Temporal Variations of Chlorinated Solvents in Abstraction Wells

Data obtained during an organic water quality survey of abstraction (pumping) wells in the Triassic Sandstone Aquifer of Birmingham (U.K.) indicate that there are important variations of chlorinated solvent concentrations with time. Short-term observation of solvent concentrations with elapsed pumping time indicates widely differing well responses; such observations are important in establishing good sampling protocols. Long-term monitoring indicates that solvent concentrations, particularly trichloroethene, are often stable with time. When large solvent variations do occur, these are shown to be due to the variation in the abstraction history of the well or significant migration of solvent plumes during the monitoring period. The latter effect is particularly exemplified by rising trends in 1,1,1-trichlroethane concentrations. The changes observed in solvent concentrations during long-term monitoring of the Birmingham Aquifer are slow to occur, but often large.     

Linear system techniques applied to the Fuenmayor Karst Spring, Huesca (Spain)

Black box identification techniques are very useful tools to study the relationship between rainfall and the discharge of karst aquifers. Autocorrelation, cross-correlation, cross-spectral, impulse response identification (Wiener–Hopf and error minimization methods) and parametric identification of transfer functions techniques have been used by different authors. A review of these techniques has been realized to assess the possibilities and limitations. The reviewed techniques are applied to a time rainfall–discharge series of Fuenmayor karst spring, (southern central Pyrenees, Spain) to establish the relative quality of the obtained models. The quality is evaluated with the Nash–Sutcliffe model efficiency coefficient. In addition, effective rainfall has been used to improve the performance of every model. The whitening technique has been used in the cross-correlation technique with good results. The studied spring shows a Fontestorbes type behavior. The linearity of the system has been analyzed by the coherence function. Fuenmayor has an acceptable linear response, except for high frequency events. The parametric identification provides the best efficiency value E = 0.8164 and provides a proper transfer function, with five parameters (one zero, two poles, the gain and the delay). The prediction power of this transfer function is validated with another time series, with an efficiency value of E = 0.7904.     

Genesis of monazite and Y zoning in garnet from the Black Hills, South Dakota

The paragenesis of monazite in metapelitic rocks from the contact aureole of the Harney Peak Granite, Black Hills, South Dakota, was investigated using zoning patterns of monazite and garnet, electron microprobe dating of monazite, bulk-rock compositions, and major phase mineral equilibria. The area is characterized by low-pressure and high-temperature metamorphism with metamorphic zones ranging from garnet to sillimanite zones. Garnet porphyroblasts containing euhedral Y annuli are observed from the garnet to sillimanite zones. Although major phase mineral equilibria predict resorption of garnet at the staurolite isograd and regrowth at the andalusite isograd, textural and mass balance analyses suggest that the formation of the Y annuli is not related to the resorption-and-regrowth of garnet having formed instead during garnet growth in the garnet zone. Monazite grains in Black Hills pelites were divided into two generations on the basis of zoning patterns of Y and U: monazite 1 with low-Y and -U and monazite 2 with high-Y and -U. Monazite 1 occurs in the garnet zone and persists into the sillimanite zone as cores shielded by monazite 2 which starts to form in the andalusite zone. Pelites containing garnet porphyroblasts with Y annuli and monazite 1 with patchy Th zoning are more calcic than those with garnet with no Y annuli and monazite with concentric Th zoning. Monazite 1 is attributed to breakdown of allanite in the garnet zone, additionally giving rise to the Y annuli observed in garnet. Monazite 2 grows in the andalusite zone, probably at the expense of garnet and monazite 1 in the andalusite and sillimanite zones. The ages of the two different generations of monazite are within the precision of chemical dating of electron microprobe. The electron microprobe ages of all monazites from the Black Hills show a single ca. 1713 Ma population, close to the intrusion age of the Harney Peak Granite (1715 Ma). This study demonstrates that Y zoning in garnet and monazite are critical to the interpretation of monazite petrogenesis and therefore monazite ages.     

Structural similarity and variety at the tips in a wide range of strike–slip faults: a review

Strike–slip faults are often accompanied by a variety of structures, particularly at their tips. The zones of additional fracturing are classified as tip‐damage zones. These zones can be subdivided into several different damage patterns based on the nature and orientation of faults and fractures developed. Damage zones at the ends of small strike–slip faults (mode II tips) develop wing cracks, horsetail splays, antithetic faults, synthetic branch faults and solution surfaces. Similar tip‐damage patterns are also commonly observed at larger (regional) scales, but with a dominance of faulting over tensile cracks and solution surfaces. Wing cracks and horsetail splays developed at small‐scale faults are replaced by normal faults in large‐scale faults. Antithetic faults and synthetic branch faults are observed at small and large scales. Thrust faults are developed at large scales, in a similar pattern to solution surfaces at a small scale. All these structures may show slightly different angular relationships to the master fault at small and large scale, but develop in response similar stress distribution and mechanics around the fault. Thus, mode II tip‐damage zones show similar patterns over a wide range of fault scales.     

Exploring Chile: Identities and Their Relation with the Environment through the Film Football Stories

Cinema can be considered a useful tool for understanding different geographic concepts, showing physical and human factors and the interactions between them. Andres Wood's film Football Stories explores the Chilean territory allowing the observation of the differences between the north and south of the country. Geographic components such as landscapes, architectures, the impact of anthropogenic activities, social inequalities, ways of life, and city and countryside differences are analyzed, as well as the importance of location, the spatial environment, and cinematic narration. The study of geography through films could contribute to understanding of our world and to spatial knowledge.     

Jet Deflection by a Quasi-Steady-State Side Wind in the Laboratory

We present experimental data on the steady state deflection of a highly supersonic jet by a side-wind in the laboratory. The use of a long interaction region enables internal shocks to fully cross the jet, leading to the development of significantly more structure in the jet than in previous work with a similar setup (Lebedev et al., 2004). The ability to control the length of the interaction region in the laboratory allows the switch between a regime representing a clumpy jet or wind and a regime similar to a slowly varying mass loss rate. The results indicate that multiple internal oblique shocks develop in the jet and the possible formation of a second working surface as the jet attempts to tunnel through the ambient medium.     

Reactivated strike–slip faults: examples from north Cornwall, UK

Several strike–slip faults at Crackington Haven, UK show evidence of right-lateral movement with tip cracks and dilatational jogs, which have been reactivated by left-lateral strike–slip movement. Evidence for reactivation includes two slickenside striae on a single fault surface, two groups of tip cracks with different orientations and very low displacement gradients or negative (left-lateral) displacements at fault tips.

Evidence for the relative age of the two strike–slip movements is (1) the first formed tip cracks associated with right-lateral slip are deformed, whereas the tip cracks formed during left-lateral slip show no deformation; (2) some of the tip cracks associated with right-lateral movement show left-lateral reactivation; and (3) left-lateral displacement is commonly recorded at the tips of dominantly right-lateral faults.

The orientation of the tip cracks to the main fault is 30–70° clockwise for right-lateral slip, and 20–40° counter-clockwise for left-lateral slip. The structure formed by this process of strike–slip reactivation is termed a “tree structure” because it is similar to a tree with branches. The angular difference between these two groups of tip cracks could be interpreted as due to different stress distribution (e.g., transtensional/transpressional, near-field or far-field stress), different fracture modes or fractures utilizing pre-existing planes of weakness.

Most of the d–x profiles have similar patterns, which show low or negative displacement at the segment fault tips. Although the d–x profiles are complicated by fault segments and reactivation, they provide clear evidence for reactivation. Profiles that experienced two opposite slip movements show various shapes depending on the amount of displacement and the slip sequence. For a larger slip followed by a smaller slip with opposite sense, the profile would be expected to record very low or reverse displacement at fault tips due to late-stage tip propagation. Whereas for a smaller slip followed by larger slip with opposite sense, the d–x profile would be flatter with no reverse displacement at the tips. Reactivation also decreases the ratio of d_max/L since for an original right-lateral fault, left lateral reactivation will reduce the net displacement (d_max) along a fault and increase the fault length (L).

Finally we compare Crackington Haven faults with these in the Atacama system of northern Chile. The Salar Grande Fault (SGF) formed as a left-lateral fault with large displacement in its central region. Later right-lateral reactivation is preserved at the fault tips and at the smaller sub-parallel Cerro Chuculay Fault. These faults resemble those seen at Crackington Haven.     

Controls on the location,morphology and evolution of complex esker systems at decadal timescales,Breiðamerkurjökull,southeast Iceland

This paper uses detailed mapping of eskers to address three questions which are important for reconstructing meltwater behaviour beneath contemporary and ancient ice masses: ‘What controls the morphology of simple and complex esker systems?’, ‘How do esker systems evolve through time?’ and ‘Are esker patterns compatible with groundwater controlled hydraulic spacing of esker tunnels?’. Esker crestlines and widths are mapped on the Breiðamerkurjökull foreland for eight time slices between 1945 and 2007, from high resolution (~50 cm) aerial photography, permitting their long‐term morphological evolution to be analysed in a high level of detail. We find that complex eskers develop where meltwater and sediment is abundant, such that sediment clogs channels, forming distributary eskers. Isolated eskers are simpler and smaller and reflect less abundant meltwater and sediment, which is unable to clog channels. Eskers may take several decades to emerge from outwash deposits containing buried ice and can increase or decrease in size when ice surrounding and underlying them melts out. It has been suggested that groundwater–channel coupling dictates the spacing between eskers at Breiðamerkurjökull. Our results do not dispute this, but suggest that the routing of sediment and meltwater through medial moraines is an additional important control on esker location and spacing. These results may be used to better understand the processes surrounding esker formation in a variety of geographical settings, enabling a more detailed understanding of the operation of meltwater drainage systems in sub‐marginal zones beneath glaciers and ice sheets. Copyright © 2015 John Wiley & Sons, Ltd.     

Frequency modified fourier transform and its application to asteroids

Recently a method has been suggested to analyze the chaotic behaviour of a conservative dynamical system by numerical analysis of the fundamental frequencies. Frequencies and amplitudes are determined step by step. As the frequencies are not generally orthogonal, a Gramm-Schmidt orthogonalization is made and for each new frequency the old amplitudes of previously determined frequencies are corrected. For a chaotic trajectory variations of the frequencies and amplitudes determined over different time periods are expected. The change of frequencies in such a calculation is a measure of the chaoticity of the trajectory. While amplitudes are corrected, the frequencies (once determined) are constant. We suggest here simple linear corrections of frequencies for the effect of other close frequencies. The improvement of frequency determination is demonstrated on a model case. This method is applied to the first fifty numbered asteroids.     

Phase transformations and inherited lattice preferred orientations: implications for seismic properties

In phase transitions via either the martensitic (diffusionless shear) or nucleation and growth mechanism a specific orientation relationship may exist between the two phases. In cases where the orientation relationship is known, the lattice preferred orientation (LPO) inherited by the new phase may be calculated from the LPO of the old phase. The method of calculation is presented in a form suitable for the spherical harmonic method of texture analysis using the orientation distribution function (ODF). Examples are presented for the -β-quartz, calcite-aragonite, orthopyroxene-clinopyroxene and olivine-spinel transformations.

The seismic properties of the transformed and untransformed phases are calculated from the ODF and the single crystal elastic constants. In particular the -β quartz transformation is considered in detail. The quartz polycrystal is very anisotropic in the alpha field (V_p anisotropy coefficient, A = 8.1%) and almost isotropic in the β-field (A = 2.1%). The transition is accompanied by V_p velocity increase of 0.6 km/s. In the other example discussed, olivine-β-spinel, there is also a decrease in V_p anisotropy coefficient from 11.1% (olivine) to 4.0% (β-spinel). The estimate of the volume fraction of olivine at the 400 km discontinuity (associated with this phase transition) is shown to depend on the direction of wave propagation.