Isotopic and element exchange during serpentinization and metasomatism at the Atlantis Massif (MAR 30°N): Insights from B and Sr isotope data

The Lost City hydrothermal system at the southern Atlantis Massif (Mid-Atlantic Ridge, 30°N) provides a natural laboratory for studying serpentinization processes, the temporal evolution of ultramafic-hosted hydrothermal systems, and alteration conditions during formation and emplacement of an oceanic core complex. Here we present B, O, and Sr isotope data to investigate fluid/rock interaction and mass transfer during detachment faulting and exhumation of lithospheric sequences within the Atlantis Massif. Our data indicate that extensive serpentinization was a seawater-dominated process that occurred predominately at temperatures of 150-250 °C and at high integrated W/R ratios that led to a marked boron enrichment (34-91 ppm). Boron removal from seawater during serpentinization is positively correlated with changes in δ¹¹B (11-16‰) but shows no correlation with O-isotope composition. Modeling indicates that B concentrations and isotope values of the serpentinites are controlled by transient temperature-pH conditions. In contrast to prior studies, we conclude that low-temperature marine weathering processes are insignificant for boron geochemistry of the Atlantis Massif serpentinites. Talc- and amphibole-rich fault rocks formed within a zone of detachment faulting at temperatures of approximately 270-350 °C and at low W/R ratios. Talc formation in ultramafic domains in the massif was subsequent to an early stage of serpentinization and was controlled by the access of Si-rich fluids derived through seawater-gabbro interactions. Replacement of serpentine by talc resulted in boron loss and significant lowering of δ¹¹B values (9-10‰), which we model as the product of progressive extraction of boron. Our study provides new constraints on the boron geochemical cycle at oceanic spreading ridges and suggests that serpentinization associated with ultramafic-hosted hydrothermal systems may have important implications for the behavior of boron in subduction zone settings.     

The non-oxidative dissolution of galena nanocrystals: Insights into mineral dissolution rates as a function of grain size, shape, and aggregation state

The acidic, non-oxidative dissolution of galena (PbS) nanocrystals has been studied in detail using transmission electron microscopy (TEM) to follow the evolution of the size and shape of the nanocrystals before and after dissolution experiments, X-ray photoelectron spectroscopy (XPS) to follow particle chemistry, and dissolution rate analysis to compare dissolution rates between nanocrystalline and bulk galena. Dissolution characteristics were also studied as a function of nanocrystal access to bulk vs. confined solution due to the degree of proximity of next-nearest grains. Nearly monodisperse galena nanocyrstals with an average diameter of 14.4 nm were synthesized for this study, and samples were exposed to pH 3, deoxygenated HCl solutions for up to 3 h at 25 °C. Detailed XPS analysis showed the nanocrystals to be free of unwanted contamination, surface complexes, and oxidative artifacts, except for small amounts of lead-containing oxidation species in both pre- and post-dissolution samples which have been observed in fresh, natural bulk galena. Depending on the calculation methods used, galena nanocrystals, under the conditions of our experiments, dissolve at a surface area normalized rate of one to two orders of magnitude faster than bulk galena under similar conditions. We believe that this reflects the higher percentage of reactive surface area on nanocrystalline surfaces vs. surfaces on larger crystals. In addition, it was shown that {1 1 1} and {1 1 0} faces dissolve faster than {1 0 0} faces on nanocrystals, rationalized by the average coordination number of ions on each of these faces. Finally, dissolution was greatly inhibited for galena nanocrystal surfaces that were closely adjacent (1-2 nm, or less) to other nanocyrstals, a direct indication of the properties of aqueous solutions and ion transport in extremely confined spaces and relevant to dissolution variations that have been suspected within aggregates.     

Detection of mRNA sequences homologous to the human glutathione peroxidase and rat cytochrome P-450IVA1 genes in Mytilus edulis

In this study we have used cloned gene probes for human glutathione peroxidase (GPX), rat cytochrome P-450IVA1 and rat cytochrome P-450IIE1 to detect homologous sequences in RNA from the hepato-pancreas of Mytilus edulis. The presence of sequences hybridising to the GPX and P-450IVA1 probes, but not to the P-450IIE1 probe, confirms the ancient origin of the former genes and indicates that conserved-sequence DNA probes from higher organisms can be used to examine the structure and function of genes of environmental interest in marine organisms.     

Structure and Stability of Non-Transform Discontinuities on the Mid-Atlantic Ridge between 24° N and 30° N

Observations of the median valley within the 24–30° N area ofthe Mid-Atlantic Ridge (MAR), using the IOSDL high resolutionside-scan sonar instrument TOBI, image four separate areas of themedian valley, containing part or all of nine spreading segments, and fivenon-transform discontinuities between spreading segments (NTDs).These high resolution side scan images were interpreted in parallel withmultibeam bathymetry (Purdy et al., 1990), giving a greater degree ofstructural precision than is possible with the multibeam data alone. Threedistinct types of NTD were identified, corresponding in part to typespreviously identified from the multibeam bathymetric survey of the area.Type 1 NTDs are termed septal offsets, and are marked by a topographic ridgeseparating the two spreading segments. The offset between the spreadingsegments ranges from 9 to 14 km. These can be further subdivided into Type1A in which the septa run parallel to the overall trend of the MAR and Type1B in which the septa lie at a high angle to the bulk ridge trend. Type 1ANTDs are characterised by overlap of the neovolcanic zones of the segmentson each side, and strong offaxis traces, while Type 1B NTDs show no overlapof neovolcanic zones, and weak offaxis traces. Type 2 NTDs arebrittle/ductile extensional shear zones, marked by oblique extensionalfractures, and associated with rotation of tectonic and volcanic structuresaway from the overall trend of the MAR. Type 3 NTDs are associated withoffsets of less than 5 km, and show no sign of any accommodating structure.In this type of NTD, the offset zone is covered with undeformed volcanics.The type of NTD developed at any locality along the ridge axis appears todepend on the amount of segment offset and segment overlap, the overalltrend of the mid-ocean ridge, the width of the zone of discontinuity, themedian valley offset and the longevity of the offset. These factorsinfluence the mechanical properties of the lithosphere across thediscontinuity, and ultimately the tectonic style of the NTD that can besupported. Thus brittle/ductile extensional shear zones are long-livedstructures favoured by large segment offsets, and small or negative segmentoverlaps. Septa can be short or long lived, and are associated with largesegment offsets. Segment overlaps vary from negative (an along axis gap) tozero, for Type 1B septal offsets, or positive to zero for Type 1A septaloffsets. Non-tectonised NTDs are generally short lived structures,characterised by small segment offsets and zero or positive overlaps.     

Modelling of run up of steep non-breaking waves

A Navier–Stokes solver is used to examine steep waves as they run up a steep beach (10.54°). The volume of fluid method (VOF) is used to model the free surface. Comparison with experimental results shows reasonable overall agreement in the prediction of the free-surface, velocities and accelerations within the flow. A spurious feature at the free-surface was found which does reduce the quality of the results. For a steep wave we see the transition from a steep wave front to a smooth run-up tongue at the beach that is in qualitative agreement with experiment.     

The Black Band Disease of Atlantic Reef Corals.

Abstract. The cyanophyte (Cyanobaclerium) that causes black band disease of Atlantic reef corals is described under the name Phormidium corallyticum , new species (family Oscillatoriaceae) , and its generic placement is discussed from the standpoint of the GEITLERian (classical) and D rouet systems. Distinguishing characters include densely interwoven filaments that form a blackish mat and trichomes without significant cell wall constrictions, almost isodiametric cells (4.2 μm mean width, 4.0μm mean length) tapering end cells, and thin (0.1 μm or less) mucilaginous wall coating. Transmission electron microscopy shows typical cyanophyte cell walls, sheath, nucleoplasm, and cytoplasmic inclusions, but an unusual thylakoid of straight, and, as seen in cell cross section, radiating lamellae. The dark coloration is due to a high concentration of phycocyanin and some phycoerythrin. The species is similar to Oscillatoria (= Phormidium) submembranacea , which differs in several morphological features and does not infect coral tissue. It is concluded that Phormidium should be used for this and related species that have external mucilage but not the distinct sheath found in Lyngbya.     

Fault scarp identification in side-scan sonar and bathymetry images from the Mid-Atlantic Ridge using wavelet-based digital filters

Digital filters designed using wavelet theory are applied to high resolution deep-towed side-scan sonar data from the median valley walls, crestal mountains, and flanks of the Mid-Atlantic Ridge at 29°10 N. With proper tuning, the digital filters are able to identify the location, orientation, length, and width of highly reflective linear features in sonar images. These features are presumed to represent the acoustic backscatter from axis-facing normal faults. The fault locations obtained from the digital filters are well correlated with visual geologic interpretation of the images. The side-scan sonar images are also compared with swath bathymetry from the same area. The digitally filtered bathymetry images contain nine of the eleven faults identified by eye in the detailed geologic interpretation of the side-scan data. Faults with widths (measured perpendicular to their strike) of less than about 150 m are missed in the bathymetry analysis due to the coarser resolution of these data. This digital image processing technique demonstrates the potential of wavelet-based analysis to reduce subjectivity and labor involved in mapping and analyzing topographic features in side-scan sonar and bathymetric image data.     

Cadmium, copper, and zinc interactions with marine humus as a function of ligand structure

The interactions in seawater of cadmium, copper, and zinc with natural levels of marine humus (fulvic and humic acids) were studied using differential pulse anodic stripping voltammetry (DPASV). Interactions with Cu were also examined by ultraviolet spectrophotometry. The degree of interaction relates to the structure of the particular fulvic or humic acid tested. Marine fulvic and humic acids with different equivalent weights and varying degrees of aromaticity and heteroatom substitution were tested to assess the relative importance of these fundamental structural features in determining the degree of interaction. An index of heteroatom substitution, derived from proton magnetic resonance spectra of these materials, when combined with equivalent weights correlated with the nature and degree of metal interaction. Both marine fulvic and humic acids appreciably interacted with Zn. In contrast, the extent of interaction of fulvic acids with Cu appears to be related to their structure while humic acids appear to interact with Cu regardless of structure. Cadmium interacts only with mature, highly crosslinked humic acids.     

Applying a science-forward approach to groundwater regulatory design

Hydrogeology Journal - Groundwater sustainability is challenged by the difference between legal and scientific understanding of groundwater, as well as the lack of focused attention to regulatory...