Facies architecture of a submarine fan channel–levee complex: the Juniper Ridge Conglomerate, Coalinga, California

The Upper Cretaceous Juniper Ridge Conglomerate (JRC) near Coalinga, California, provides a rare, high-quality exposure of a submarine channel to overbank transition. The facies architecture of the JRC comprises a thick, predominantly mudstone sequence overlain by a channellized conglomerate package. Conglomeratic bounding surfaces truncate successions of interbedded turbiditic sandstones and mudstones both vertically and laterally. Thick-bedded, massive sandstones are interbedded with conglomerates. Facies architecture, palaeocurrent indicators, slump features, sandstone percentages and sandstone bed thickness trends lead to the interpretation that these elements comprise channel and overbank facies. A vertical sequence with conglomerate at the base, followed by thick-bedded sandstone, and capped by interbedded turbiditic sandstone and mudstone form a fining-upward lithofacies association that is interpreted as a single channel-fill/overbank system. Three similar lithofacies associations can be related to autocyclic processes of thalweg migration and submarine fan aggradation or to allocyclically driven changes in sediment calibre.     

Glacio-periglacial landforms within the Susquehanna Great Bend area of New York and Pennsylvania

Previous attention has been called to the morphology of the glaciated Appalachian Plateau, including periglacial phenomena (Coates, 1970; Conners, 1969). This paper deals with an unusually well-developed hierarchy of small landforms in the Great Bend area of the Susquehanna River. Essential properties of these features include: (1) concentration in N-S valleys, (2) till composition, (3) concavo-convex form, sometimes ending in a hill on the valley floor, (4) alternation with steep, truncated bedrock spurs, (5) a col in the interfluve at their head. These characteristics could be explained by the following sequence of events. A prior fluvial landscape was eroded with tributary streams forming lateral valleys that head in cols along the divides. The main stream flowed south between interlocking spurs. Ice then widened the valley, leaving truncated spurs and a straightened stream. Deposition of locally derived till filled tributary valleys, similar to till shadows (Coates, 1966). In periglacial conditions, while nivation was widening the tributary valley heads, solifluction in the unstable till was forming the concavo-convexities that alternate with the truncated bedrock spurs. The hierarchy of forms range from minor convexities to small hills on the main valley floor. Thus, the features are primarily of periglacial origin, but owe their development and position to prior subaerial and glacial events. The cycle may have occurred during more than a single glacial episode. The recession of bedrock spurs and the valley floor convexity of the till features have caused a reversal in stream sinuosity of the main valley.     

Minimizing dredging disposal via sediment management in New York Harbor

The Port of New York/New Jersey is naturally shallow, and therefore dredging is required to maintain depths necessary for navigation. About six million cubic yards of material must be dredged annually to maintain navigation channels and berthing areas. Opportunities for disposal of dredged materials in the metropolitan region are limited. The existing ocean disposal site that has, until recently, received the majority of dredged materials is nearing capacity. Under the new, more stringent, guidance for ocean disposal, a large percentage of the dredged material is not considered acceptable for ocean disposal because of contamination. This paper explores nondredging alternatives to reduce the volume of materials to be dredged, thus reducing the disposal volume. These alternatives include short-term options (e.g., reprofiling operations, in which sediments from high spots in berths are dragged to depressions in lower spots) and long-term sedimentation minimization options (e.g., subsurface berms or air bubblers deployed around berths and interpier areas). These methods require an understanding of sedimentation/circulation patterns of the harbor as a whole and the local area in which the specific methodology may be employed.     

Analysis of the Chesapeake Bay Hypoxia Regime Shift: Insights from Two Simple Mechanistic Models

Recent studies of Chesapeake Bay hypoxia suggest higher susceptibility to hypoxia in years after the 1980s. We used two simple mechanistic models and Bayesian estimation of their parameters and prediction uncertainty to explore the nature of this regime shift. Model estimates show increasing nutrient conversion efficiency since the 1980s, with lower DO concentrations and large hypoxic volumes as a result. In earlier work, we suggested a 35% reduction from the average 1980–1990 total nitrogen load would restore the Bay to hypoxic volumes of the 1950s–1970s. With Bayesian inference, our model indicates that, if the physical and biogeochemical processes prior to the 1980s resume, the 35% reduction would result in hypoxic volume averaging 2.7 km³ in a typical year, below the average hypoxic volume of 1950s–1970s. However, if the post-1980 processes persist the 35% reduction would result in much higher hypoxic volume averaging 6.0 km³. Load reductions recommended in the 2003 agreement will likely meet dissolved oxygen attainment goals if the Bay functions as it did prior to the 1980s; however, it may not reach those goals if current processes prevail.     

The synergistic effect of calcium on organic carbon sequestration to ferrihydrite

Sequestration of organic carbon (OC) in environmental systems is critical to mitigating climate change. Organo-mineral associations, especially those with iron (Fe) oxides, drive the chemistry of OC sequestration and stability in soils. Short-range-ordered Fe oxides, such as ferrihydrite, demonstrate a high affinity for OC in binary systems. Calcium commonly co-associates with OC and Fe oxides in soils, though the bonding mechanism (e.g., cation bridging) and implications of the co-association for OC sequestration remain unresolved. We explored the effect of calcium (Ca²⁺) on the sorption of dissolved OC to 2-line ferrihydrite. Sorption experiments were conducted between leaf litter-extractable OC and ferrihydrite at pH 4 to 9 with different initial C/Fe molar ratios and Ca²⁺ concentrations. The extent of OC sorption to ferrihydrite in the presence of Ca²⁺ increased across all tested pH values, especially at pH ≥ 7. Sorbed OC concentration at pH 9 increased from 8.72 ± 0.16 to 13.3 ± 0.20 mmol OC g^?1 ferrihydrite between treatments of no added Ca²⁺ and 30 mM Ca²⁺ addition. Batch experiments were paired with spectroscopic studies to probe the speciation of sorbed OC and elucidate the sorption mechanism. ATR-FTIR spectroscopy analysis revealed that carboxylic functional moieties were the primary sorbed OC species that were preferentially bound to ferrihydrite and suggested an increase in Fe-carboxylate ligand exchange in the presence of Ca at pH 9. Results from batch to spectroscopic experiments provide significant evidence for the enhancement of dissolved OC sequestration to 2-line ferrihydrite and suggest the formation of Fe–Ca-OC ternary complexes. Findings of this research will inform modeling of environmental C cycling and have the potential to influence strategies for managing land to minimize OM stabilization.