The mineralogic transformation of ferrihydrite induced by heterogeneous reaction with bioreduced anthraquinone disulfonate (AQDS) and the role of phosphate

Bioreduced anthraquinone-2,6-disulfonate (AH₂DS; dihydro-anthraquinone) was reacted with a 2-line, Si-substituted ferrihydrite under anoxic conditions at neutral pH in PIPES buffer. Phosphate (P) and bicarbonate (C); common adsorptive oxyanions and media/buffer components known to effect ferrihydrite mineralization; and Fe(II)_aq (as a catalytic mineralization agent) were used in comparative experiments. Heterogeneous AH₂DS oxidation coupled with Fe(III) reduction occurred within 0.13-1 day, with mineralogic transformation occurring thereafter. The product suite included lepidocrocite, goethite, and/or magnetite, with proportions varing with reductant:oxidant ratio (r:o) and the presence of P or C. Lepidocrocite was the primary product at low r:o in the absence of P or C, with evidence for multiple formation pathways. Phosphate inhibited reductive recrystallization, while C promoted goethite formation. Stoichiometric magnetite was the sole product at higher r:o in the absence and presence of P. Lepidocrocite was the primary mineralization product in the Fe(II)_aq system, with magnetite observed at near equal amounts when Fe(II) was high [Fe(II)/Fe(III)] = 0.5 and P was absent. P had a greater effect on reductive mineralization in the Fe(II)_aq system, while AQDS was more effective than Fe(II)_aq in promoting magnetite formation. The mineral products of the direct AH₂DS-driven reductive reaction are different from those observed in AH₂DS-ferrihydite systems with metal reducing bacteria, particularly in presence of P.     

Diamondiferous peridotitic microxenoliths from the Diavik Diamond Mine, NT

Twenty-five diamonds recovered from 21 diamondiferous peridotitic micro-xenoliths from the A154 South and North kimberlite pipes at Diavik (Slave Craton) match the general peridotitic diamond production at this mine with respect to colour, carbon isotopic composition, and nitrogen concentrations and aggregation states. Based on garnet compositions, the majority of the diamondiferous microxenoliths is lherzolitic (G9) in paragenesis, in stark contrast to a predominantly harzburgitic (G10) inclusion paragenesis for the general diamond production. For garnet inclusions in diamonds from A154 South, the lherzolitic paragenesis, compared to the harzburgitic paragenesis, is distinctly lower in Cr content. For microxenolith garnets, however, Cr contents for garnets of both the parageneses are similar and match those of the harzburgitic inclusion garnets. Assuming that the microxenolith diamonds reflect a sample of the general diamond population, the abundant Cr-rich lherzolitic garnets formed via metasomatic overprinting of original harzburgitic diamond sources subsequent to diamond formation, conversion of original harzburgitic diamond sources occurred in the course of metasomatic overprint re-fertilization. Metasomatic overprinting after diamond formation is supported by the finding of a highly magnesian olivine inclusion (Fo₉₅) in a microxenolith diamond that clearly formed in a much more depleted environment than indicated by the composition of its microxenolith host. Chondrite normalized REE patterns of microxenolith garnets are predominantly sinusoidal, similar to observations for inclusion garnets. Sinusoidal REE_N patterns are interpreted to indicate a relatively mild metasomatic overprint through a highly fractionated (very high LREE/HREE) fluid. The predominance of such patterns may explain why the proposed metasomatic conversion of harzburgite to lherzolite appears to have had no destructive effect on diamond content. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Lötschberg–geology for tunnellers

Switzerland's Lötschberg tunnels present a long story of both failure and success. Tunnelling that began 100 years ago ended in a massive disaster–which is a classic of engineering geology–but subsequent works were very much more successful.     

Interactive visualization of 3D mantle convection

The current availability of thousands of processors at many high performance computing centers has made it feasible to carry out, in near real time, interactive visualization of 3D mantle convection temperature fields, using grid configurations having 10–100 million unknowns. We will describe the technical details involved in carrying out this endeavor, using the facilities available at the Laboratory of Computational Science and Engineering (LCSE) at the University of Minnesota. These technical details involve the modification of a parallel mantle convection program, ACuTEMan; the usage of client–server socket based programs to transfer upwards of a terabyte of time series scientific model data using a local network; a rendering system containing multiple nodes; a high resolution PowerWall display, and the interactive visualization software, DSCVR. We have found that working in an interactive visualizastion mode allows for fast and efficient analysis of mantle convection results. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

A depositional model for deep‐lacustrine,partially confined,turbidite fans: Early Cretaceous,North Falkland Basin

This paper presents a model of facies distribution within a set of early Cretaceous, deep‐lacustrine, partially confined turbidite fans (Sea Lion Fan, Sea Lion North Fan and Otter Fan) in the North Falkland Basin, South Atlantic. As a whole, ancient deep‐lacustrine turbidite systems are under‐represented in the literature when compared with those documented in marine basins. Lacustrine turbidite systems can form extensive, good quality hydrocarbon reservoirs, making the understanding of such systems crucial to exploration within lacustrine basins. An integrated analysis of seismic cross‐sections, seismic amplitude extraction maps and 455 m of core has enabled the identification of a series of turbidite fans. The deposits of these fans have been separated into lobe axis, lobe fringe and lobe distal fringe settings. Seismic architectures, observed in the seismic amplitude extraction maps, are interpreted to represent geologically associated heterogeneities, including: feeder systems, terminal mouth lobes, flow deflection, sinuous lobe axis deposits, flow constriction and stranded lobe fringe areas. When found in combination, these architectures suggest ‘partial confinement’ of a system, something that appears to be a key feature in the lacustrine turbidite setting of the North Falkland Basin. Partial confinement of a system occurs when depositionally generated topography controls the flow‐pathway and deposition of subsequent turbidite fan deposits. The term ‘partial confinement’ provides an expression for categorising a system whose depositional boundaries are unconfined by the margins of the basin, yet exhibit evidence of internal confinement, primarily controlled by depositional topography. Understanding the controls that dictate partial confinement; and the resultant distribution of sand‐prone facies within deep‐lacustrine turbidite fans, is important, particularly considering their recent rise as hydrocarbon reservoirs in rift and failed‐rift settings.     

The Solar Mass Ejection Imager (Smei)

We describe an instrument (SMEI) which has been specifically designed to detect and forecast the arrival of solar mass ejections and other heliospheric structures which are moving towards the Earth. Such events may cause geomagnetic storms, with resulting radiation hazards and disruption to military and commercial communications; damage to Earth-orbiting spacecraft; and also terrestrial effects such as surges in transcontinental power transmission lines. The detectors are sensitive over the optical wave-band, which is measured using CCD cameras. SMEI was launched on 6 January 2003 on the Coriolis spacecraft into a Sun-synchronous polar orbit as part of the US DoD Space Test Programme. The instrument contains three cameras, each with a field of view of 60°×3°, which are mounted onto the spacecraft such that they scan most of the sky every 102-min orbit. The sensitivity is such that changes in sky brightness equivalent to a tenth magnitude star in one square degree of sky may be detected. Each camera takes an image every 4 s. The normal telemetry rate is 128 kbits s^–1. In order to extract the emission from a typical large coronal mass ejection, stellar images and the signal from the zodiacal dust cloud must be subtracted. This requires accurate relative photometry to 0.1%. One consequence is that images of stars and the zodiacal cloud will be measured to this photometric accuracy once per orbit. This will enable studies of transient zodiacal cloud phenomena, flare stars, supernovae, comets, and other varying point-like objects.     

Detection and monitoring of offshore oil seeps using ERS/ENVISAT SAR/ASAR data and seep-seismic studies in Krishna–Godavari offshore basin,India

An attempt has been made to use synthetic aperture radar (SAR) data for detection and monitoring of offshore oil seeps in the eastern offshore areas of the Krishna–Godavari Basin, which has been supplemented and correlated with collateral free-air gravity and seismic data. Images of the study area obtained from ENVISAT ASAR image mode were processed and analysed in detail. A number of natural oil seepages were identified and distinguished from pollution and biogenic slicks. These were subsequently studied using different parameters to assign various degrees of confidence. The repetitiveness of the identified seepages was studied and a total of five areas of seep repetitions had been recognized in the study area. The seeps that are repeated in images of different dates are more likely to be of natural origin than others. Simulation and modelling of a particular oil slick arising has been attempted over the Krishna–Godavari offshore using MIKE 21 software.     

Defining and detecting undesirable disturbance in the context of marine eutrophication

An understanding of undesirable disturbance to the balance of organisms is needed to diagnose marine eutrophication as defined by EU Directives and OSPAR. This review summarizes the findings of the UK Defra-funded Undesirable Disturbance Study Team, which concluded that 'an undesirable disturbance is a perturbation of a marine ecosystem that appreciably degrades the health or threatens the sustainable human use of that ecosystem'. A methodology is proposed for detecting disturbance of temperate salt-water communities dominated by phytoplanktonic or phytobenthic primary producers. It relies on monitoring indicators of ecosystem structure and vigour, which are components of health. Undesirable disturbance can be diagnosed by accumulating evidence of ecohydrodynamic type-specific changes in: (i) bulk indicators; (ii) frequency statistics; (iii) flux measurements; (iv) structural indicators; and (v) indicator species. These are exemplified by (i) chlorophyll, transparency, dissolved oxygen, and opportunistic seaweed cover; (ii) HABs frequency; (iii) primary production; (iv) benthic and planktonic 'trophic indices'; (v) seagrasses and Nephrops norvegicus. Ecological Quality Objectives are proposed for some of these. Linking the diagnosis to eutrophication requires correlation of changes with nutrient enrichment. The methodology, which requires the development of a plankton community index and emphasizes the importance of primary production as an indicator of vigour, can be harmonized with the EU Water Framework Directive and OSPAR's Strategy to Combat Eutrophication.     

Dynamic response characterization and simplified analysis methods for viscoelastic dampers considering heat transfer

Viscoelastic (VE) dampers are sensitive to temperature, excitation frequency, and strain level. As they dissipate the kinetic energy from earthquake or wind-induced structural vibrations, their temperature increases from the heat generated, consequently softening their VE materials and lowering their dynamic mechanical properties. Temperature increase can be significant for long-duration loading, but can be limited by heat conduction and convection which depend on damper configuration. The writers analytically explored such effect on the six different dampers by using their previously proposed three-dimensional finite-element analysis method. Results provided better understanding of how heat is generated within the VE material, conducted and stored in different damper parts, and dispersed to the surrounding air. These results also led to characterization of both local (e.g., temperatures, properties, and strain energy density) and global (e.g., hysteresis loops, and stiffness) behavior of VE dampers, and provided a framework for a new simplified one-dimensional (1D) modeling approach for time-history analysis. This new proposed 1D method greatly improves the computation time of the previously proposed long-duration method coupling fractional time-derivatives VE constitutive rule with 1D heat transfer analysis. Unlike the previous method, it idealizes uniform shear strain and VE material property distributions for computational efficiency, but still simulating non-uniform temperature distribution along the thickness direction of the VE material. Despite the approximations, it accurately predicts VE damper global responses.     

A geochemical model of mid-ocean ridge magma chambers

A computer model of mid-ocean ridge basalt generation using trace element geochemistry has been developed. The model simulates a periodically replenished, continually cooled and fractionated magma chamber, with periodic lava extrusion. Primitive basalts from the ocean floor are used to generate likely evolution paths for the magma chamber. The steady state variant of this model has led to the isolation of several variables which critically affect the basalt composition. Although the fraction of cumulates is an important parameter, other variables such as the volume of incoming magma batches, their frequency, and the volume of the mixing cell, play a critical part especially on slow-spreading ridges. The growing magma chamber model uses random number generators to simulate the initiation and growth of a chamber. This model predicts a rapid increase in incompatible element concentrations, immediately after chamber initiation on a fast-spreading ridge. This would occur in situations such as propagating rifts and may help in the understanding of ferrobasalt generation.