The role of pH and pulp redox potential (EH) to control the flotation and depression of arsenopyrite has been investigated through studies on microflotation of arsenopyrite crystals and batch flotation of an arsenopyritic ore using isopropyl xanthate as collector. The transition between flotation and depression of arsenopyrite is established by the reversible potential of the xanthate/dixanthogen couple. Adsorption of arsenate ions on ferric hydroxide has been studied through electrokinetics to delineate mechanisms involved in the depression of arsenopyrite using oxidants. Chemical binding between arsenate species and ferric hydroxide sites on arsenopyrite is suggested as the mechanism responsible for depression of arsenopyrite. EH conditions are given for the flotation and depression of arsenopyite at various pH values for the arsenopyritic ore. 相似文献
The goal of this study was to develop an innovative chloroethene biodegradation module based on biological, thermodynamical and mechanistic concepts. The biodegradation scheme was based on the postulate that in each part of an aquifer only one degradation mechanism is dominant: the one involving the most energetic electron acceptor. Thus, the selection of the active degradation mechanism was a function of the concentration of different electron acceptors. Modified Monod-type kinetics was used in order to take into account the possible influence of some compounds on the biodegradation of a given organic compound. The numerical model developed was applied to a simple test case, whose results are presented here. To cite this article: F. Nex et al., C. R. Geoscience 338 (2006).相似文献
Palynological, sedimentological and stable isotopic analyses of carbonates and organic matter performed on the El Portalet sequence (1802 m a.s.l., 42°48′00?N, 0°23′52?W) reflect the paleoclimatic evolution and vegetation history in the central-western Spanish Pyrenees over the last 30,000 yr, and provide a high-resolution record for the late glacial period. Our results confirm previous observations that deglaciation occurred earlier in the Pyrenees than in northern European and Alpine sites and point to a glacial readvance from 22,500 to 18,000 cal yr BP, coinciding with the global last glacial maximum. The patterns shown by the new, high-resolution pollen data from this continental sequence, chronologically constrained by 13 AMS 14C dates, seem to correlate with the rapid climate changes recorded in Greenland ice cores during the last glacial-interglacial transition. Abrupt events observed in northern latitudes (Heinrich events 3 to 1, Oldest and Older Dryas stades, Intra-Allerød Cold Period, and 8200 cal yr BP event) were also identified for the first time in a lacustrine sequence from the central-western Pyrenees as cold and arid periods. The coherent response of the vegetation and the lake system to abrupt climate changes implies an efficient translation of climate variability from the North Atlantic to mid latitudes. 相似文献
The Walter‐Outalpa shear zone in the southern Curnamona Province of NE South Australia is an example of a shear zone that has undergone intensely focused fluid flow and alteration at mid‐crustal depths. Results from this study have demonstrated that the intense deformation and ductile shear zone reactivation, at amphibolite facies conditions of 534 ± 20 °C and 500 ± 82 MPa, that overprint the Proterozoic Willyama Supergroup occurred during the Delamerian Orogeny (c. 500 Ma) (EPMA monazite ages of 501 ± 16 and 491 ± 19 Ma). This is in contrast to the general belief that the majority of basement deformation and alteration in the southern Curnamona Province occurred during the waning stages of the Olarian Orogeny (c. 1610–1580 Ma). These shear zones contain hydrous mineral assemblages that cut wall rocks that have experienced amphibolite facies metamorphism during the Olarian Orogeny. The shear zone rock volumes have much lower δ18O values (as low as 1‰) than their unsheared counterparts (7–9‰), and calculated fluid δ18O values (5–8‰) consistent with a surface‐derived fluid source. Hydrous minerals show a decrease in δD(H2O) from ?14 to ?22‰, for minerals outside the shear zones, to ?28 to ?40‰, for minerals within the shear zones consistent with a contribution from a meteoric source. It is unclear how near‐surface fluids initially under hydrostatic pressure penetrate into the middle crust where fluid pressures approach lithostatic, and where fluid flow is expected to be dominantly upward because of pressure gradients. We propose a mechanism whereby faulting during basin formation associated with the Adelaidean Rift Complex (c. 700 Ma) created broad hydrous zones containing mineral assemblages in equilibrium with surface waters. These panels of fault rock were subsequently buried to depths where the onset of metamorphism begins to dehydrate the fault rock volumes evolving a low δ18O fluid that is channelled through shear zones related to Delamerian Orogenic activity. 相似文献
A series of small scale tests, simulating multi-hole blasts have been performed to establish the effect of delays on blast fragmentation. The blasts were performed in high quality granodiorite blocks, which were cut from stone prepared by dimensional stone quarry operations. The pattern used was equilateral triangular, with a distance of 10.2 cm between boreholes, which had a diameter of 11 mm, were loaded with detonating cord and the coupling medium was water. The delays used were achieved using different lengths of detonating cord for the cases of delays between 0 and 100 μs between holes and a sequential blasting machine firing seismic detonators for larger delays up to 4 ms. All fragments were collected and screened. The experiments showed that the worst fragmentation was achieved with simultaneous initiation of all charges. Fragmentation improved with the delay time between holes up to 1 ms between holes. If the experiments are scaled up, the results show that in granodiorite, fragmentation optimization requires delays of few milliseconds per metre of burden. The findings, agree with previously published work, involving larger scale experiments and other rock types. 相似文献
In this paper, a multi-method approach for the assessment of the stability of natural slopes and landslide hazard mapping applied to the Dakar coastal region is presented. This approach is based on the effective combination of geotechnical field and laboratory works, of GIS, and of mechanical (deterministic and numerical) stability analysis. By using this approach, valuable results were gained regarding instability factors, landslide kinematics, simulation of slope failure and coastal erosion. This led to a thorough assessment and strong reduction in the subjectivity of the slope stability and hazard assessment and to the development of an objective landslide danger map of the SW coast of Dakar. Analysis of the results shows that the slides were influenced by the geotechnical properties of the soil, the weathering, the hydrogeological situation, and the erosion by waves. The landslide susceptibility assessment based on this methodological approach has allowed for an appropriate and adequate consideration of the multiple factors affecting the stability and the optimization of planning and investment for land development in the city. 相似文献
Investigation of deposits for traditional extraction activities (metals and coal) has generally been based on determining grade, or content, of the required material. In order to apply the grade concept to an ornamental rock such as slate, it is first necessary to define the variables that determine both the geotechnical recovery rate for the rock mass — which conditions the size of the extracted blocks – and the aesthetic features of the slate — which define the quality of the slabs as potential roofing material.
For this research, geotechnical and aesthetic data for a slate deposit were collected from 16 continuous core borehole samples. A fuzzy expert system was then developed using this data, defining the rock mass recovery rate and slab quality in accordance with the criteria of a slate expert, producing as a final output a zonation of the deposit in terms of top quality slate, medium quality slate or waste.
A mathematical model based on fuzzy logic was chosen due to the fact that the boundaries between different quality groups in a deposit are not clearly distinguished. Moreover, quality also depends on a company's infrastructures for transformation of the blocks, and also on its commercial strategies. 相似文献