Mineralogical controls on environmental mobility of arsenic from historic mine processing residues,New Zealand

Processing of arsenopyrite ore took place at Blackwater Au mine, New Zealand, between 1908 and 1951 and no rehabilitation was undertaken after mine closure. High As concentrations in solid processing residues (up to 40 wt% As) are due to secondary As minerals. Site pH regimes vary from 4.1 to circum-neutral. Originally, all processed As was present as arsenolite (arsenic trioxide polymorph, As^III), a by-product of arsenopyrite roasting. Near the roaster, scorodite precipitated as a result of the high dissolved As concentration during arsenolite dissolution. The formation of scorodite has two major consequences. Firstly, the scorodite precipitate cements the ground in the vicinity of the roaster area, thereby creating an impermeable surface crust (up to 30 wt% As) and encapsulating weathered arsenolite grains within the cement. Secondly, formation of scorodite temporarily immobilizes some of the dissolved As that is generated during nearby arsenolite dissolution. Where all the available arsenolite has dissolved, scorodite becomes soluble, and the dissolved As concentrations are controlled by scorodite solubility, which is at least two orders of magnitudes lower than arsenolite solubility. Downstream Eh conditions fall below the As^V/As^III boundary, so that scorodite does not precipitate and dissolved As concentrations are controlled by arsenolite solubility. Dissolved As reaches up to 52 mg/L in places, and exceeds the current WHO drinking water guideline of 0.01 mg/L by 5200 times. This study shows that dissolved As concentrations in discharge waters at historic mine sites are dependent on the processing technology and associated mineralogy.     

Geochemical changes during neutralisation of acid mine drainage in a dynamic mountain stream, New Zealand

The Mangatini Stream drains a coal mining area in the mountains of northwestern South Island of New Zealand. Abundant rainfall on pyritic rocks yields acid mine drainage (AMD) to the stream, which flows through a steep gorge at discharges that rapidly increase from <1 to >100 m³/s during frequent rain events. The AMD is treated with finely ground limestone, which is discharged as a slurry at a point in the middle of the gorge. The limestone slurry mixes and reacts with the AMD during flow ∼4 km downstream over ∼12 h. Neutralisation reactions increase stream pH from near 3 (untreated Mangatini Stream water impacted by AMD) to 5–6 in the first 250 m downstream, although mixing is commonly incomplete in this zone. Large stream discharge volumes in rain events dilute the neutralising material input, thus driving the pH back towards 4 downstream of treatment. More complete neutralisation is achieved 4 km downstream, even in major rain events, and pH can rise to >7. Partial neutralisation is sufficient to remove most of the dissolved Fe(III) (typically ∼30 mg/L) from the Mangatini Stream in the first 10 m, and remaining dissolved Fe is essentially all Fe(II), which decreases over time as it oxidises and precipitates. Dissolved Al in the Mangatini Stream (typically ∼50 mg/L) decreases steadily downstream over ∼100 m in the limestone mixing zone. Precipitated Fe and Al form amorphous oxyhydroxides that are transported as suspended solids and deposited on the stream bed with excess limestone in zones of low flow velocity. Dissolved Zn is removed from solution by adsorption to Fe oxyhydroxide when pH reaches ∼5, but dissolved Ni remains in solution despite the neutralisation process. Gypsum precipitation occurs throughout the limestone mixing zone, resulting in at least 30% decrease in dissolved . Minor ettringite forms in the first 100 m, but then probably redissolves. The limestone dosing system is an effective method of neutralising the effects of AMD and removing most dissolved metals in a steep mountain stream with frequent rain events where this dynamic environment places many constraints on treatment options.     

Place Perception and Social Interaction on an Exurban Landscape in Central Colorado*

An assumption commonly made in research on exurbanization is that the subdivision of land ownership necessarily creates a socially divisive landscape devoid of shared place perceptions and concerns. This article presents the results of an ethnography project undertaken in a former Colorado ranching valley that is currently exurbanizing. The study revealed not only the emergence of social networks and groups among new residents, but also the presence of distinct themes in place perception and assessment within these assemblages. In particular, the results indicated that concerns about natural hazards and environmental limitations have motivated new residents to interact with one another.     

The radio–optical correlation in steep-spectrum quasars

Using complete samples of steep-spectrum quasars, we present evidence for a correlation between radio and optical luminosity which is not caused by selection effects, nor caused by an orientation dependence (such as relativistic beaming), nor a by-product of cosmic evolution. We argue that this rules out models of jet formation in which there are no parameters in common with the production of the optical continuum. This is arguably the most direct evidence to date for a close link between accretion on to a black hole and the fuelling of relativistic jets. The correlation also provides a natural explanation for the presence of aligned optical/radio structures in only the most radio-luminous high-redshift galaxies.     

The Asian Tsunami disaster,December 2004

The tragic scenes of human suffering in the wake of the Asian tsunami in late December 2004 have thrown into sharp relief the Earth's destructive power (Fig. 1 ). Caused by a tectonic event off the coast of Sumatra, it could be described as a very large earthquake, an unusual tsunami and a massive disaster. Or, with a longer view, it could be considered a normal feature of a convergent plate boundary. Both views are correct.

Figure 1 Open in figure viewer PowerPoint Mass destruction after the tsunami hit the village on the sand bar at Phi Phi Island, Thailand, with unscathed limestone hills behind (Rex Features).     

Solar X-ray Spectrometer (Soxs) Mission on Board GSAT2 Indian Spacecraft: The Low-Energy Payload

The first space-borne solar astronomy experiment of India, namely Solar X-ray Spectrometer (SOXS), was successfully launched on 08 May 2003 on board geostationary satellite GSAT-2 of India. The SOXS is composed of two independent payloads, viz. SOXS Low-Energy Detector (SLD) Payload and SOXS High-Energy Detector (SHD) Payload. The SOXS aims to study the full-disk integrated X-ray emission in the energy range from 4 keV to 10 MeV. In this paper we present the first report on the SLD instrumentation and its in-orbit performance. The SLD payload was designed and developed at the Physical Research Laboratory in collaboration with various centers of Indian Space Research Organisation (ISRO). The basic scientific aim of the SLD payload is to study solar flares in the energy range from 4 to 60 keV with high spectral and temporal resolution. To meet these requirements, the SLD payload employs state-of-the-art solid state detectors, the first time for a solar astronomy experiment, viz. Si PIN (4 –25 keV), and cadmium–zinc–telluride (4 –60 keV). With their superb high-energy resolution characteristics, SLD can observe iron and iron–nickel complex lines that are visible only during solar flares. In view of its 3.4 FOV, the detector package is mounted on a Sun Aspect System, for the first time, to get uninterrupted observations in a geostationary orbit. The SLD payload configuration, its in-flight operation, and the response of the detectors are presented. We also present the first observations of solar flares made by the SLD payload and briefly describe their temporal and spectral mode results.     

The Solar Mass-Ejection Imager (SMEI) Mission

We have launched into near-Earth orbit a solar mass-ejection imager (SMEI) that is capable of measuring sunlight Thomson-scattered from heliospheric electrons from elongations to as close as 18 to greater than 90 from the Sun. SMEI is designed to observe time-varying heliospheric brightness of objects such as coronal mass ejections, co-rotating structures and shock waves. The instrument evolved from the heliospheric imaging capability demonstrated by the zodiacal light photometers of the Helios spacecraft. A near-Earth imager can provide up to three days warning of the arrival of a mass ejection from the Sun. In combination with other imaging instruments in deep space, or alone by making some simple assumptions about the outward flow of the solar wind, SMEI can provide a three-dimensional reconstruction of the surrounding heliospheric density structures.     

The alkaline porphyry associated Yao’an gold deposit,Yunnan, China: rare earth element and stable isotope evidence for magmatic-hydrothermal ore formation

The Yaoan vein-type gold deposit is located in the Ailaoshan-Jinshajiang alkaline intrusive belt, Yunnan Province, China, and is associated both in time and space with 33.5±1.0-Ma-old alkaline intrusions. The gold mineralization is associated with potassic wall-rock alteration. The REE distribution patterns of secondary K-feldspar are generally similar to those of the igneous perthite but with about seven times higher total REE abundances. The alteration is ascribed to a high-REE magmatic fluid derived from the Yaoan alkaline intrusive suite. The hydrothermal Yaoan gold deposit formed during two gold-bearing stages, i.e. a sulfide (pyrite) stage and a sulfide-oxide stage (pyrite-specularite). The REE abundance of early stage I pyrite is relatively high with strong enrichment in LREE, (La/Yb)_n of 40–290, generally positive Eu anomalies (Eu/Eu*=0.86–1.55), and REE patterns very similar to those of secondary feldspar. In contrast, the later stage II pyrite has much lower REE concentrations and lower (La/Yb)_n of 5.5–11.8, Eu/Eu* of 0.49–0.76, and flat chondrite-normalized spidergram patterns. The stage I pyrite has ³⁴S in the range of –2.2 to +3.2, and overlaps with regionally distributed pyrite in least-altered syenite porphyry. In contrast, stage II pyrite has much higher ³⁴S values between +7.8 and +16.5. Carbon isotope data for four samples from stage II revealed ¹³C (PDB) values between –6 and –8. These stable isotope and REE data suggest that magmatic fluids of the alkaline intrusions caused both potassic alteration and stage I sulfide mineralization. The system evolved from stage I to stage II mineralization by influx of meteoric fluids with relatively heavier sulfur, although calcite carbon isotope data suggest that the CO₂ remained dominantly of magmatic origin.Editorial handling: B. Lehmann