磁铁矿的穆斯堡尔谱研究

我们对大冶、马坑、大顶、黄沙坪、鞍山五个矿区的七个铁矿石样品中的磁铁矿作了室温~(57)Fe和~(119)Sn穆斯堡尔谱测定,并根据穆斯堡尔数据和化学分析推算出磁铁矿的非理想配比的分子结构式. 初步研究表明,不同的成矿条件和Zn、Mg等二价阳离子的类质同像替代的多少,明显地影响晶胞参数和穆斯堡尔参数.文中讨论了它们的变化规律性.     

Alteration and mineralization styles of the orogenic disseminated Zhenyuan gold deposit,southeastern Tibet: Contrast with carlin gold deposit

Orogenic disseminated and Carlin gold deposits share much similarity in alteration and mineralization.The disseminated orogenic Zhenyuan Au deposit along the Ailaoshan shear zone,southeastern Tibet,was selected to clarify their difference.The alteration and mineralization from the different lithologies,including meta-quartz sandstone,carbonaceous slate,meta-(ultra)mafic rock,quartz porphyry and lamprophyre were researched.According to the mineral assemblage and replacement relationship in all types of host rocks,two reactions show general control on gold deposition:(1)replacement of earlier magnetite by pyrite and carbonaceous material;(2)alteration of biotite and phlogopite phenocrysts in quartz porphyry and lamprophyre into dolomite/ankerite and sericite.Despite the lamprophyre is volumetrically minor and much less fractured than other host rocks,it contains a large portion of Au reserve,indicating that the chemically active lithology has played a more important role in gold precipitation compared to structure.LA-ICP-MS analysis shows that Au mainly occurs as invisible gold in fine-grained pyrite disseminated in the host rocks,with Au content reaching to 258.95 ppm.The diagenetic core of pyrite in meta-quartz sandstone enriched in Co,Ni,Mo,Ag and Hg is wrapped by hydrothermal pyrite enriched in Cu,As,Sb,Au,Tl,Pb and Bi.Different host rock lithology has much impact on the alteration and mineralization features.Carbonate and sericite in altered lamprophyre show they have higher Mg than those developed in other of host rocks denoting that the carbonate and sericite incorporated Mg from phlogopite phenocrysts in the primary lamprophyre during alteration.The ore fluid activated the diagenetic pyrite in meta-quartz sandstone leading the hydrothermal pyrite enriched in Cu,Mo,Ag,Sb,Te,Hg,Tl,Pb and Bi,but the hydrothermal pyrite in meta-(ultra)mafic rock is enriched in Co and Ni as the meta-(ultra)mafic rock host rock contain high content of Co and Ni.However,Au and As shear similar range in both types of host rocks indicating that these two elements most likely come from the deep source fluid rather than the host rocks.It was shown in the disseminated orogenic gold deposit that similar hydrothermal alteration with mineral assemblage of carbonate(mainly dolomite and ankerite),sericite,pyrite and arsenopyrite develops in all types of host rocks.This is different from the Nevada Carlin type,in which alteration is mainly dissolution and silicification of carbonate host rock.On the other hand,Au mainly occur as invisible gold in both disseminated orogenic and Carlin gold deposits.     

新疆北部主要金矿床的成矿地球化学特征

主要依据成矿作用方式,基本成矿特点及关键控矿标志等,将新疆北部的主要原生金矿新划分为７个矿床类型,分别是浅成低温热液型金矿、韧性剪切带蚀变岩型金矿、微细粒浸染型金矿、浅成岩－构造蚀变岩型金矿、变质热液型金矿、石英脉型金矿及铜、金伴生型矿床。通过分析比较各矿床类型典型金矿的ＲＥＥ分布型式、其矿石的微量元素含量与分布型式、硫与铅同位素组成及流体包裹体成分等资料,探讨了其成矿地球化学特征。     

Yanshanian Magma-Tectonic-Metallogenic Belt in East China of Circum-Pacific Domain (Ⅰ):Igneous Rocks and Orogenic Processes

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VBA在桩基检测数据批量处理中的应用

工程上有时需将Excel中的数据批量处理成Word文档,以充分利用Excel强大的数据处理和计算分析功能与Word较强的文字处理和排版能力。当工程数据信息较多时,采用传统手工编辑的方法,其工作量非常大,重复性工作多,既费时又很容易出错。结合大型桩基工程,利用Microsoft Office软件中的VBA编程方法实现了桩基检测信息的自动批量生成,为桩基检测提供了及时准确的数据,大大提高了工作效率,具有重要的应用价值。     

基于冠层温度的作物缺水研究进展

冠导温度信息可以很好地反映作物的水分状况。自20世纪70年代以来，基于冠层温度的作物缺水指标的研究经历了三个阶段，即单纯研究冠层温度本身变化特征的第一阶段、以冠层能量平衡原理为基础的作物水分胁迫指数的第二阶段和考虑冠层和土壤的复合温度的水分亏缺指数的第三阶段。指标的局长也由使用手持式红外辐射仪信息扩大到使用航空和卫星遥感信息。这一类指标在点和区域尺度上均可应用。加强这一类指标的研究对于我国北方地区农作物的有效灌溉和区域水资源的管理都有重要意义。     

桂林岩溶洼地和洞穴发生、发展的构造控制剖析

通过对桂林地质构造和岩溶建造的研究,并对岩溶洼地、洞穴发育特征进行分析,认为它们在发生、发展上具有成生的内在联系,从而反映在时空方面具有特定的关系。 这些关系集中表现在岩溶洼地、洞穴是岩溶水沿断裂、裂隙溶蚀、侵蚀扩大、改造、堆积、再改造的结果。其规律性主要反映在方向性、等距性、继承性、成层性及形态关系等几个方面。 实践表明,研究岩溶发育规律,要对构造控制因素进行分析,必须从构造形迹鉴别入手,分析其成生联系、体系归属,了解地质构造的发生。发展阶段和序次,并以此和岩溶岩系(建造)为依据,联系成岩环境(特征)和水文地质条件进行综合分析,才能客观反映构造的控制规律。      

岩溶沉积堆积建造类型及其特征

岩溶沉积— 堆积建造是岩溶作用形成的产物,是认识岩溶发育史、发育规律的物质依据,是岩溶作用时间和空间的记录。本文根据岩溶沉积— 堆积建造的成因以及赋存空间的相互关系,将岩溶沉积—堆积建造划分为岩溶外(地表)沉积和岩溶内(洞穴)沉积两大类;而依据沉积建造的成岩物质及其形成作用,又可分为不含矿的岩溶外沉积、含矿的岩溶外沉积、不含矿的岩溶内沉积和含矿的岩溶内沉积等四大亚类。此外,还根据大地构造运动与岩溶的发育关系,将中国岩溶发育史划分为五大岩溶建造期: ( 1)元古代古岩溶期; ( 2)早古生代加里东古岩溶期; ( 3)晚古生代海西古岩溶期; ( 4)中生代印支和燕山古岩溶期;( 5)新生代喜山岩溶期。      

贵州遵义二叠纪锰矿气液喷口群的发现及地质意义

在通过对遵义市锰矿整装勘查区及周边所有探矿工程资料整理、分析研究的基础上,结合野外大比例尺专项地质填图、剖面实测和测试的成果。将贵州遵义二叠系锰矿与华南古天然气渗漏沉积型锰矿床成矿理论进行详细对比,认为遵义锰矿总体是"内生外成",成锰物质主体来自地幔,遵义锰矿属"古天然气渗漏沉积型锰矿床",借鉴古天然气渗漏沉积型锰矿床的成矿理论和研究方法,运用遵义锰矿裂陷槽盆地结构的划分、同沉积断裂的识别和中心相、过渡相和边缘相判别标志,在断陷盆地中喷溢口及附近,发现矿石及其顶底板具有古天然气渗漏沉积型锰矿床独有的结构构造、同位素、生物组合等特征。研究认为遵义成锰盆地至少存在5个气液渗漏喷溢口,分布于Ⅲ级断陷盆地内,每一个喷溢口构成一个相对独立的气液渗漏喷溢沉积成矿系统,遵义锰矿床是形成由若干个气液渗漏喷溢沉积成矿子系统构成的沉积成矿系统。贵州遵义二叠纪锰矿成矿的气液渗漏喷溢口的发现,对遵义锰矿"内生外成"成因研究提供了宏观地质证据,为建立深部锰矿找矿预测模型提供了重要依据,为研究遵义锰矿的古天然气渗漏沉积型锰矿床成矿系统具有重要意义。     

Hydrogeochemical effects of secondary forest in Guangxi Nongla karst areas in China

Rainfall, throughfall, stemflow and spring were studied in a secondary forest during a wet season from April to August in 2006. Some of the chemicals in throughfall, stemflow and spring were increased in contrast with incident rainfall. Specifically, Cl⁻, HCO₃ ⁻, Na⁺ and Ca²⁺ were leached negatively in throughfall, but K⁺ and Mg²⁺ were leached positively. In stemflow, Cl⁻ and Na⁺ were leached negatively, the others were leached positively and their concentrations were higher than those in throughfall. Total carbon, organic carbon and inorganic carbon in throughfall and stemflow were increased as rainfall went through the secondary forest. The concentration of free CO₂ in rainfall was lower than both, throughfall and stemflow; the relationship between total acidity and free CO₂ was linear. pH of throughfall and stemflow , such as maximum, minimum and mean, were lower than that of rainfall and the extent of pH in spring was changed minimally. We came to a conclusion that rainfall via the secondary forest can lead to further erosion, accelerate the biogeochemical cycle in epikarst zone, enhance the effective state of alkali elements in the soil, supply vegetation with more nutrients and advance vegetation’s growth and succession, which are reasonably sufficient to form a stable karst ecosystem.