The mechanical property of frozen saline sandy soil is complicated due to its complex components and sensitivity to salt content and confining pressure. Thus, a series of triaxial compression tests were carried out on sandy samples with different Na2SO4 contents under different confining pressures to explore the effects of particle breakage, pressure melting, shear dilation and strain softening or hardening. The test results indicate that the stress–strain curves exhibit strain softening/hardening phenomena when the confining pressures are below or above 6 MPa, respectively. A shear dilation phenomenon was observed in the loading process. With increasing confining pressure, the strength firstly increases and then decreases. By taking into consideration the changes between the grain size distributions before and after triaxial compression tests, a failure strength line incorporating the influences of both particle breakage and pressure melting is proposed. In order to describe the deformation characteristics of frozen saline sandy soil, an elastoplastic incremental constitutive model is established based on the test results. The proposed model considers the plastic compressive, plastic shear and breakage mechanisms by adopting the non-associated flow rule. The breakage mechanism can be reflected by an index related to the initial, current and ultimate grain size distributions. The hardening parameters corresponding to compressive and shear mechanisms consider the influence of particle breakage. Then the effect of particle breakage on both the stress–strain and volumetric strain curves is analyzed. The calculated results fit well with the test results, indicating that the developed constitutive model can well describe the mechanical and deformation features of frozen saline sandy soil under various stress levels and stress paths. In addition, the strain softening/hardening, contraction, high dilation and particle breakage can be well captured.
Acta Geotechnica - This paper studies the dilative behavior of clay during drained creep along triaxial tests under constant mean effective stress, where the volumetric strain is caused by the sole... 相似文献
Natural sinhalites, MgAlBO4, from the Ratnapura District, Sri Lanka, and from Bodnar Quarry near Hamburg, Sussex Co., New Jersey, USA, have been characterized by 57Fe Mössbauer spectroscopy, electron microprobe, X-ray single-crystal diffractometry and by electronic structure calculations in order to determine the oxidation state and site occupancy of iron in the sinhalite structure. The samples contain about 3.35 and 1.46 wt% of total iron oxide, respectively. The structure refinement is successful and reproduces the total iron content provided that the substitution of Mg2+ by Fe2+ on the M2 position only is assumed. The 57Fe Mössbauer spectra at 77, 293, 573 and 773 K can be resolved into two doublets with hyperfine parameters common for octahedrally coordinated high-spin Fe2+. There is no evidence for iron in the tetrahedral site. Electronic structure calculations in local spin density approximation yield hyperfine parameters for Fe2+ on the M2-site at 0, 293, 573 and 773 K in quantitative agreement with experiments. Calculated spectroscopic properties for Fe2+ on the M1-site are at variance with the experimental data and, thus, indicate that substitution of Al3+ by Fe2+, if occurring at all, must be accompanied by considerable local expansion and distortion of the M1-octahedron. 相似文献
High concentrations of heavy metal in farmland threatens food production and human health. Our study assesses soil quality and the distribution of Cd, Cr, Cu, Zn, Pb and Ni, to identify possible sources of heavy metals along the banks of the Yangtze River in Huangshi. Heavy metal concentrations of 22 topsoil samples were measured using the inductively coupled plasma mass spectrometry instrument and data was analyzed by multivariate statistic approaches. Heavy metal contamination risk assessment was performed using a combination of the Nemerow multi-factor index method, the Hakanson potential ecological risk index method and the Muller index of geo-accumulation method. These methods determined similar results indicating that cadmium (Cd) poses a health risk to residents at the study site while Cr, Cu, Zn, Pb and Ni do not. The Nemerow multi-factor index method demonstrated that 18 samples were heavily polluted, three moderately polluted and one lightly polluted. The Muller index of geo-accumulation method found ten samples were moderately to strongly polluted by Cd, five were moderately polluted, six were lightly to moderately polluted and one was lightly polluted. The Hakanson potential ecological risk index method proved six samples were strongly polluted, seven were moderately polluted and nine were lightly polluted. Since our sampling sites were all in agricultural lands, we recommend the potential ecological risk index method as the most effective given it not only considers the range of pollutants contributing to soil pollution but factors in heavy metals toxicity. We are apt that the source of the high concentrations of Cd found in topsoil is derived from alluvial sediments upstream of the Yangtze River with a high percentage of residual speciation and a low percentage of exchangeable speciation distribution of Cd. This in turns indicates that a high concentration of Cd in soil had little impact on the natural environment. However, 31.9% of the iron-manganese oxides bound speciation indicating that such levels of Cd in soil would be potentially hazardous to the crops, particularly if exposed to a reductive condition. 相似文献