Petrographical and geochemical signatures of Jurassic rocks of Chari Formation,Western India: implications for provenance and tectonic setting

The sandstones of the Ridge and Athleta members of Chari Formation (Callovian-Oxfordian) exposed at Jara have been analyzed for their petrographical and geochemical studies. Texturally, these sandstones are medium to coarse grained, poorly to well sorted, sub-angular to sub-rounded, and show low to medium sphericity. These sandstones were derived from a mixed provenance including granites, granite-gneisses, low and high-grade metamorphic, and some basic rocks of Aravalli range and Nagarparkar massif. The petrofacies analysis reveals that these sandstones belong to the continental block and recycled orogen tectonic regime. The studied sandstones are modified by paleoclimate, distance of transport, and diagenesis. Mineralogically and geochemically, sandstones are classified as quartzarenite, subarkose, arkose, sublithic arenite, and wacke, respectively. The A-CN-K ternary plot and CIA, CIW, PIA, and ICV values suggest that the similar source rocks suffered moderate to high chemical weathering under a hot-humid climate in an acidic environment with higher \({\text{P}}_{{{\text{CO}}_{ 2} }}\). Generally good to strong correlations between Al₂O₃ and other oxides in these sediments indicate clay mineral control. The K₂O/Na₂O versus SiO₂ diagram indicates that the studied samples occupy passive margin fields but the SiO₂/Al₂O₃ versus K₂O/Na₂O plot suggests that the Athleta Sandstone and Ridge Sandstone fall within the passive margin field, while Ridge Shale falls within the active continental margin field.     

Provenance,tectonic setting,source weathering and palaeoenvironmental implications of Middle-Upper Jurassic rocks of Ler dome,Kachchh, western India: Inferences from petrography and geochemistry

The Middle-Upper Jurassic sandstones and shales of Ler dome (Chari and Katrol Formations), Kachchh, western India, have been analyzed for modal, bulk mineralogy and geochemistry to deduce their provenance, tectonic setting, source area weathering and palaeoenvironmental conditions. The detrital modes of Ler dome sandstones indicate that they were emanated from recycled orogen (uplifted shoulders of rift) and stable cratonic source in passive margin setting. Rapid deposition of sediments from a granitic source area can be predicted from feldspar abundance. A highly mature heavy mineral assemblage characterized in the form of high Zircon-Tourmaline-Rutile (ZTR) index also endorses these findings. The X-ray diffraction patterns (XRD) and scanning electron microscope (SEM) data show the presence of clay minerals depicting moderate to extensive chemical weathering in an oxidizing environment with periodic cycles of transgression and regression. The chemical index of weathering, chemical index of alteration and plagioclase index of alteration suggest moderate to high and low to moderate weathering conditions for sandstone and shales, respectively, that took place in low to moderate relief. We postulate that Ler dome sediments are derivative of the eroded and weathered parts of the Aravalli craton located on east and northeast of the basin and the Nagarparkar Massif placed to the north and northwest.     

2D and 3D rockfall hazard analysis and protection measures for Saptashrungi Gad Temple,Vani, Nashik,Maharashtra – A case study

The Saptashrungi gad temple (SGT) situated on basaltic hills belongs to Deccan volcanic of Upper Cretaceous to Lower Eocene, is one among the 51 Shakti Peeths and most holy place for pilgrims. Rockfall is a major problem in the past and causing danger to the lives of the villagers settled at the toe of the SGT hill as well as the pilgrims who perform parikrama along the tracks. On the evening of 16 April 2011, an old woman died due to rockfall at SGT hill when she was performing parikrama, moreover, two persons got injured during the deliverance process of this old woman from the continuous rockfall activity. The problem of rockfall could be linked to rainfall, jointing, weathering, man-made or the compounding of all. In this research, the rockfall hazard analysis at SGT hill is assessed using both 2D and 3D rockfall programs along the two parikrama paths: Parikrama Path 1 (or the Badi Parikrama Path ‘BPP’), and Parikrama Path 2 (or the Chhoti Parikrama Path ‘CPP’). Also, the study area of the SGT hill has been divided into eight zones (Zone#01 to Zone#08), based on field observations, orientations of joint sets and hill slope faces and eighteen topographic profiles (AA' to RR') have been taken from these eight zones for rockfall analysis. A detailed topographic survey along with field investigation has been carried out along the temple for ascertaining the nature of rock, discontinuity orientations, and slope geometry. DEM has been generated using topographic profile in ArcGIS to facilitate the 3D rockfall analysis. Maximum rock block sizes are taken into the analysis and run-out distance, bounce height, kinetic energy and velocity of the basaltic blocks are evaluated separately. Based on the analyzed data, the rockfall hazard zone map has been prepared and site having potential rockfall risks have been identified. Finally, wire/net meshing has been proposed after removal of unstable blocks as a stabilization and protection measures.It is worth mentioning here that for the first time rockfall hazard assessment was made in such detail for a site. Suggestions made are implemented by the State Government for the protection of the temple as well as the life of pilgrims performing the parikrama from the rockfall.     

Evaluation of magma mixing in the subvolcanic rocks of Ghansura Felsic Dome of Chotanagpur Granite Gneiss Complex,eastern India

Mineralogy and Petrology - The subvolcanic rocks exposed in the Ghansura Felsic Dome (GFD) of the Bathani volcano-sedimentary sequence at the northern fringe of the Rajgir fold belt in the...     

Hyperspectral satellite data analysis for pure pixels extraction and evaluation of advanced classifier algorithms for LULC classification

The study was carried out for Indian capital city Delhi using Hyperion sensor onboard EO-1 satellite of NASA. After MODTRAN-4 based atmospheric correction, MNF, PPI and n-D visualizer were applied and endmembers of 11 LCLU classes were derived which were employed in classification of LULC. To incur better classification accuracy, a comparative study was also carried out to evaluate the potential of three classifier algorithms namely Random Forest (RF), Support Vector Machines (SVM) and Spectral Angle Mapper (SAM). The results of this study reemphasize the utility of satellite borne hyperspectral data to extract endmembers and also to delineate the potential of random forest as expert classifier to assess land cover with higher classification accuracy that outperformed the SVM by 19% and SAM by 27% in overall accuracy. This research work contributes positively to the issue of land cover classification through exploration of hyperspectral endmembers. The comparison of classification algorithms’ performance is valuable for decision makers to choose better classifier for more accurate information extraction.     

Erosion potential assessment of watersheds through GIS<Emphasis Type="Bold">-</Emphasis>based hypsometric analysis: a case study of Kurram Tangi Dam

Sediment discharge due to soil and rock erosion within the watersheds is the major cause of siltation in water reservoirs. Siltation in reservoirs reduces the capacity for power production, irrigation water supply, and other domestic purposes. Hypsometric analysis has widely been used to identifying the geomorphic development stages (stabilized, equilibrium, and un-stable) to assess the erosion proneness of watersheds. In this study, watershed of Kurram Tangi Dam and its four sub-watersheds (SWs) were considered to determine their sediment discharge capacity through hypsometric analysis. The boundaries of watershed and sub-watersheds were delineated from Digital Elevation Model (DEM). The hypsometric parameters i.e., hypsometric integral (HI) and curves were generated using Geographic Information System (GIS) techniques. The HI values of SW-1 (0.41) and SW-2 (0.36) indicated that these two SWs were relatively more prone to erosion and contributed higher sediment discharge in Dam siltation. The results were validated through sampling the main drainage channel (Kurram River) to determine the sediment concentration at 12 sites during summer, winter, and spring seasons. Comparison of HI and sediment concentration of SWs presented high correlation (R²?=?0.87). The results emphasized the effective watershed management, extensive afforestation, and construction of silt-control structures at appropriate locations in sub-watersheds. This will ultimately maintain the water and power generation capacity as well as extending the life span of the Dam.     

Investigating the removal of ethylbenzene from aqueous solutions using modified graphene oxide: application of response surface methodology

This research focused on the application of response surface methodology (RSM) for the removal of ethylbenzene by the graphene oxide grafted with polymethyl vinyl ketone and aniline (GO-MVK-ANI) from wastewater. The adsorbent was prepared through polymerization of graphene oxide with methyl vinyl ketone using ammonium persulfate initiator and further modification by aniline. The synthesized material was characterized via Fourier transform infrared resonance spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy and Brunauer–Emmett–Teller analysis. RSM was used to minimize the number of experiments and investigate the effect of three selected parameters (contact time, initial pH and adsorbent dose) on the removal efficiency of ethylbenzene. Additionally, the affecting parameters were optimized based on the selected target (ethylbenzene removal efficiency). The results show that 73% ethylbenzene could be adsorbed with initial ethylbenzene concentration of 20 mg/l under the optimum conditions (the contact time of 11 min, pH of 5.64 and adsorbent dose of 3.75 g/l). In this paper, high R ²-value (97.18%) for ethylbenzene removal and a good agreement with adjusted R ²-value (94.65%) indicated that the model was successful and the results demonstrated a reasonable proportion of the experimental and the predicted results.     

Correction: Impact of excessive groundwater pumping on rejuvenation processes in the Bandung basin (Indonesia) as determined by hydrogeochemistry and modeling

In the Bandung basin, Indonesia, excessive groundwater pumping caused by rapid increases in industrialization and population growth has caused subsurface environmental problems, such as excessive groundwater drawdown and land subsidence. In this study, multiple hydrogeochemical techniques and numerical modeling have been applied to evaluate the recharge processes and groundwater age (rejuvenation). Although all the groundwater in the Bandung basin is recharged at the same elevation at the periphery of the basin, the water type and residence time of the shallow and deep groundwater could be clearly differentiated. However, there was significant groundwater drawdown in all the depression areas and there is evidence of groundwater mixing between the shallow and deep groundwater. The groundwater mixing was traced from the high dichlorodifluoromethane (CFC-12) concentrations in some deep groundwater samples and by estimating the rejuvenation ratio (R) in some representative observation wells. The magnitude of CFC-12 concentration, as an indicator of young groundwater, showed a good correlation with R, determined using ¹⁴C activity in samples taken between 2008 and 2012. These correlations were confirmed with the estimation of vertical downward flux from shallower to deeper aquifers using numerical modeling. Furthermore, the change in vertical flux is affected by the change in groundwater pumping. Since the 1970s, the vertical flux increased significantly and reached approximately 15% of the total pumping amount during the 2000s, as it compensated the groundwater pumping. This study clearly revealed the processes of groundwater impact caused by excessive groundwater pumping using a combination of hydrogeochemical methods and modeling.

     

Mapping rubber trees based on phenological analysis of Landsat time series data-sets

This study proposes a strategy for accurate mapping of rubber trees through the analysis of Landsat time series datasets. The phenological dynamics of rubber trees were derived from the Normalized Difference Vegetation Index (NDVI) to verify the three important phenological metrics of rubber trees; defoliation, foliation and their growing stages. A decade (2006–2015) ago, Landsat time series NDVIs were used to study the strength of relationship between rubber trees, evergreen trees and oil palm trees. Two important results that could discriminate these three types of vegetation were found; firstly, a weak relationship of NDVIs between rubber trees and evergreen trees during the defoliation period (r² = 0.1358) and secondly between rubber trees and oil palm trees during the growing period (r² = 0.2029). This analysis was verified using Support Vector Machine to map the distribution of the three types of vegetation. An accurate mapping strategy of rubber trees was successfully formulated.     

Global scale evaluation of coastal fresh groundwater resources

This paper presents a simplified approach to assess the effects of global warming on global coastal groundwater resources over the next century based on the smallest but necessary number of elements such as rainfall, temperature, hydraulic conductivity of the aquifers, and population changes regarding the consumption of groundwater. The positive aspect in this approach is that there is availability of the above elements in the majority of the planet. Methodology includes a sharp interface concept model and simplified estimation of groundwater recharge using limited climate data. The evaluation shows that the future climate changes would decrease fresh groundwater resources in Central American, South American, South African and Australian regions whereas most of the areas in Asia, except South-East Asia. Combinations of fresh groundwater loss and global population are considered to state the vulnerability of future fresh groundwater supply. Vulnerability assessment shows that South Asia, Central America, North Africa and the Sahara, South Africa and the Middle East countries are highly vulnerable whereas, Northern Europe, Western part of South America, New Zealand and Japan are less vulnerable with respect to future fresh groundwater supply. Further, this paper highlights the necessity Integrated Coastal Management (ICM) practices in these vulnerable coastal regions to ensure the sustainable development in coastal regions.