The estimation of acid dissociation constants in seawater media from potentionmetric titrations with strong base. I. The ionic product of water — Kw

The various assumptions implicit in the calculation of acid dissociation constants (based on ionic medium standard states) from potentiometric titrations using a cell with liquid junction (i.e. a pH measuring cell) have been examined. It was concluded that results can be obtained having an accuracy commensurate with the experimental precision. It has been shown that although the precise composition of the medium is a function of the hydrogen ion concentration (because of the protolytic nature of some of the ions in the media, e.g., sulphate and fluoride), the effect of such variations in the medium composition can be compensated for when defining the activity of hydrogen ion on an ionic medium standard state by defining the concentration of hydrogen ion as:

where β_HSO4 and β_HF are the relevant association constants and S_T and F_T are the total concentrations of sulphate and fluoride, respectively.This approach was used to obtain values for the ionic product of water (K_W) in artificial seawater media at various temperatures and ionic strengths. These were fitted to give the equation (molal concentration units):

$\text{pK}{}_{\mathrm{w}}\text{=}\text{3441.0}\text{T}\text{+2.256-0.7091}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{(}\text{rms deviation 0.01}\text{)}$

where I is the formal ionic strength of the artificial seawater medium and T is the absolute temperature. The values obtained are in reasonable agreement with those found by previous workers.     

The salt composition of rivers in Wrangel Island

Pioneer information about the chemical composition of river water in Wrangel Island has been obtained. It is shown that the water composition reflects the lithogeochemical specifics of primary rocks and ore mineralization. In contrast to many areas of the Russian Far North, river waters of the island are characterized by an elevated background value of total mineralization (i.e., total dissolved solids, TDS) (0.3–2 g/l) and specific chemical type (SO₄-Ca-Mg). This is related to abundance of Late Carboniferous gypsiferous and dolomitic sequences in the mountainous area of the island. It has also been established that the salt composition of some streams is appreciably governed by supergene alterations of the sulfide mineralization associated with the quartz-carbonate vein systems. They make up natural centers of surface water contamination. Waters in such streams are characterized by low pH values (2.4–5.5), high TDS (up to 6–23 g/l) and the SO₄-Mg composition. These waters are also marked by anomalously high concentrations of heavy and nonferrous metals, as well as REE, U, and Th.     

Agglutinated abyssal foraminifers of the equatorial pacific

The quantitative study of the distribution and taxonomic composition of recent living and dead (without plasma) benthic foraminifers revealed three foraminiferal assemblages in the bottom sediments of the Pacific Ocean at depths of 3350 to 4981 m. The assemblage dominated by the epibenthic Lagenammina difflugiformis, Reophax dentaliniformis, and Saccorhiza ramosa occupies the slopes of underwater hills. The assemblage with a high share of the infaunal Cribrostomoides subglobosum, C. nitidum, and Ammobaculites agglutinans is registered on the abyssal plateau. The assemblage with a significant proportion of the large Astrorhiza and Reophax species, which are characterized by an active way of life, populates gentle slopes and narrow depressions with potentially strong bottom currents.     

Radon-rich waters in Russia

In radon mineral curative waters, according to Russian mineral water classification, the radon concentration should be greater than 185 Bq/l. There are about 30 mineral waters with high levels of radon in Russia. Radon-rich waters have high therapeutic effects. It is proven that natural background radiation stimulates the human immune system. Radon is a natural radioactive gas that has no taste, smell or color. Radon-222 is one of the heaviest elements in the zero groups of inert gases. It is a gaseous radioactive element. All radon isotopes are -emitters while the transformation of its decay products is accompanied by the emitting of -or -particles. The main products of radon decay are short-lived isotopes Po, Pb, Bi, and TL. Belonging to the uranium and thorium decay chain, radon isotopes form directly during the decay of radium isotopes. Therefore the radon concentration depends upon the concentration of its parent's isotope in water and rocks washed by it as well as upon the amount of radon emanation. Loose rocks or rocks with a great number of cracks are characterized by higher radon concentration (zones of tectonic disturbance, weathering crusts, etc.).Crystalline rocks usually have higher uranium concentrations than the average bedrock. Examples of rock types, which often have enhanced uranium concentration >5% ppm U includes the following: granites, syenites, pegmatite, acid volcanic rocks and acid gneisses. In the earth's crust radon migrates either in a gaseous or dissolved state. It can go to the surface without any chemical reaction. Formation of the radon-rich therapeutics waters of Russia has been analyzed, and most of them are genetically connected to crystalline acid rocks that have exceeded uranium-radium mineralization. The radon content in Russia reaches more than 8,000 Bq/l. Radon-rich waters of this type occur in the Altai, Karelia, St Petersburg and Trans-Baikal regions. Another type is connected to geodynamic activity of regions and secondary radioactivity. A well-known example of radon-rich waters of the second type is Pyatigorsk in the North Caucasus. Mixing confined carbon dioxide-hydrogen sulfide water and unconfined groundwater forms radon waters. The radon concentration is 1,170–2,430 Bq/l. The occurrence of radon-rich water deposits in other regions of Russia is described. Further investigation of the radon content in other geological environments will contribute to the environmental safety as well as to the solution to many genetic, hydrogeochronological, paleoreconstructive and prediction problems in hydrogeology.     

Two-Dimensional Periodic Waves in an Inviscid Continuously Stratified Fluid

Izvestiya, Atmospheric and Oceanic Physics - In this paper we study the propagation of two-dimensional periodic waves in an inviscid continuously stratified fluid with a free surface in the...     

A new magneto-hydrostatic theory of sunspots

The structure of a stationary sunspot of circular shape is considered. Schluter-Temesvary theory, based on the similarity assumption is criticized. It is shown that this theory does not describe the observed inclination of magnetic field lines in a sunspot. A new assumption is proposed taking into account field lines which return to the photosphere. On the basis of this assumption, the main equation of the new theory is obtained and the results compare well with observations.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

Modelling the time variation of the surface differential rotation in AB Doradus and LQ Hydrae

Sequences of Doppler images of the young, rapidly rotating late-type stars AB Dor and LQ Hya show that their equatorial angular velocity and the amplitude of their surface differential rotation vary versus time. Such variations can be modelled to obtain information on the intensity of the azimuthal magnetic stresses within stellar convection zones. We introduce a simple model in the framework of the mean-field theory and discuss briefly the results of its application to those solar-like stars. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)