The global distribution of pyroclastic deposits on Mercury: The view from MESSENGER flybys 1–3

We present a global survey of candidate pyroclastic deposits on Mercury, derived from images obtained during MESSENGER flybys 1–3 that provided near-global coverage at resolutions between 5 and 0.5 km/pixel. Thirty-five deposits were identified and characterized and are located principally on the floors of craters, along rims of craters, and along the edge of the Caloris basin. Deposits are commonly centered on rimless, often irregularly shaped pits, mostly between 5 and 45 km in diameter. The deposits identified are generally similar in morphology and absolute reflectance to lunar pyroclastic deposits. Spectrally the deposits appear brighter and redder than background Mercury terrain. On the basis of the available coverage, the candidate pyroclastic deposits appear to be essentially globally distributed. The diameters of the deposits, when mapped to lunar gravity conditions, are larger than their lunar counterparts, implying that more abundant volatiles were present during the typical eruptive process than on the Moon. These observations indicate that if these deposits resulted from hawaiian-style eruptions, the volatile contents required would be between ～1600 and 16,000 ppm CO or an equivalent value of H₂O, CO₂, SO₂, or H₂S (for a more oxidizing interior), or N₂, S₂, CS₂, S₂Cl, Cl, Cl₂, or COS (for a more reducing interior). These abundances are much greater than those predicted by existing models for Mercury's formation. An apparent lack of small deposits, compared with the Moon, may be due to resolution effects, a topic that can be further assessed during the orbital phase of the MESSENGER mission. These results provide a framework within which orbital observations by MESSENGER and the future BepiColombo mission can be analyzed.     

Eutrophication of a Maryland/Virginia Coastal Lagoon: a Tipping Point,Ecosystem Changes,and Potential Causes

Water quality in the Maryland/Virginia Coastal Bays has been declining for many years from anthropogenic inputs, but conditions appear to have worsened abruptly following a shift from long-term dry to long-term wet conditions in the early 2000s. Annually and regionally averaged total nitrogen concentrations are approximately twofold higher, but ammonium (NH₄ ⁺) concentrations are up to an order of magnitude higher than in the early 1990s. Averaged nitrate concentrations, however, changed to a lesser degree throughout the time course; water column concentrations remain very low. Total phosphorus has only increased in some bay segments, but increases in phosphate (PO₄ ^3?) have been more pervasive. There were differences in the year in which large increases in each nutrient were first noted: PO₄ ^3? in ~2001–2002, followed by NH₄ ⁺ ~a year later. The effects of a combination of steadily increasing anthropogenic nutrient increases from development, superimposed on nutrient loads from farming and animal operations, and groundwater inputs were accelerated by changes in freshwater flow and associated, negatively reinforcing, biogeochemical responses. Regionally, chlorophyll a concentrations have increased, and submersed aquatic vegetation has decreased. The system is now characterized by sustained summer picoplanktonic algal blooms, both brown tide and cyanobacteria. The retentive nature of this coastal lagoon combined with the reducing nature of the system will make these changes difficult to reverse if the current dual nutrient management practices are not accelerated.     

Inorganic and Organic Nitrogen Use by Phytoplankton Along Chesapeake Bay,Measured Using a Flow Cytometric Sorting Approach

Two different approaches to measuring phytoplankton nitrogen (N) use were compared in late summer 2004 along the main axis of Chesapeake Bay. Uptake of ¹⁵N-labeled ammonium and nitrate and dual-labeled (¹⁵N and ¹³C) urea and dissolved free amino acids (DFAA) were measured in surface water samples from upper, mid, and lower bay stations. Two distinct methods were used to assess the relative uptake of N substrates by phytoplankton and correct for bacterial artifacts: (1) traditional filtration using Whatman glass fiber (GF/F) filters and (2) flow cytometric (FCM) sorting of chlorophyll-containing cells. The concentration of dissolved inorganic N (DIN) decreased with distance south along the bay, whereas dissolved organic N (DON) concentrations were relatively constant. Absolute N uptake rates measured using the traditional approach exceeded those of FCM-sorted phytoplankton, thereby suggesting the possibility of bacterial “contamination.” Ammonium was the dominant N form used throughout the transect, although FCM-sorted phytoplankton relied more on urea and DFAA as the ratio of DON/DIN increased toward the bay mouth. Overall, ammonium comprised 74 ± 17%, urea 10 ± 9%, DFAA 9 ± 7%, and nitrate 7 ± 12% of total measured N uptake by phytoplankton. Results suggest that bacteria relied primarily on DFAA and ammonium for N nutrition but also used N from urea at a rate similar to that of phytoplankton, whereas bacterial nitrate uptake was insignificant. On average, phytoplankton uptake of ammonium, urea, and DFAA was overestimated by 61%, 53%, and 135%, respectively, as a result of bacterial retention on GF/F filters.     

Decoupled stochastic mapping [for mobile robot & AUVnavigation]

This paper describes decoupled stochastic mapping (DSM), a new computationally efficient approach to large-scale concurrent mapping and localization (CML). DSM reduces the computational burden of conventional stochastic mapping by dividing the environment into multiple overlapping submap regions, each with its own stochastic map. Two new approximation techniques are utilized for transferring vehicle state information from one submap to another, yielding a constant-time algorithm whose memory requirements scale linearly with the number of submaps. The approach is demonstrated via simulations and experiments. Simulation results are presented for the case of an autonomous underwater vehicle navigating in an unknown environment with 110 and 1200 features using simulated observations of point features by a forward look sonar. Empirical tests are used to examine the consistency of the error bounds calculated by the different methods. Experimental results are also presented for an environment with 93 features using sonar data obtained in a 3 by 9 by 1 m testing tank     

The icy Galilean satellites: ultraviolet phase curve analysis

Ultraviolet disk-integrated solar phase curves of the icy galilean satellites Europa, Ganymede, and Callisto are presented, using combined data sets from the International Ultraviolet Explorer (IUE), Hubble Space Telescope (HST), and the Galileo Ultraviolet Spectrometer. Global, disk-integrated solar phase curves for all three satellites, in addition to disk-integrated solar phase curves for Europa's leading, trailing, jovian, and anti-jovian hemispheres, are modeled using Hapke's equations for 7 broadband UV wavelengths between 260 and 320 nm. The sparse coverage in solar phase angle, particularly for Ganymede and Callisto, and the noise in the data sets poorly constrain some of the photometric parameter values in the model. However, the results are sufficient for forming a preliminary relationship between the effects of particle bombardment on icy surfaces and photometric scattering properties at ultraviolet wavelengths. Callisto exhibits a large UV opposition surge and a surface comprised of relatively low-backward scattering particles. Europa's surface displays a dichotomy between the jovian and anti-jovian hemispheres (the anti-jovian hemisphere is more backward scattering), while a less pronounced hemispherical variation was detected between the leading and trailing hemispheres. Europa's surface, with the exception of the trailing hemisphere region, appears to have become less backscattering between the late-1970s-early-1980s and the mid-1990s. These results are commensurate with the bombardment history of these surfaces by magnetospheric charged particles.     

Local topographic effects on photometry and reflectance spectra of planetary surfaces: An example based on lunar photometry

Abstract— The photometric properties of the average lunar surface are characterized using Hapke's equations and whole disk observations ranging from 0.36 to 1.06 μm. Synthetic spectra across a crater topographic profile are created using the modeling results. The synthetic spectra are examined for spectral variations created by changes in lighting conditions induced by the topography. Changes above the modeling uncertainties are seen in both spectral slope and band depths, though the most pronounced change is in band depth. The data have insufficient spectral resolution to determine if there are any changes in band center due to photometric effects. No additional absorption features are introduced by the photometry. These results have serious implications on the interpretation of spectral observations in terms of abundance estimates and alteration processes as a function of location and association with geologic features.     

U-Th systematics and Th ages of carbonate chimneys at the Lost City Hydrothermal Field

The Lost City Hydrothermal Field (LCHF) is a serpentinite-hosted vent field located 15 km west of the spreading axis of the Mid-Atlantic Ridge. In this study, uranium-thorium (U-Th) geochronological techniques have been used to examine the U-Th systematics of hydrothermal fluids and the ²³⁰Th ages of hydrothermally-precipitated carbonate chimneys at the LCHF. Fluid sample analyses indicate that endmember fluids likely contain only 0.0073 ng/g U or less compared to 3.28 ± 0.03 ng/g of U in ambient seawater. For fluid samples containing only 2-21% ambient seawater (1.1-11 mmol/kg Mg), Th concentration is 0.11-0.13 pg/g and surrounding seawater concentrations average 0.133 ± 0.016 pg/g. The ²³⁰Th/²³²Th atomic ratios of the vent fluids range from 1 (±10) × 10⁻⁶ to 11 (±5) × 10⁻⁶, are less than those of seawater, and indicate that the vent fluids may contribute a minor amount of non-radiogenic ²³⁰Th to the LCHF carbonate chimney deposits. Chimney ²³⁸U concentrations range from 1 to 10 μg/g and the average chimney corrected initial δ²³⁴U is 147.2 ± 0.8, which is not significantly different from the ambient seawater value of 146.5 ± 0.6. Carbonate ²³²Th concentrations range broadly from 0.0038 ± 0.0003 to 125 ± 16 ng/g and ²³⁰Th/²³²Th atomic ratios vary from near seawater values of 43 (±8) × 10⁻⁶ up to 530 (±25) × 10⁻³. Chimney ages, corrected for initial ²³⁰Th, range from 17 ± 6 yrs to 120 ± 13 kyrs. The youngest chimneys are at the intersection of two active, steeply-dipping normal faults that cut the Atlantis Massif; the oldest chimneys are located in the southwest portion of the field. Vent deposits on a steep, fault-bounded wall on the east side of the field are all <4 kyrs old, indicating that mass wasting in this region is relatively recent. Comparison of results to prior age-dating investigations of submarine hydrothermal systems shows that the LCHF is the most long-lived hydrothermal system known to date. It is likely that seismic activity and active faulting within the Atlantis Massif and the Atlantis Fracture Zone, coupled with volumetric expansion of the underlying serpentinized host rocks play major roles in sustaining hydrothermal activity at this site. The longevity of venting at the LCHF may have implications for ecological succession of microorganisms within serpentinite-hosted vent environments.     

Desert Pavement Disturbance and Artifact Taphonomy: A Case Study from the Eastern Libyan Plateau,Egypt

Accretionary desert pavements on the eastern Libyan Plateau of central Egypt support a rich Middle and Upper Paleolithic artifact assemblage exhibiting intensive blank production and minimal tool production. These assemblages appear to be in primary context with numerous examples of lithic refits showing on‐site lithic production. However, the smallest (length ≤2.5 cm) archaeological fragments are recovered at a much lower rate on this desert pavement surface than expected given comparable data from lithic assemblages in cave and shelter contexts in France. Excavation of archaeological contexts on the Libyan Plateau reveals the loss of small artifact fragments into the subsurface due to aeolian accumulation of silts, whereas geomorphic examination of desert pavement surfaces suggests a potential for relatively isolated bioturbation as a source of lateral and vertical disturbance of desert pavement surfaces over small areas. Archaeologists should be aware of the potential for long‐term assemblage stability as well as small artifact burial in surficial desert pavement contexts.