Short-Timescale Chemo-Mechanical Effects and their Influence on the Transport Properties of Fractured Rock

Anomalous changes in permeability are reported in fractures circulated by fluids undersaturated with respect to the mineral host. Under net dissolution and net removal of mineral mass, fractures may alternately gape or seal, depending on the prevailing mechanical and chemical conditions. The influence on transport properties is observed to be large, rapid, and irreversible: Permeabilities may change by two orders of magnitude in a month, and the direction of permeability change may switch spontaneously, for no apparent change in environmental forcing. These behaviors are apparent in continuous circulation experiments conducted on fractures in novaculite and limestone, intermittently imaged by X-ray CT. In novaculite, permeability reduces by two orders of magnitude as silica is net removed from the sample. Surprisingly, these changes can occur at modest temperatures (~80°C) and stresses (~3.5 MPa), where compaction progresses as temperatures are incremented. Isothermal (~20°C) circulation tests in limestone show similar compaction driven by pressure solution. Where circulation remains undersaturated in Ca, the change in permeability spontaneously switches from net reduction to net increase as a wormhole forms. The surprising magnitude and rapidity of these changes are investigated in the context of the competition between stress- and chemistry-mediated effects.     

Coral bleaching indices and thresholds for the Florida Reef Tract, Bahamas, and St. Croix, US Virgin Islands

It is well established that elevated sea temperatures cause widespread coral bleaching, yet confusion lingers as to what facet of extreme temperatures is most important. Utilizing long-term in situ datasets, we calculated nine thermal stress indices and tested their effectiveness at segregating bleaching years a posteriori for multiple reefs on the Florida Reef Tract. The indices examined represent three aspects of thermal stress: (1) short-term, acute temperature stress; (2) cumulative temperature stress; and (3) temperature variability. Maximum monthly sea surface temperature (SST) and the number of days >30.5 °C were the most significant; indicating that cumulative exposure to temperature extremes characterized bleaching years. Bleaching thresholds were warmer for Florida than the Bahamas and St. Croix, US Virgin Islands reflecting differences in seasonal maximum SST. Hind-casts showed that monthly mean SST above a local threshold explained all bleaching years in Florida, the Bahamas, and US Virgin Islands.     

Category, narrative, and value in the governance of small-scale fisheries

Since the 1970s, small-scale fisheries have had an important place in fisheries social science and in fisheries management. While there has been substantial discussion of what constitutes the category of small-scale fisheries, its considerable ambiguity is nevertheless often passed over. This paper argues that while the category of scale fisheries can be best understood in terms of scale, the underlying reason for the power of the category lies in the values of social justice and ecological sustainability that it has come to represent in response to dominant high modern narratives of change. Fisheries governance may better be served by prioritising these values rather than by making a fetish out of small-scale fisheries.     

Aeolian fetch distance and secondary airflow effects: the influence of micro‐scale variables on meso‐scale foredune development

Unsuccessful attempts to use process‐scale models to predict long‐term aeolian sediment transport patterns have long been a feature of aeolian research. It has been proposed that one approach to overcome these problems is to identify micro‐scale variables that are important at longer timescales. This paper assesses the contribution of two system variables (secondary airflow patterns and fetch distance) to medium‐term (months to years) dune development. The micro‐scale importance of these variables had been established during previous work at the site (Magilligan Strand, Northern Ireland). Three methods were employed. First, sand drift potentials were calculated using 2 years of regional wind data and a sediment transport model. Second, wind data and large trench traps (2 m length × 1 m width × 1·5 m depth) were used to assess the actual sediment transport patterns over a 2‐month period. Third, a remote‐sensing technique for the identification of fetch distance, a saltation impact sensor (Safire) and wind data were utilized to gauge, qualitatively, sediment transport patterns over a 1‐month period. Secondary airflow effects were found to play a major role in the sediment flux patterns at these timescales, with measured and predicted rates matching closely during the trench trap study. The results suggest that fetch distance is an unimportant variable at this site. Copyright © 2007 John Wiley & Sons, Ltd.     

The distribution of particulate iodine in the Atlantic Ocean

The iodine content of marine suspended matter obtained from thirteen stations in the Atlantic between 75°N and 55°S has been measured. The concentration of particulate iodine is high in the surface, up to 127 ng/kg of seawater being observed. Below the euphotic zone, it drops sharply to 1–2 ng/kg. The iodine-containing particles are probably biogenic. A simple box-model calculation shows that only 3% of the particulate iodine produced in the surface water may reach the deep sea and that the residence time of these particles in the surface water is about 0.1 year.     

Organic Geochemical and Petrographic Characteristics of the Coal Measure Source Rocks of Pinghu Formation in the Xihu Sag of the East China Sea Shelf Basin: Implications for Coal Measure Gas Potential

Coal measure source rocks, located in the Xihu Sag of the East China Sea Shelf Basin, were analyzed to define the hydrocarbon generation potential, organic geochemistry/petrology characteristics, and coal preservation conditions. The Pinghu source rocks in the Xihu Sag are mainly gas-prone accompany with condensate oil generation. The coals and shales of the Pinghu Formation are classified from "fair" to "excellent" source rocks with total organic carbon(TOC) contents ranging from 25.2% to 77.2% and 1.29% to 20.9%, respectively. The coals are richer in TOC and S1+S2 than the shales, indicating that the coals have more generation potential per unit mass. Moreover, the kerogen type of the organic matter consists of types Ⅱ-Ⅲ and Ⅲ, which the maturity Ro ranges from 0.59% to 0.83%. Petrographically, the coals and shales are dominated by vitrinite macerals(69.1%–96.8%) with minor proportions of liptinite(2.5%–17.55%) and inertinite(0.2%–6.2%). The correlation between maceral composition and S1+S2 indicates that the main contributor to the generation potential is vitrinite. Therefore, the coals and shales of the Pinghu Formation has good hydrocarbon generation potential, which provided a good foundation for coal measure gas accumulation. Furthermore, coal facies models indicates that the Pinghu coal was deposited in limno-telmatic environment under high water levels, with low tree density(mainly herbaceous) and with low-moderate nutrient supply. Fluctuating water levels and intermittent flooding during the deposition of peat resulted in the inter-layering of coal, shale and sandstone, which potentially providing favorable preservation conditions for coal measure gas.     

西准噶尔包古图成矿斑岩年代学与地球化学:岩石成因与构造、铜金成矿意义

西准噶尔包古图地区的一些小型斑岩体或脉岩与铜金矿化的关系非常密切,引起了人们的广泛关注.报道了一些斑岩的LA-ICP-MS锆石U-Pb定年结果和岩石地球化学成分资料.Ⅱ、V岩体的石英闪长斑岩中岩浆结晶锆石的定年结果分别为314.9±1.7 Ma和309.9±1.9 Ma,Ⅲ岩体的闪长玢岩中岩浆结晶锆石的定年结果为313.9±2.6 Ma,表明包古图地区的岩体形成于晚石炭世.包古图地区小岩体的岩石富Na、高Sr,贫Y和Yb,无明显的Eu异常,具有埃达克岩特征,同时有些岩石富集MgO(3.93%～4.78%),具有高的Mg#(68～74),类似高镁安山岩.结合区域地质和岩浆岩的资料,认为:(1)包古图地区的小岩体形成于晚石炭世的岛弧环境,并可能与石炭纪的洋脊俯冲有关,其中埃达克质岩为俯冲洋脊两侧的板片熔融而形成,而高镁闪长岩类为俯冲板片熔体与地幔橄榄岩相互作用的产物;(2)包古图地区的铜金矿床也很可能与洋脊俯冲有关,高氧逸度的板片熔体上升并与地幔橄榄岩相互作用,这使得地幔中的金属硫化物不稳定,释放出金属成矿物质,从而使得Cu、Au等在熔体中不断富集而形成矿床.     

Diagenesis of plant biopolymers: Decay and macromolecular preservation of Metasequoia

Analysis of modern Metasequoia leaves revealed the presence of the structural polyester cutin, guaiacyl lignin units and polysaccharides. Analysis of environmentally decayed Metasequoia leaves revealed that guaiacyl lignin units and cellulose were degraded more than vinyl phenol (the last being the primary pyrolysis product of cutin and plant cuticles) suggesting that cutin is more stable than lignin and cellulose during degradation, contrary to some previous studies. This observation is supported by electron microscopy showing changes in the cellular structure and cuticle of modern, decayed and fossil Metasequoia leaves. Metasequoia fossils from the Eocene of Republic (Washington State) showed a significant aliphatic component, but biopolymeric lignin and polysaccharides were not detected. Fossils from the Eocene of Axel Heiberg revealed the presence of lignin and an aliphatic polymer up to C₂₉ with cellulose, and fossils from the Miocene Clarkia deposit (Idaho) revealed lignin and an aliphatic polymer up to C₂₇ without any polysaccharides. Modern Metasequoia needles heated experimentally in confined conditions generated a macromolecular composition with an aliphatic polymer up to C₃₂ and additional phenolic compounds similar to those present in the fossils. Experimental heating of cutin is known to generate an aliphatic polymer with carbon chain length units <C₂₀. Thus, the n-alkyl component with chain length units >C₂₀ in the heated Metasequoia needles is a product of incorporation of longer chain plant waxes, indicated by the odd/even predominance of the >C₂₇ n-alkanes. The resistant nature of cutin compared to lignin and polysaccharides explains the presence of an n-alkyl component (<C₂₀) in fossil leaves even when polysaccharides are absent and lignin has decayed; cutin and its diagenetically altered products contribute significantly to the presence of aliphatic components in terrestrially derived sedimentary organic matter.     

Field measurements of intertidal bar evolution on a high‐energy beach system

Nearshore bars play a pivotal role in coastal behaviour, helping to protect and restore beach systems particularly in post‐storm conditions. Examination of bar behaviour under various forcing conditions is important to help understand the short‐ to medium‐term evolution of sandy beach systems. This study carried out over a nine‐week period examines, the behaviour of three intertidal bars along a high energy sandy beach system in northwest Ireland using high‐frequency topographic surveys and detailed nearshore hydrodynamic modelling. Results show that, in general, there was onshore migration for all the bars during the study period, despite the variability observed between bars, which was driven mostly by wave dominated processes. Under the prevailing conditions migration rates of up to 1.83 m day^?1 and as low as 0.07 m day^?1 were observed. During higher wave energy events the migration rates of the bars decelerated in their onshore route, however, under lower wave energy conditions, they quickly accelerated maintaining their shoreward migration direction. Tidal influence appears to be subordinate in these conditions, being restricted to moderating the localized wave energy at low tides and in maintaining runnel configurations providing accommodation space for advancing slip faces. The study highlights the intricate behavioural patterns of intertidal bar behaviour along a high energy sandy coastline and provides new insights into the relative importance of wave and tidal forcing on bar behaviour over a relatively short time period. Copyright © 2016 John Wiley & Sons, Ltd.     

A Review of Some Environmental Issues Affecting Marine Mining

This article reviews information recently available from existing marine and coastal mining for responses to environmental issues affecting marine mining at different depths. It is particularly but not exclusively concerned with those issues affecting seabed biodiversity impact and recovery. Much information has been gathered in the past 10 years from shallow mining operations for construction aggregate, diamonds, and gold, from coastal mines discharging tailings to shallow and deep water, and from experimental deep mining tests. The responses to issues identified are summarized in a series of eight tables intended to facilitate site-specific consideration. Since impacts can spread widely in the surface mixing layer SML, and can affect the biologically productive euphotic zone, the main issues considered arise from the depth of mining relative to the SML of the sea. Where mining is below the SML, the issue is whether it is environmentally better to bring the extraction products to the surface vessel for processing (and waste discharge), or to process the extraction products as much as possible on the seabed. Responses to the issues need to be sitespecific, and dependent on adequate preoperational environmental impact and recovery prediction. For deep tailings disposal from a surface vessel, there are four important environmental unknowns: (1) the possible growth of "marine snow" (bacterial flocs) utilizing the enormous quantities of fine tailings particles (hundreds or thousands of metric tons per day) as nuclei for growth, (2) the possibility that local keystone plankton and nekton species may migrate diurnally down to and beyond the depth of deep discharge and hence be subjected to tailings impact at depth, (3) the burrow-up capability of deep benthos and their ability to survive high rates of tailings deposition, and (4) the pattern and rate of dispersion of a tailings density current through the deep water column from discharge point to seabed. Actions to obtain relevant information in general and site-specifically are suggested.