The contribution of throughflow to storm runoff: An evaluation of a chemical mixing model

The contribution of throughflow to storm runoff is examined using a chemical mixing model. The results predict that throughflow is an important component of storm runoff particularly during the period of stream recession. Supporting hydrological data suggests that a major throughflow input occurs coincident with the stream discharge peak. The two sets of results therefore conflict in the predicted timing of the throughflow response.     

Orthodoxy and creativity in theories of mountain building before 1922

In the 1870s, theories of mountain building emerged from little more than speculation to inference based on a growing body of observation and documentation. This coincided with abandonment of models stressing uplift, and their replacement, in the new orthodoxy, by models in which earth contraction led to lateral compression in its outer shell. Nevertheless, perceived weaknesses in this model gave impetus to new theories, some emphasizing primary vertical movement, and others continental displacement or subcrustal flow. The rebel theories added to the understanding of earth processes in important ways, by drawing attention to the weaknesses in the prevailing orthodoxy. But, in 1922, the complete answer remained out of reach.

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Zusammenfassung Die siebziger Jahre des vorigen Jahrhunderts brachten den Anfang von wissenschaftlich fundierten Theorien der Gebirgsbildung. Diese Zeit sah auch den Übergang von Erhebungstheorien zur neuen Lehrmeinung, nach welcher Erdkontraktion zu lateralen Drucken in der Außenhülle der Erde führte. Erkannte Schwächen dieses Modells führten jedoch zu neuen Gegentheorien, von denen einige primäre Vertikalbewegungen in den Vordergrund stellten, während andere Kontinentalverschiebung oder Unterströmungen als den Motor der Gebirgsbildung sahen. Diese Gegentheorien haben den Fortschritt der Erdwissenschaften gefördert, indem sie auf Schwächen der herrschenden Lehrmeinung aufmerksam machten. Aber selbst zu Argands Zeit war ein völlig befriedigendes Modell noch gar nicht erreichbar.

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Résumé C'est dans les années 1870–1880 que commençaient à s'établir les premières théories vraiment scientifiques de l'orogenèse. C'était la décade qui marqua l'abandon des théories à base de soulèvement et le début du règne de la nouvelle orthodoxie d'après laquelle la contraction de la terre mène à la compression latérale d'une pellicule extérieure. Néansmoins, certaines faiblesses du nouveau modèle servaient d'élan à des théories rebelles dont quelques-unes soulignaient l'importance des soulèvements primaires, tandisque d'autres cherchaient le moteur de l'orogenèse dans la dérive des continents ou dans des courants dans une masse quasi-fluide subcrustale. Ces théories rebelles ont avancé la science en soulignant les faiblesses de l'orthodoxie. En fin de compte, une solution complètement satisfaisante ne paraissait pas encore pouvoir être atteinte à l'époque d'Argand.

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Concentration,vertical flux,and remineralization of particulate uranium in seawater

Concentrations and fluxes of particulate U were measured throughout the water column at several locations in the Atlantic and Pacific Oceans with in situ filtration systems and sediment traps. The results indicate that dissolved U is fixed to particles in surface seawater. Organic matter appears to be the carrier phase. Formation of particulate authigenic U below the surface waters could not be detected. Authigenic U is remineralized within the bathypelagic layers at the open ocean sites studied. In the Panama Basin, an upwelling area with high biological productivity, remineralization of authigenic U in the deep water column was not observed. The rate of remineralization of authigenic U in the deep sea is insufficient to produce a measurable concentration gradient between surface and deep waters within the mixing time of the oceans. Formation of authigenic U in the water column in areas such as the Panama Basin is not a significant sink for U on an ocean wide basis.     

Characteristics of air flow above and within soybean canopies

Air flow was observed above and within canopies of a number of kinds of soybeans. The Clark cultivar and two isolines of the Harosoy cultivar were studied in 1979 and 1980, respectively. Wind speed above the canopy was measured with cup anemometers. Heated thermistor anemometers were used to measure air flow within the canopy. Above-canopy air flow was characterized in terms of the zero-plane displacement (d), roughness parameter (z _o) and drag coefficient (C _d). d and z _o were dependent on canopy height but were independent of friction velocity in the range 0.55 to 0.75 m s^?1 · C _d for the various canopies ranged from 0.027 to 0.035. Greater C _d values were measured over an erectophile canopy than over a planophile canopy. C _d was not measurably affected by differences in leaf pubescence. Within-canopy wind profiles were measured at two locations: within and between rows. The wind profile was characterized by a region of great wind shear in the upper canopy and by a region of relatively weak wind shear in the middle canopy. Considerable spatial variability in wind speed was evident, however. This result has significant implications for canopy flow modeling efforts aimed at evaluating transport in the canopy. In the lower canopy, wind speed within a row increased with depth whereas wind speed between two rows decreased with depth. The wind speeds at the two locations tended to converge to a common value at a height near 0.10 m. The attenuation of within-canopy air flow was stronger in canopies with greater foliage density. Canopy flow attenuation seemed to decrease with increasing wind speed, suggesting that high winds distorted the shape of the canopy in such a manner that the penetration of wind into the canopy increased.     

Autoxidation of N(III), S(IV), and other Species in Frozen Solution – A Possible Pathway for Enhanced Chemical Transformation in Freezing Systems

The chemistry of glycolaldehyde (hydroxyacetaldehyde) relevant to the troposphere has been investigated using UV absorption spectrometry and FTIR absorption spectrometry in an environmental chamber. Quantitative UV absorption spectra have been obtained for the first time. The UV spectrum peaks at 277 nm with a maximum cross section of (5.5± 0.7)×10^–20 cm² molecule^–1. Studies of the ultraviolet photolysis of glycolaldehyde ( = 285 ± 25 nm) indicated that the overall quantum yield is > 0.5 in one bar of air, with the major products being CH₂OH and HCO radicals. Rate coefficients for the reactions of Cl atoms and OH radicals with glycolaldehyde have been determined to be (7.6± 1.5)×10^–11 and (1.1± 0.3)×10^–11 cm³ molecule^–1 s^–1, respectively, in good agreement with the only previous study. The lifetime of glycolaldehyde in the atmosphere is about 1.0 day for reaction with OH, and > 2.5 days for photolysis, although both wet and dry deposition should also be considered in future modeling studies.     

Detection Time for Plausible Changes in Annual Precipitation, Evapotranspiration, and Streamflow in Three Mississippi River Sub-Basins

We use diagnostic studies of off-line variable infiltration capacity (VIC) model simulations of terrestrial water budgets and 21st-century climate change simulations using the parallel climate model (PCM) to estimate the time required to detect predicted changes in annual precipitation (P), evapotranspiration (E), and discharge (Q) in three sub-basins of the Mississippi River Basin. Time series lengths on the order of 50–350 years are required to detect plausible P, E, and Q trends in the Missouri, Ohio, and Upper Mississippi River basins. Approximately 80–160, 50, and 140–350 years, respectively, are needed to detect the predicted P, E, and Q trends with a high degree of statistical confidence. These detection time estimates are based on conservative statistical criteria (α = 0.05 and β = 0.10) associated with low probability of both detecting a trend when it is not occurring (Type I error) and not detecting a trend when it is occurring (Type II error). The long detection times suggest that global-warming-induced changes in annual basin-wide hydro-climatic variables that may already be occurring in the three basins probably cannot yet be detected at this level of confidence. Furthermore, changes for some variables that may occur within the 21st century might not be detectable for many decades or until the following century – this may or may not be the case for individual recording station data. The long detection times for streamflow result from comparatively low signal-to-noise ratios in the annual time series. Finally, initial estimates suggest that faster detection of acceleration in the hydrological cycle may be possible using seasonal time series of appropriate hydro-climatic variables, rather than annual time series.