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41.
The trapped fluid phase in upper mantle xenoliths from Victoria,Australia: implications for mantle metasomatism 总被引:5,自引:0,他引:5
T. Andersen Suzanne Y. O'Reilly W. L. Griffin 《Contributions to Mineralogy and Petrology》1984,88(1-2):72-85
Mantle-derived xenoliths of spinel lherzolite, spinel pyroxenite, garnet pyroxenite and wehrlite from Bullenmerri and Gnotuk maars, southwestern Victoria, Australia contain up to 3 vol.% of fluids trapped at high pressures. The fluid-filled cavities range in size from fluid inclusions (1–100 m) up to vugs 11/2 cm across, lined with euhedral high-pressure phases. The larger cavities form an integral part of the mosaic microstructure. Microthermometry and Raman laser microprobe analysis show that the fluids are dominantly CO2. Small isolated inclusions may have densities 1.19 g/cm3, but most inclusions show microstructural evidence of partial decrepitation during eruption, and these have lower fluid densities. Mass-spectrometric analysis of gases released by crushing or heating shows the presence of He, N2, Ar, H2S, COs and SO2 in small quantities; these may explain the small freezing-point depressions observed in some inclusions. Petrographic, SEM and microprobe studies show that the trapped fluids have reacted with the cavity walls (in clinopyroxene grains) to produce secondary amphiboles and carbonates. The trapped CO2 thus represents only a small residual proportion of an original volatile phase, which has undergone at least two stages of modification — first by equilibration with spinel lherzolite to form amphibole (±mica±apatite), then by limited reaction with the walls of the fluid inclusions. The inferred original fluid was a CO2-H2O mixture, with significant contents of (at least) Cl and sulfur species. Generation of this fluid phase in the garnet-peridotite stability field, followed by its migration to the spinel peridotite stability field, would provide an efficient mechanism for metasomatic enrichment of the upper mantle in LIL elements. This migration could involve either a volatile flux or transport in small volumes of silicate melt that crystallize in the spinel peridotite field. These observations suggest that some portions of the subcontinental upper mantle contain large reservoirs of free fluid CO2, which may be liberated during episodes of rifting or magmatism, to induce granulite-facies metamorphism of the lower crust. 相似文献
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Auger electron spectroscopy has been used to study K-feldspar that has been reacted with both aqueous 10% HF and a 50% mixture of a 10% HF/0.1 N H2SO4 solution. In the feldspar/HF system, the resulting feldspar surface was shown to have been fluorinated; depth profiling, using argon ion sputtering, showed the fluorination to have occurred substantially into the mineral bulk. In the feldspar/ system, the resulting surface contained both fluorine and sulfur. The fluorination had again penetrated into the bulk, but the sulfur could be removed with mild argon ion sputtering. The signal ratio was much lower on the feldspar surface treated with the 10% HF/0.1 N H2SO4 solution than the feldspar surface treated with the weaker 10% HF acid solution. 相似文献
44.
F. Kaminsky O. Zakharchenko R. Davies W. Griffin G. Khachatryan-Blinova A. Shiryaev 《Contributions to Mineralogy and Petrology》2001,140(6):734-753
Alluvial diamonds from the Juina area in Mato Grosso, Brazil, have been characterized in terms of their morphology, syngenetic mineral inclusions, carbon isotopes and nitrogen contents. Morphologically, they are similar to other Brazilian diamonds, showing a strong predominance of rounded dodecahedral crystals. However, other characteristics of the Juina diamonds make them unique. The inclusion parageneses of Juina diamonds are dominated by ultra-high-pressure ("superdeep") phases that differ both from "traditional" syngenetic minerals associated with diamonds and, in detail, from most other superdeep assemblages. Ferropericlase is the dominant inclusion in the Juina diamonds. It coexists with ilmenite, Cr-Ti spinel, a phase with the major-element composition of olivine, and SiO2. CaSi-perovskite inclusions coexist with titanite (sphene), "olivine" and native Ni. MgSi-perovskite coexists with TAPP (tetragonal almandine-pyrope phase). Majoritic garnet occurs in one diamond, associated with CaTi-perovskite, Mn-ilmenite and an unidentified Si-Mg phase. Neither Cr-pyrope nor Mg-chromite was found as inclusions. The spinel inclusions are low in Cr and Mg, and high in Ti (Cr2O3<36.5 wt%, and TiO2>10 wt%). Most ilmenite inclusions have low MgO contents, and some have very high (up to 11.5 wt%) MnO contents. The rare "olivine" inclusions coexisting with ferropericlase have low Mg# (87-89), and higher Ca, Cr and Zn contents than typical diamond-inclusion olivines. They are interpreted as inverted from spinel-structured (Mg, Fe)2Si2O4. This suite of inclusions is consistent with derivation of most of the diamonds from depths near 670 km, and adds ilmenite and relatively low-Cr, high-Ti spinel to the known phases of the superdeep paragenesis. Diamonds from the Juina area are characterized by a narrow range of carbon isotopic composition ('13C=-7.8 to -2.5), except for the one majorite-bearing diamond ('13C=-11.4). There are high proportions of nitrogen-free and low-nitrogen diamonds, and the aggregated B center is predominant in nitrogen-containing diamonds. These observations have practical consequences for diamond exploration: Low-Mg olivine, low-Mg and high-Mn ilmenite, and low-Cr spinel should be included in the list of diamond indicator minerals, and the role of high-Cr, low-Ti spinel as the only spinel associated with diamond, and hence as a criterion of diamond grade in kimberlites, should be reconsidered. 相似文献
45.
Sonja Aulbach William L. Griffin Norman J. Pearson Suzanne Y. O’Reilly Buddy J. Doyle 《Contributions to Mineralogy and Petrology》2007,154(4):409-427
Major-element compositions of minerals in peridotite xenoliths from the Lac de Gras kimberlites provide constraints on the
mode of lithosphere formation beneath the central Slave Craton, Canada. Magnesia contents of reconstructed whole rocks correlate
positively with NiO and negatively with CaO contents, consistent with variable partial melt extraction. Alumina and Cr2O3 contents are broadly positively correlated, suggestive of melt depletion in the absence of a Cr–Al phase. Garnet modes are
high at a given Al2O3 content (a proxy for melt depletion), falling about a 7 GPa melt depletion model. These observations, combined with high
olivine Mg# and major-element relationships of FeO-poor peridotites (<7.5 wt%) indicative of melt loss at pressures >3 GPa
(residual FeO content being a sensitive indicator of melt extraction pressure), and similar high pressures of last equilibration
(∼4.2 to 5.8 GPa), provide multiple lines of evidence that the mantle beneath the central Slave Craton has originated as a
residue from high-pressure melting, possibly during plume subcretion. Apparent low melt depletion pressures for high-FeO peridotites
(>7.5 wt%) could suggest formation in an oceanic setting, followed by subduction to their depth of entrainment. However, these
rocks, which are characterised by low SiO2 contents (<43 wt%), are more likely to be the result of post-melting FeO-addition, leading to spuriously low estimates of
melt extraction pressures. They may have reacted with a silica-undersaturated melt that dissolved orthopyroxene, or experienced
olivine injection by crystallising melts. A secular FeO-enrichment of parts of the deep mantle lithosphere is supported by
lower average Mg# in xenolithic olivine (91.7) compared to olivine inclusions in diamond (92.6). 相似文献
46.
Hybrid Estimation of Semivariogram Parameters 总被引:1,自引:0,他引:1
Two widely used methods of semivariogram estimation are weighted least squares estimation and maximum likelihood estimation.
The former have certain computational advantages, whereas the latter are more statistically efficient. We introduce and study
a “hybrid” semivariogram estimation procedure that combines weighted least squares estimation of the range parameter with
maximum likelihood estimation of the sill (and nugget) assuming known range, in such a way that the sill-to-range ratio in
an exponential semivariogram is estimated consistently under an infill asymptotic regime. We show empirically that such a
procedure is nearly as efficient computationally, and more efficient statistically for some parameters, than weighted least
squares estimation of all of the semivariogram’s parameters. Furthermore, we demonstrate that standard plug-in (or empirical)
spatial predictors and prediction error variances, obtained by replacing the unknown semivariogram parameters with estimates
in expressions for the ordinary kriging predictor and kriging variance, respectively, perform better when hybrid estimates
are plugged in than when weighted least squares estimates are plugged in. In view of these results and the simplicity of computing
the hybrid estimates from weighted least squares estimates, we suggest that software that currently estimates the semivariogram
by weighted least squares methods be amended to include hybrid estimation as an option. 相似文献
47.
Dust in the Wind: Long Range Transport of Dust in the Atmosphere and Its Implications for Global Public and Ecosystem Health 总被引:4,自引:0,他引:4
Movement of soil particles in atmospheres is a normal planetary process. Images of Martian dust devils (wind-spouts) and dust
storms captured by NASA's Pathfinder have demonstrated the significant role that storm activity plays in creating the red
atmospheric haze of Mars. On Earth, desert soils moving in the atmosphere are responsible for the orange hues in brilliant
sunrises and sunsets. In severe dust storm events, millions of tons of soil may be moved across great expanses of land and
ocean. An emerging scientific interest in the process of soil transport in the Earth's atmosphere is in the field of public
and ecosystem health. This article will address the benefits and the potential hazards associated with exposure to particle
fallout as clouds of desert dust traverse the globe.
This revised version was published online in September 2006 with corrections to the Cover Date. 相似文献
48.
Elizabeth Griffin 《Astronomy& Geophysics》2001,42(2):2.25-2.26
Elizabeth Griffin argues for international action to rescue astronomical observations from decay and obsolescence. 相似文献
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