain) stranded inside the Piemonte-Ligurian ocean far from the Dent Blanche-Sesia domain and Adriatic margin.  相似文献