A universal thermal equation-of-state

Evidence has steadily accumulated to show that at high temperatures (above the Debye temperature, θ) the thermal pressure, P_TH, of solids, is linear with T to a close approximation. This empirical finding yields a simple relationship between P, V, and T quite useful for the computation of the equation-of-state (EOS). For geophysical applications, the empirical data is, so far, limited to a few minerals, all of which are important to our geophysical models of the Earth. The same results have been found for a variety of types of solids, including alkali metals, noble gas solids, alkali halides and metals in addition to minerals. It is argued that the linearity between P_TH and T is a general high-temperature property of solids. This includes minerals. Thus it is proposed that there exists a common thermal EOS which transcends the chemical bonding type and crystallographic class.     

Kolmogorov constants for CO2, wind velocity,air temperature,and humidity fluctuations over a crop surface

The Kolmogorov constants for CO₂, wind velocity, air temperature, and humidity fluctuations were evaluated from measurements made over soybean and grain sorghum fields and found to be 0.78 ± 0.11, 0.49 ± 0.08, 0.70 ± 0.15, and 0.99 ± 0.16, respectively. These results are consistent with recent observations reported in the literature.Published as Paper No. 7255, Journal Series, Nebraska Agricultural Experiment Station. The work reported here was conducted under Regional Research Project 11-33 and Nebraska Agricultural Experiment Station Project 27-003.Associate Professor and Post Doctoral Research Associate, respectively, Center for Agricultural Meteorology and Climatology, Institute of Agriculture and Natural Resources, University of Nebraska, Lincoln, NE, U.S.A., 68583-0728.     

Geochemical constraints on magma processes in a peralkaline system: The Paisano volcano,west Texas

Major and trace element data for a sequence of peralkaline silicic lavas and pyroclastic flows, exposed in the caldera wall of the Paisano volcano, west Texas, document systematic fractional crystallization during magmatic evolution and an open system, magma mixing event in the upper parts of the sequence. Stratigraphically lowest flows are comendite and comenditic quartz trachyte lavas and ash flow tufts. Overlying these units is a trachyte with compositional, textural and mineralogical features indicating that it is the product of magma-mixing; similar flows occur in other parts of the volcano at the same stratigraphic level. This composite trachyte is considered to be a mixture of mugearitic or mafic trachytic magma, derived from a similar source region which yielded the earlier caldera wall flows. Trace element concentrations of the post-trachyte comenditic quartz trachyte lavas suggest they were erupted from a chamber whose magma was diluted by an influx of mugearitic or mafic trachytic magma during a magma mixing event.Rayleigh fractionation calculations show that the comendites and comenditic quartz trachytes can be derived from a parental mugearite magma by 88% to 93% fractionation of dominantly plagioclase and alkali feldspar, with lesser amounts of clinopyroxene, magnetite and apatite. Zircon was not a significant fractionating phase. The composition, mineralogy and depth of the source region(s) which generated these magmas cannot be constrained from the present data set.     

Forecasting errors: The importance of the decision-making context

This article demonstrates the importance of context on forecast errors. It de J.scribes the development of an unrealistic transportation planning forecast for Denver, Colorado, noting its influence on air quality planning for Denver. The importance of two contextual features, procedural rationality and conflict of interest, to the introduction of error is discussed. The case described implies that different decision-making contexts define different rules of rationality, and substantive rationality may not fit the rules. The type of context and not necessarily a code of ethics will determine this.     

Intra-field variability of scalar flux densities across a transition between a desert and an irrigated potato field

This paper reports on measurements of sensible and latent heat and CO₂ fluxes made over an irrigated potato field, growing next to a patch of desert. The study was conducted using two eddy correlation systems. One measurement system was located within the equilibrium boundary layer 800 m downwind from the edge of the potato field. The other measurement system was mobile and was placed at various downwind positions to probe the horizontal transition of vertical scalar fluxes. Latent (LE) and sensible (H) heat fluxes, measured at 4 m above the surface, exhibited marked variations with downwind distance over the field. Only after the fetch to height ratio exceeded 75 to 1 didLE andH become invariant with downwind distance. When latent and sensible heat fluxes were measured upwind of this threshold, significant advection of humidity-deficit occurred, causing a vertical flux divergence ofH andLE.The measured fluxes of momentum, heat, and moisture were compared with predictions from a second-order closure two-dimensional atmospheric boundary layer model. There is good agreement between measurements and model predictions. A soil-plant-atmosphere model was used to examine nonlinear feedbacks between humidity-deficits, stomatal conductance and evaporation. Data interpretation with this model revealed that the advection of hot dry air did not enhance surface evaporation rates near the upwind edge of the potato field, because of negative feedbacks among stomatal conductance, humidity-deficits, andLE. This finding is consistent with results from several recent studies.     

Short polarity intervals within the Matuyama: transitional field records from hydraulic piston cored sediments from the North Atlantic

Detailed sampling of two short magnetozones within the Matuyama Chronozone recorded at DSDP Site 609 (49.86°N, 335.77°E) confirms that one, the Cobb Mountain Subchronozone (1.12 Ma), is a very short, full normal polarity interval and that the other, the older interval, is a record of a geomagnetic excursion which occurred at approximately 1.55 Ma. The Cobb Mountain Subchron lasted approximately 25,000 years, one third the duration of the Jaramillo Subchron. The normal polarity interval is bounded by two transition zones which document an antisymmetry in the sequence of directions in the reverse to normal and normal to reverse polarity transitions. We interpret the antisymmetry as reflecting a dependence upon the sense of the reversal, without significant changes in the relative contributions of non-dipole terms. The polarity interval recorded at 1.55 Ma lasted only 8,800 years with what may be regarded as full polarity directions observed across only 3 cm of stratigraphic section. This feature is interpreted as an excursion of the geomagnetic field and appears to be correlative with the Gilsa Subchron. Similarities between the transition bounding these two magnetozones suggest that these features occur as the result of the same process or triggering mechanisms in the earth's outer core.     

Suction-controlled triaxial testing: Laboratory procedures in relation to resistance envelope methods

In certain tropical slopes it appears possible that soil suction may play a significant role in maintaining stability. This communication outlines a laboratory suction-controlled triaxial test that can be undertaken to validate the threshold suction predicted by resistance envelope methods. It is shown that for two sites examined in St. Lucia, West Indies, the results from such a test confirm results obtained by use of resistance envelopes.