Intrinsic groundwater vulnerability assessment: issues,comparison of different methodologies and correlation with nitrate concentrations in NW Italy

The concept of aquifer vulnerability is certainly useful in the field of groundwater protection. Nevertheless, within the scientific community, the definition of vulnerability is still under debate and lacks standardisation. As a consequence, the methods for evaluating the vulnerability degree are numerous and often lead to conflicting results. Thus, in this study, three methods that are commonly used in groundwater vulnerability assessments due to their easy application (namely DRASTIC, GOD and TOT) were utilised in four areas of the Piedmont region (NW Italy). The results obtained by the different methods were compared and correlated with the nitrate concentrations in the groundwater. The aims of the study were (i) to evaluate the effectiveness of the adopted methods and their comparability, (ii) to discuss the limits of the intrinsic vulnerability methods and (iii) to verify the applicability of nitrate as a tracer in the assessment of groundwater vulnerability or explain the reasons why it is not applicable. It was observed that the three intrinsic vulnerability methods are not able to uniquely identify the most or least vulnerable areas. Additionally, the comparison of the intrinsic vulnerability indexes only occasionally showed a reasonable correlation. Furthermore, there was no clear correlation between the vulnerability indexes and nitrate concentrations in the groundwater. These results could be explained by several reasons: (1) the methods are mostly based on the level of groundwater protection provided by the overlaying lithologies and do not consider the physical processes occurring in the aquifer; (2) the intrinsic vulnerability methods only consider vertical pathways for contaminants, but a pre-existing contaminant could be present in the aquifer; (3) groundwater nitrate concentrations are affected by the nitrate input and surplus; and (4) nitrates are subject to physical and biological attenuation in aquifers and cannot necessarily be considered stable tracers in the assessment of groundwater vulnerability.     

Application of Binary Permeability Fields for the Study of $${\hbox {CO}_{2}}$$ Leakage from Geological Carbon Storage in Saline Aquifers of the Michigan Basin

The feasibility of geological carbon storage (GCS) sites depends on their capacity to retain safely \({\hbox {CO}_{2}}\). While deep saline formations and depleted gas/oil reservoirs are good candidates to sequester \({\hbox {CO}_{2}}\), gas/oil reservoirs typically have a limited storage capacity compared to ideal targets (\(\sim \) 1 Mt/year) considered for \({\hbox {CO}_{2}}\) disposal (Celia et al. in Water Resour Res 51(9):6846–6892, 2015. doi: 10.1002/2015WR017609). In this respect, deep saline aquifers are considered more appropriate formations for GCS, but present the disadvantage of having limited characterization data. In particular, information about the continuity of the overlying sealing formations (caprock) is often sparse if it exists at all. In this work, a study of \({\hbox {CO}_{2}}\) leakage is conducted for a candidate GCS site located in the Michigan Basin, whose sealing properties of the caprock are practically unknown. Quantification of uncertainty on \({\hbox {CO}_{2}}\) leakage from the storage formation is achieved through a Monte Carlo simulation approach, relying on the use of a computationally efficient semi-analytical leakage model based upon the solution derived by Nordbotten et al. (Environ Sci Technol 43(3):743–749, 2009), which assumes leakage occurs across “passive” wells intersecting caprock layers. A categorical indicator Kriging simulator is developed and implemented to represent the caprock sealing properties and model the permeability uncertainty. Binary fields of caprock permeability are generated and exhibit mostly low permeability, with sparsely-occurring local high permeability areas where brine and \({\hbox {CO}_{2}}\) may leak out of the storage formation. In addition, the feasibility of extending the use of the semi-analytical model to large-area leakage pathways is studied. This work advances a methodology for preliminary uncertainty quantification of \({\hbox {CO}_{2}}\) leakage at sites of GCS with little or no information on the sealing properties of the caprock. The implemented analysis shows that, for the considered site, \({\hbox {CO}_{2}}\) leakage may not be negligible even for relatively low (\(\sim \) 1%) probabilities of finding permeable inclusions in the caprock and highlights the importance of being able to characterize caprock sealing properties over large areas.     

Asbestos and other fibrous minerals contained in the serpentinites of the Gimigliano-Mount Reventino Unit (Calabria,S-Italy)

Serpentinites are metamorphic rocks with good technological properties and valuable ornamental characteristics, which have been exploited since ancient times. Actually, their use is limited and monitored in several countries worldwide because they can contain fibrous asbestos minerals that may be carcinogenic. Furthermore, certain types of fibrous minerals can be confused with asbestos, and must therefore be carefully investigated. We have investigated the possible presence of the asbestos and non-asbestos fibrous phases contained in serpentinitic rocks in a meta-ophiolitic sequence from the Gimigliano-Mount Reventino Unit (Southern Italy), which had not been previously assessed. The detection and quantification of asbestos and the correct distinction of the fibrous non-asbestos minerals are very important not only from a scientific point of view, but also from a legislative one. This is especially the case for the administrative agencies that have to take decisions with regards to the implementation of public and occupational health protection measures (e.g., in road yards and quarry excavations). As a consequence of this, serpentinitic rock samples have been characterized in detail through X-ray powder diffraction, scanning and transmission electron microscopy combined with energy-dispersive spectrometry, analytical electron microscopy (SEM–EDS and TEM–AEM), differential scanning calorimetry, thermogravimetry and micro-Raman spectroscopy. Two kinds of asbestos and four kinds of non-asbestos fibrous silicates have been detected in the examined samples. In order of decreasing abundance these are polygonal serpentine, chrysotile, fibrous antigorite, tremolite, gedrite and magnesiohornblende. The size, morphology, crystallinity and chemical composition of the fibres were also discussed, in the light of the possible role these properties could play in the carcinogenic effect on human health.     

Earthquakes in Switzerland and surrounding regions during 2009

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2009. During this period, 450 earthquakes and 68 quarry blasts were detected and located in the region under consideration. The three strongest events occurred about 15 km NW of Basel in southern Germany (M_L 4.2), near Wildhaus in the Toggenburg (M_L 4.0) and near Bivio in Graubünden (M_L 3.5). Although felt by the population, they were not reported to have caused any damage. With a total of 24 events with M_L ≥ 2.5, the seismic activity in the year 2009 was close to the average over the previous 34 years.