The age of the Roter Kamm impact crater,Namibia: Constraints from 40Ar-39Ar,K-Ar,Rb-Sr,fission track,and 10Be-26Al studies

Abstract The well-preserved 2.5 km diameter Roter Kamm impact crater is located in the Namib desert in Namibia. The impact has occurred in Precambrian granitic and granodioritic orthogneisses of the 1200–900 Ma old Namaqualand Metamorphic Complex which were partly covered by Gariep metasediments; the granites are invaded by quartz veins and quartz-feldspar-pegmatites. Previous geological field evidence suggested a crater age of about 5–10 Ma. In order to constrain this age, we selected a set of basement rocks (granites, granodiorites) exposed at the crater rim and studied the Rb-Sr, K-Ar, ⁴⁰Ar-³⁹Ar, and ¹⁰Be-²⁶Al isotopic systems as well as apatite fission track ages of these samples. The Rb-Sr isotopic systematics confirm the derivation of these samples from the Namaqualand basement (age about 1.29 Ga), which underwent Damaran orogenesis at about 650 Ma. No basement rocks with Rb-Sr ages younger than about 410 Ma were identified. The K-Ar ages of pseudotachylite and melt breccia samples show that these samples are dominated by incompletely degassed fragments of basement rocks, with some retaining their original metamorphic ages of about 470 Ma. The apatite fission track ages range from 20–28 Ma, which may be interpreted as an extension of the 25 Ma Burdigalian peneplanation event, or as incomplete resetting of the apatite fission tracks during the impact event. The ¹⁰Be and ²⁶Al exposure age of a quartz sample isolated from a quartz-pegmatite was found to be 150 ka; it is likely that the exposure of the sample began after material covering it had been removed by erosion 150 ka ago. Two glassy fractions extracted from a rim granite were dated by ⁴⁰Ar-³⁹Ar analysis. One sample gives practically a plateau age of 3.7 ± 0.3 Ma, while the other gives a minimum age of 3.6 Ma. The best available age estimate for the Roter Kamm crater is therefore 3.7 ± 0.3 Ma.     

Observational and model evidence of global emergence of permanent, unprecedented heat in the 20th and 21st centuries

Given the severe impacts of extreme heat on natural and human systems, we attempt to quantify the likelihood that rising greenhouse gas concentrations will result in a new, permanent heat regime in which the coolest warm-season of the 21(st) century is hotter than the hottest warm-season of the late 20(th) century. Our analyses of global climate model experiments and observational data reveal that many areas of the globe are likely to permanently move into such a climate space over the next four decades, should greenhouse gas concentrations continue to increase. In contrast to the common perception that high-latitude areas face the most accelerated response to global warming, our results demonstrate that in fact tropical areas exhibit the most immediate and robust emergence of unprecedented heat, with many tropical areas exhibiting a 50% likelihood of permanently moving into a novel seasonal heat regime in the next two decades. We also find that global climate models are able to capture the observed intensification of seasonal hot conditions, increasing confidence in the projection of imminent, permanent emergence of unprecedented heat.     

Identification of geomorphic process units in Kärkevagge, northern Sweden, by remote sensing and digital terrain analysis

Sediment transport processes in the Kärkevagge are investigated concerning their spatial and temporal characteristics due to long–term monitoring. Within this study remote sensing techniques and GIS modelling in connection with geomorphic mapping are applied for identification and characterization of geomorphic process units. Relationships between geomorphometric parameters and slope processes like solifluction, talus creep and rockfall have been analysed. Multitemporal Landsat–TM5 scenes are used as source for landcover characteristics (Normalized Difference Vegetation Index) after preprocessing involving orthorectification and topographic normalization in order to remove possible terrain–induced effects. Additionally, a digital elevation model with a resolution of 20 m for the Kärkevagge catchment is developed and parameters like slope gradient, slope aspect and profile curvature are extracted as input for the analysis of the sediment transport system. The combination of landcover information, geomorphometrical and topological features allows the definition of areas for single process activities. They show specific sediment displacement characteristics depending on material conditions, topological and geometrical features. Geomorphic process units, which show a homogenous composition, are extracted from these available layers.     

Paleoweathering features in the Sergi Formation (Jurassic-Cretaceous), northeastern Brazil,and implications for hydrocarbon exploration

Paleoweathering in the Sergi Formation has been classified and analyzed to ascertain its origin and relationship with stratigraphic evolution. The Sergi Formation belongs to the pre-rift sequence of the Recôncavo Basin (northeastern Brazil) and comprises a complex association of eolian and fluvial sandstones and lacustrine mudstones. This formation can be subdivided into three depositional sequences bounded by regional unconformities. Four paleoweathering types, each one related to a distinct origin, have been described in the Sergi Formation: (1) textural mottling, which is distinguished by alternating rock colors as a result of the iron oxide mobilization within mineral phases that evolved under alternating oxidation (yellowish, brownish and reddish shades) and reduction (grayish or greenish hues) conditions; (2) non-textural mottling, which displays a discoloration pattern that is independent of the original rock texture; (3) carbonate concentrations, usually related to carbonate nodule formation, which display a massive internal structure that reveals their origin through continuous growth or crystallization; and (4) banded carbonates (silicified), associated with the beginning of regular surface formation due to the chemical precipitation of carbonates within lacustrine environments. Both mottling color motifs and carbonate accumulation usually represent groundwater oscillation rather than pedogenesis. Only carbonate intraclasts and banded carbonate (silicified) have their origin ascribed to pedogenesis sensu stricto, although the carbonate intraclasts do not represent soil deposits in situ, but calcretes eroded from areas close to channels, and the banded carbonates (silicified) have strong diagenetic modifications. Therefore, it is reasonable to assume that fluvial and meteoric water have controlled paleoweathering evolution as well as deposition, yet both aspects are ruled by the same mechanisms (relief, sedimentation rate and, above all, climate).     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Ozone production due to emissions from vegetation burning

Ozone has been observed in elevated concentrations by satellites over areas previously believed to be background. There is meteorological evidence, that these ozone plumes found over the Atlantic Ocean originate from vegetation fires on the African continent.In a previous study (DECAFE-88), we have investigated ozone and assumed precursor compounds over African tropical forest regions. Our measurements revealed large photosmog layers at altitudes from 1.5 to 4 km. Both chemical and meteorological evidence point to savanna fires up to several thousand km upwind as sources.Here we describe ozone mixing ratios observed over western Africa and compare ozone production ratios from different field measurement campaigns related to vegetation burning. We find that air masses containing photosmog ingredients require several days to develop their oxidation potential, similar to what is known from air polluted by emissions from fossil fuel burning. Finally, we estimate the global ozone production due to vegetation fires and conclude that this source is comparable in strength to the stratospheric input.     

Transient twenty-first century changes in daily-scale temperature extremes in the United States

A key question for climate mitigation and adaptation decisions is how quickly significant changes in temperature extremes will emerge as greenhouse gas concentrations increase, and whether that emergence will be uniform between hot and cold extremes and across different geographic areas. We use a high-resolution, multi-member ensemble climate model experiment over the United States (U.S.) to investigate the transient response of the annual frequency, duration and magnitude of 8 daily-scale extreme temperature indices during the twenty-first century of the A1B emissions scenario. We evaluate the time of emergence of a permanent exceedance (PE) above the colder part of the historical (1980–2009) extremes distribution, and the time of emergence of a new norm (NN) centered on the historical maxima (for hot extremes) or minima (for cold extremes). We find that during the twenty-first century, hot extremes permanently exceed the historical distribution’s colder half over large areas of the U.S., and that the hot extremes distribution also becomes centered on or above the historical distribution’s maxima. The changes are particularly robust for the exceedance of the annual 95th percentile of daily maximum temperature over the West and the Northeast (with the earliest emergence of a PE by 2030 and of a NN by 2040), for warm days over the Southwest (with the earliest emergence of a PE by 2020 and of a NN by 2030), and tropical nights over the eastern U.S. (with the earliest emergence of a PE by 2020 and of a NN by 2030). Conversely, no widespread emergence of a PE or a NN is found for most cold extremes. Exceptions include frost day frequency (with a widespread emergence of a PE below the historical median frequency by 2030 and of a NN by 2040 over the western U.S.), and cold night frequency (with an emergence of a PE below the historical median frequency by 2040 and of a NN by 2060 in virtually the entire U.S.). Our analysis implies a transition over the next half century to a climate of recently unprecedented heat stress in many parts of the U.S., along with cold extremes that, although less frequent, remain at times as long and as severe as are found in the current climate.     

Atmospheric Circulation Changes in Response to an Observed Stratospheric Zonal Ozone Anomaly

Abstract

In a sensitivity study, the influence of an observed stratospheric zonal ozone anomaly on the atmospheric circulation was investigated using the Fifth Generation European Centre Hamburg Model (ECHAM5) which is a general circulation model. The model was run from 1960 to 1999 (40 years) with a mean seasonal cycle of zonally symmetric ozone. In order to isolate the induced dynamical influence of the observed zonally asymmetric part of the three-dimensional stratospheric ozone, a second run was performed for the boreal extratropics using prescribed monthly means from the 40-year reanalysis dataset from the European Centre for Medium-range Weather Forecasts (ERA-40). The main findings are the interdecadal westward shift of the polar vortex at about 65°N and a significant increase in the number of stratospheric sudden warmings during the 1980–99 period. Under the action of zonally asymmetric ozone a decrease in the Arctic Oscillation was identified between the mid-1980s and the mid-1990s. The lag correlation between the mean Arctic Oscillation at the surface and the daily stratospheric northern annular mode increased in mid-winter. Furthermore, we examined the influence of the stratospheric zonal ozone anomaly on Rossby wave breaking in the upper troposphere and found a significant westward shift of poleward Rossby wave breaking events over western Europe in the winter. By this we show that the stratospheric zonal ozone anomaly has a strong influence on the tropospheric circulation as a result of enhanced dynamical coupling processes.     

Hypolimnetic density currents traced by sulphur hexafluoride (SF6)

The artificial tracer sulphur hexafluoride (SF₆) has been used to study the density-driven deep water exchange between two sill-separated basins of Lake Lucerne, Gersauersee and Urnersee. The sources of the density gradients between the two basins are (1) salinity differences between the major inlets due to the different geology of their drainage areas, and (2) temperature differences due to spatial variation of wind forcing. Wind speeds are generally larger in Urnersee, especially in spring during the so-called Föhn events, when winds blow from the south. In contrast, Gersauersee is protected form these winds. In spring 1989, a total of 630 g of SF₆ was released at 80 to 120 m depth in the small Treib Basin located between Urnersee and Gersauersee. During about 100 days the distribution of SF₆ in the lake was determined by gaschromatography. Two models are used to quantify the exchange flow, (1) a one-box mass balance model for SF₆ in the deep part of Treib Basin, and (2) a one-dimensional diffusion/advection model describing the temporal and vertical temperature variation in Urnersee. According to the first model, the flow into the deep hypolimnion of Urnersee, decreases from 21·10⁶ m³·d^?1 at the end of March to about 8·10⁶ m³·d^?1 in late April. The second model yields similar flow rates. The decrease of the flow rate during spring, confirmed by both approaches, is consistent (1) with the decreasing strength of the density gradient above the sill during spring and early summer, and (2) with hydrographic information collected in Lake Lucerne during other years.     

Field Signatures of the SE-Asian Mega-Tsunami along the West Coast of Thailand Compared to Holocene Paleo-Tsunami from the Atlantic Region

The Andaman-Sumatra Tsunami of Dec. 26, 2004, was by far the largest tsunami catastrophe in human history. An earthquake of 9 to 9.3 on the Richter scale, the extension of waves over more than 5000 km of ocean and run-ups up to 35 m are its key features. These characteristics suggest significant changes in coastal morphology and high sediment transport rates. A field survey along the west coast of Thailand (Phuket Island, Khao Lak region including some Similan Islands, Nang Pha mangrove areas and Phi Phi Don Islands) seven to nine weeks after the tsunami, however, discovered only small changes in coastal morphology and a limited amount of dislocated sediments, restricted to the lower meters of the tsunami waves. This is in striking contrast to many paleo-tsunami's events of the Atlantic region. Explanations for this discrepancy are sought in: a. Mechanics of the earthquake. A rather slow shock impulse on the water masses over the very long earthquake zone, b. Shallow water in the earthquake zone, and c. Bathymetry of the foreshore zone at the impacted sites. Shallow water west of Thailand has diminished wave energy significantly. The differences in geomorphological and sedimentological signatures of this tsunami compared with many paleo-tsunami worldwide makes it unsuitable to be used as a model for old and future tsunami imprints by an event of this extreme energy and extension.