Si,Al ordering in leucite by high-resolution 27Al MAS NMR spectroscopy

High-resolution ²⁷Al MAS NMR spectra of natural leucite recorded at H ₀=11.7T contain three resolvable resonances at ²⁷Al δ _i = 69.2, 64.7, and 61.0±0.5 ppm. These three resonances are assigned to the three inequivalent framework positions of leucite: T3, T2, and T1, respectively. Fitting the observed spectra yields a Si,Al distribution for leucite in which approximately one-half of the Al is in T1 and one-quarter in each of T2 and T3. This Si,Al distribution differs substantially from those obtained by previous workers using ²⁹Si NMR spectroscopy and X-ray diffraction. New ²⁹Si NMR spectra and revision of previously reported ²⁹Si NMR peak assignments, however, make the ²⁷Al and ²⁹Si NMR results consistent. The ²⁷Al δ _i correlate linearly with the mean T-O-T′ bond angles of the average structure, which allows the peak assignments to be made. However, this correlation lies distinctly toward higher frequency and larger bond angles than correlations for Si,Al ordered aluminosilicates, suggesting that the mean T(Al)-O-T′(Si) bond angle for each site in leucite is smaller than the mean bond angle of the average structure, which is averaged over T(Al)-O-T′(Si) and T(Si)-OT′(Si,Al) angles.     

Shape analysis of Pacific seamounts

Shape statistics have been compiled from 85 profiles of well-surveyed Pacific seamounts in the height range 140–3800 m. A flat-topped cone was fit to each seamount's cross-sectional profile maintaining the slopes of the sides as closely as possible. On each profile a basal widthd_b, a summit widthd_t, and a maximum heighth, were measured. The height-to-basal-radius ratio isξ_h is estimated by the ratio2hd_b and flatnessf by the ratiod_td_b. Slope angleφ = arctan(ε) is estimated fromε =2h(d_b − d_t). Summit height and basal radius are found to be highly correlated (r = 0.93). The 85-point sample mean of the height-to-basal-radius ratio isξ_h = 0.21 ± 0.08 implying that a seamount's summit height is typically one fifth its basal radius. Despite the high correlation, individual points show some scatter, and there may be groupings into different morphological types. For example, all but one of the seamounts with summit heights above 1000 m have values ofξ_h that are larger than the sample mean. The 85-point sample mean of flatness isf = 0.31 ± 0.18. Data points show a large scatter with values off varying between 0 (a pointy cone) and 0.69 (a flat-topped cone). A histogram representation of flatness, however, indicates that certain values off may be more common than others: the histogram shows a bimodal distribution with maxima occurring at values off in the ranges 0.10–0.20 and 0.35–0.50. Moreover, there is some evidence that the mean flatness decreases with summit height so that the preferred shape of a large-sized seamount may be a pointy cone. Slope angle has an 85-point sample mean ofφ = 18 ± 6°; individual values ofφ vary between 5° and 36°. In addition to having a lower than average mean flatness seamounts with heights above 2600 m also have a lower than average mean slope angle (15°). To determine which variables account for most of the observed variation in the seamount shapes, a multivariate principal component analysis was performed on the data using five shape variables (summit height, basal radius, summit radius, flatness, and slope). The analysis indicates that most of the variation is described by two variables: flatness and summit height.     

Experimental effects of water stress on semi-arid Karoo seedlings: implications for field seedling survivorship

Very little is known about seedling establishment in the semi-arid Karoo of southern Africa. In a greenhouse study, we investigated the responses of seedlings of three shrub species to water stress by withholding water at different stages of seedling development. Mortality of the two Asteraceous species, Pteronia pallens and Osteospermum sinuatum was more rapid where seedlings were provided with water for longer periods before being subjected to water stress. Hardened seedlings, exposed to water stress at an earlier stage, survived the longest. These seedlings were the smallest with respect to root and shoot mass. Seedlings of the leaf succulent Ruschia spinosa were extremely hardy and after 400 days without water, approximately 80% of the seedlings were still alive. The last P. pallens seedling died 160 days after water had been withheld. Osteospermum sinuatum seedlings were the least tolerant to water stress and 100% mortality occurred within 120 days. These results are discussed in terms of microhabitat preferences of the seedlings in field situations.     

Farming ‘practice’ as temporally and spatially situated intersections of biography,culture and social structure

This paper brings anthropological, sociological and geographical perspectives to bear on the problem of farm sustainability and, in particular, the legitimation of sustainable farm practices. It attempts to lay some theoretical foundations for explanation of the adoption of farming practices which may, or may not, promote sustainability. A brief survey of the literature surrounding these issues finds many of the current theoretical perspectives incapable of fully accounting for the complexity of farming practice. Reductionist decision/rational‐action models, in particular, are found wanting for their lack of both cultural consistency and social/spatial specificity. Instead, this paper promotes a generative structuralist approach directed towards an analysis of social and economic practice in lived space; that is, firmly anchored in long‐term ethnographic research.     

Changing patterns of Pennsylvanian coal-swamp vegetation and implications of climatic control on coal occurrence

Improved regional and interregional stratigraphic correlations of Pennsylvanian strata permit comparisons of vegetational changes in Euramerican coal swamps. The coal-swamp vegetation is known directly from in situ coal-ball peat deposits from more than 65 coals in the United States and Europe. Interpretations of coal-swamp floras on the basis of coal-ball peat studies are extended to broader regional and stratigraphic patterns by use of coal palynology. Objectives of the quantitative analyses of the vegetation in relation to coal are to determine the botanical constituents at the peat stage and their environmental implications for plant growth and peat accumulation. Morphological and paleoecological analyses provide a basis for deducing freshwater regimes of coal swamps.Changes in composition of Pennsylvanian coal-swamp vegetation are quire similar from one paralic coal region to another and show synchrony that is attributable to climate. Paleobotany and paleogeography of the Euramerican province indicate a moist tropical paleoclimate. Rainfall, runoff and evapotranspiration were the variable climatic controls in the distribution of coal-swamp vegetation, peat accumulation and coal resources. In relative terms of climatic wetness the Pennsylvanian Period is divisible into five intervals, which include two relatively drier intervals that developed during the Lower-Middle and Middle-Upper Pennsylvanian transitions. The climate during Early Pennsylvanian time was moderately wet and the median in moisture availability. Early Middle Pennsylvanian was drier, probably seasonally dry-wet; late Middle Pennsylvanian was the wettest in the Midcontinent; early Late Pennsylvanian was the driest; and late Late Pennsylvanian was probably the wettest in the Dunkard Basin. The five climatic intervals represent a general means of dividing coal resources within each region into groups with similar botanical constituents and environments of peat accumulation. Regional differences in basinal geology and climate were significant variables, but the synchronous control of paleoclimate was of primary importance.     

Controls on sediment export from the Waipaoa River basin, New Zealand

A stability model of drainage basin mass balance is used to interpret historic and prehistoric patterns of sediment production, storage and output from the Waipaoa River basin, New Zealand and assess the sensitivity of basin sediment yield to land use change in the historic period. Climate and vegetation cover changed during the late Holocene, but the drainage basin mass balance system was stable before the basin was deforested by European colonists in the late 19th and early 20th centuries. In this meso‐scale dispersal system sediment sources and sinks are closely linked, and before that time there was also little variability in the rate of terrigenous mass accumulation on the adjacent continental shelf. However, despite strong first‐order geologic controls on erosion and extensive alluvial storage, sediment delivery to the continental shelf is sensitive and highly responsive to historic hillslope destabilization driven by land use change. Alluvial buffering can mask the effects of variations in sediment production within a basin on sediment yield at the outlet, but this is most likely to occur in basins where alluvial storage is large relative to yield and where the residence time of alluvial sediment is long relative to the time scale of environmental change. At present, neither situation applies to the Waipaoa River basin. Thus, the strength of the contemporary depositional signal may not only be due to the intensity of the erosion processes involved, but also to the fact that land use change in the historic period destabilized the drainage basin mass balance system.